Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity

Cosby, Tyler; Vicars, Zachariah; Heres, Maximilian; Sangoro, Joshua

doi:10.1103/PhysRevLett.120.136001

Title: Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity

Authors:: Cosby, Tyler; Vicars, Zachariah; Heres, Maximilian; Sangoro, Joshua

Publication Date:: 2018-03-27

Sponsoring Org.:: USDOE

OSTI Identifier:: 1429958

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review Letters

Additional Journal Information:: Journal Name: Physical Review Letters Journal Volume: 120 Journal Issue: 13; Journal ID: ISSN 0031-9007

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Cosby, Tyler, Vicars, Zachariah, Heres, Maximilian, and Sangoro, Joshua. Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevLett.120.136001.

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                    Cosby, Tyler, Vicars, Zachariah, Heres, Maximilian, & Sangoro, Joshua. Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity.  United States.  https://doi.org/10.1103/PhysRevLett.120.136001

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                    Cosby, Tyler, Vicars, Zachariah, Heres, Maximilian, and Sangoro, Joshua. Tue .  
"Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity".  United States.  https://doi.org/10.1103/PhysRevLett.120.136001.

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@article{osti_1429958,

  title        = {Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity},

  author       = {Cosby, Tyler and Vicars, Zachariah and Heres, Maximilian and Sangoro, Joshua},

  abstractNote = {},

  doi          = {10.1103/PhysRevLett.120.136001},

  journal      = {Physical Review Letters},

  number       = 13,

  volume       = 120,

  place        = {United States},

  year         = {2018},

  month        = {3}

}

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Works referenced in this record:

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye
journal, December 2014

Böhmer, Roland; Gainaru, Catalin; Richert, Ranko
Physics Reports, Vol. 545, Issue 4
DOI: 10.1016/j.physrep.2014.07.005

The Bend+Libration Combination Band Is an Intrinsic, Collective, and Strongly Solute-Dependent Reporter on the Hydrogen Bonding Network of Liquid Water
journal, November 2017

Verma, Pramod Kumar; Kundu, Achintya; Puretz, Matthew S.
The Journal of Physical Chemistry B, Vol. 122, Issue 9
DOI: 10.1021/acs.jpcb.7b09641

Transport in Proton Conductors for Fuel-Cell Applications: Simulations, Elementary Reactions, and Phenomenology
journal, October 2004

Kreuer, Klaus-Dieter; Paddison, Stephen J.; Spohr, Eckhard
Chemical Reviews, Vol. 104, Issue 10
DOI: 10.1021/cr020715f

Proton Transfer Properties of Imidazole
journal, January 1996

Scheiner, Steve; Yi, Manyin
The Journal of Physical Chemistry, Vol. 100, Issue 22
DOI: 10.1021/jp9600571

Broadband dynamics in neat 4-methyl-3-heptanol and in mixtures with 2-ethyl-1-hexanol
journal, October 2013

Bauer, S.; Wittkamp, H.; Schildmann, S.
The Journal of Chemical Physics, Vol. 139, Issue 13
DOI: 10.1063/1.4821229

Vibrational spectra of 4-methylimidazole: assignment of modes and calculation of Raman and resonance Raman intensities at the ab initio 6-31G level
journal, January 1995

Majoube, M.; Millié, Ph.; Vergoten, G.
Journal of Molecular Structure, Vol. 344, Issue 1-2
DOI: 10.1016/0022-2860(94)08412-B

Analysis of the Dielectric Permittivity of Suspensions by Means of the Logarithmic Derivative of Its Real Part
journal, May 2002

Jiménez, M. L.; Arroyo, F. J.; van Turnhout, J.
Journal of Colloid and Interface Science, Vol. 249, Issue 2
DOI: 10.1006/jcis.2001.8141

Dielectric Study of Intermolecular Association in Isomeric Octyl Alcohols
journal, March 1968

Dannhauser, Walter
The Journal of Chemical Physics, Vol. 48, Issue 5
DOI: 10.1063/1.1668989

Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols
journal, March 2013

Bauer, S.; Burlafinger, K.; Gainaru, C.
The Journal of Chemical Physics, Vol. 138, Issue 9
DOI: 10.1063/1.4793469

Proton Transport in Imidazoles: Unraveling the Role of Supramolecular Structure
journal, September 2015

Cosby, Tyler; Holt, Adam; Griffin, Philip J.
The Journal of Physical Chemistry Letters, Vol. 6, Issue 19
DOI: 10.1021/acs.jpclett.5b01887

Watching Hydrogen-Bonded Structures in an Alcohol Convert from Rings to Chains
journal, October 2012

Singh, Lokendra P.; Richert, Ranko
Physical Review Letters, Vol. 109, Issue 16
DOI: 10.1103/PhysRevLett.109.167802

Debye Type Dielectric Relaxation and the Glass Transition of Alcohols
journal, June 2005

Wang, Li-Min; Richert, Ranko
The Journal of Physical Chemistry B, Vol. 109, Issue 22
DOI: 10.1021/jp051965d

On the relaxation between Debye and nonexponential relaxation in supercooled monohydric alcohols and water: A solution study
journal, August 1989

Floriano, M. A.; Angell, C. A.
The Journal of Chemical Physics, Vol. 91, Issue 4
DOI: 10.1063/1.457013

Investigation of the shear-mechanical and dielectric relaxation processes in two monoalcohols close to the glass transition
journal, November 2008

Jakobsen, Bo; Maggi, Claudio; Christensen, Tage
The Journal of Chemical Physics, Vol. 129, Issue 18
DOI: 10.1063/1.3007988

Nuclear-Magnetic-Resonance Measurements Reveal the Origin of the Debye Process in Monohydroxy Alcohols
journal, December 2010

Gainaru, C.; Meier, R.; Schildmann, S.
Physical Review Letters, Vol. 105, Issue 25
DOI: 10.1103/PhysRevLett.105.258303

Theoretical Study of Structures, Energies, and Vibrational Spectra of the Imidazole−Imidazolium System
journal, October 2003

Tatara, Wiktor; Wójcik, Marek J.; Lindgren, Jan
The Journal of Physical Chemistry A, Vol. 107, Issue 39
DOI: 10.1021/jp030065z

Spectres de vibration de quelques sels d'imidazolium et d'imidazolium (D2) 1,3
journal, July 1971

Bellocq, Anne-Marie; Garrigou-Lagrange, Chatal
Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 27, Issue 7
DOI: 10.1016/0584-8539(71)80192-7

Shear-Modulus Investigations of Monohydroxy Alcohols: Evidence for a Short-Chain-Polymer Rheological Response
journal, March 2014

Gainaru, C.; Figuli, R.; Hecksher, T.
Physical Review Letters, Vol. 112, Issue 9
DOI: 10.1103/PhysRevLett.112.098301

Dynamics of glass-forming liquids. XVII. Dielectric relaxation and intermolecular association in a series of isomeric octyl alcohols
journal, October 2013

Singh, Lokendra P.; Alba-Simionesco, Christiane; Richert, Ranko
The Journal of Chemical Physics, Vol. 139, Issue 14
DOI: 10.1063/1.4823998

Protic ionic liquids: Fuel cell applications
journal, July 2013

Yasuda, Tomohiro; Watanabe, Masayoshi
MRS Bulletin, Vol. 38, Issue 7
DOI: 10.1557/mrs.2013.153

Communication: Slow supramolecular mode in amine and thiol derivatives of 2-ethyl-1-hexanol revealed by combined dielectric and shear-mechanical studies
journal, November 2015

Adrjanowicz, K.; Jakobsen, B.; Hecksher, T.
The Journal of Chemical Physics, Vol. 143, Issue 18
DOI: 10.1063/1.4935510

Dopant effects on 2-ethyl-1-hexanol: A dual-channel impedance spectroscopy and neutron scattering study
journal, January 2015

Singh, Lokendra P.; Raihane, Ahmed; Alba-Simionesco, Christiane
The Journal of Chemical Physics, Vol. 142, Issue 1
DOI: 10.1063/1.4904908

Far‐Infrared Spectra and Hydrogen‐Bond Frequencies of Imidazole
journal, April 1968

Perchard, C.; Novak, A.
The Journal of Chemical Physics, Vol. 48, Issue 7
DOI: 10.1063/1.1669576

Intermediate temperature proton conductors for PEM fuel cells based on phosphonic acid as protogenic group: A progress report
journal, January 2007

Steininger, H.; Schuster, M.; Kreuer, K. D.
Phys. Chem. Chem. Phys., Vol. 9, Issue 15
DOI: 10.1039/B618686F

The water association band as a marker of hydrogen bonds in trehalose amorphous matrices
journal, January 2017

Giuffrida, Sergio; Cottone, Grazia; Cordone, Lorenzo
Physical Chemistry Chemical Physics, Vol. 19, Issue 6
DOI: 10.1039/C6CP06848K

Complex hydrogen bonded cations. The imdazole/imidazolium complex cation
journal, August 1976

Bonsor, D. H.; Borah, B.; Dean, R. L.
Canadian Journal of Chemistry, Vol. 54, Issue 15
DOI: 10.1139/v76-349

Rotation of Imidazole in the Solid State and its Significance in deciding the Nature of Charge Migration in Biological Materials
journal, May 1968

Daycock, J. T.; Jones, G. P.; Evans, J. R. N.
Nature, Vol. 218, Issue 5142
DOI: 10.1038/218672a0

Theoretical and spectroscopic study of hydrogen bond vibrations in imidazole and its deuterated derivative
journal, June 2010

Wójcik, Marek J.; Kwiendacz, Jacek; Boczar, Marek
Chemical Physics, Vol. 372, Issue 1-3
DOI: 10.1016/j.chemphys.2010.04.034

Infrared Spectroscopy of Imidazole Trimer in Helium Nanodroplets: Free NH Stretch Mode
journal, March 2011

Lee, Seul-Ki; Lee, Seung-Jun; Ahn, Ah-Reum
Bulletin of the Korean Chemical Society, Vol. 32, Issue 3
DOI: 10.5012/bkcs.2011.32.3.885

Dielectric relaxation of 2-ethyl-1-hexanol around the glass transition by thermally stimulated depolarization currents
journal, June 2015

Arrese-Igor, S.; Alegría, A.; Colmenero, J.
The Journal of Chemical Physics, Vol. 142, Issue 21
DOI: 10.1063/1.4921655

Enhancement of anhydrous proton transport by supramolecular nanochannels in comb polymers
journal, April 2010

Chen, Yangbin; Thorn, Michael; Christensen, Scott
Nature Chemistry, Vol. 2, Issue 6
DOI: 10.1038/nchem.629

Substructure of the NH stretching vibrational band of imidazole
journal, April 1974

Wolff, H.; Müller, Helm.
The Journal of Chemical Physics, Vol. 60, Issue 7
DOI: 10.1063/1.1681468

412. The hydrogen bonding of imidazole in carbon tetrachloride solution
journal, January 1961

Anderson, D. M. W.; Duncan, J. L.; Rossotti, F. J. C.
Journal of the Chemical Society (Resumed)
DOI: 10.1039/jr9610002165

Dynamics of proton transfer in imidazole hydrogen-bond chains
journal, January 2016

Bua-ngern, Worapong; Chaiwongwattana, Sermsiri; Suwannakham, Parichart
RSC Advances, Vol. 6, Issue 101
DOI: 10.1039/C6RA17636D

Vibrational spectroscopy of diazoles
journal, June 1999

Billes, F.; Endrédi, H.; Jalsovszky, G.
Journal of Molecular Structure: THEOCHEM, Vol. 465, Issue 2-3
DOI: 10.1016/S0166-1280(98)00326-1

Proton dissociation and transfer in a phosphoric acid doped imidazole system
journal, January 2014

Thisuwan, Jittima; Sagarik, Kritsana
RSC Adv., Vol. 4, Issue 106
DOI: 10.1039/C4RA08198F

The Role of Electrical Anharmonicity in the Association Band in the Water Spectrum
journal, April 2014

McCoy, Anne B.
The Journal of Physical Chemistry B, Vol. 118, Issue 28
DOI: 10.1021/jp501647e

Solid State NMR Spectroscopic Investigations of Model Compounds for Imidazole-Based Proton Conductors
journal, December 2004

Fischbach, Ingrid; Spiess, Hans Wolfgang; Saalwächter, Kay
The Journal of Physical Chemistry B, Vol. 108, Issue 48
DOI: 10.1021/jp046848h

Oscillatory shear and high-pressure dielectric study of 5-methyl-3-heptanol
journal, June 2014

Gainaru, C.; Wikarek, M.; Pawlus, S.
Colloid and Polymer Science, Vol. 292, Issue 8
DOI: 10.1007/s00396-014-3274-0

The diffusion mechanism of an excess proton in imidazole molecule chains: first results of an ab initio molecular dynamics study
journal, December 2001

Münch, W.; Kreuer, K. -D; Silvestri, W.
Solid State Ionics, Vol. 145, Issue 1-4
DOI: 10.1016/S0167-2738(01)00941-9

Vibrational Spectra and Ab Initio DFT Calculations of 4-Methylimidazole and Its Different Protonation Forms: Infrared and Raman Markers of the Protonation State of a Histidine Side Chain
journal, May 2000

Hasegawa, Koji; Ono, Taka-aki; Noguchi, Takumi
The Journal of Physical Chemistry B, Vol. 104, Issue 17
DOI: 10.1021/jp000157d

Communication: Linking the dielectric Debye process in mono-alcohols to density fluctuations
journal, April 2016

Hecksher, Tina
The Journal of Chemical Physics, Vol. 144, Issue 16
DOI: 10.1063/1.4947470

Imidazole and pyrazole-based proton conducting polymers and liquids
journal, April 1998

Kreuer, K. D.; Fuchs, A.; Ise, M.
Electrochimica Acta, Vol. 43, Issue 10-11
DOI: 10.1016/S0013-4686(97)10031-7

Observation of the slow, Debye-like relaxation in hydrogen-bonded liquids by dynamic light scattering
journal, March 2014

Wang, Yangyang; Griffin, Philip J.; Holt, Adam
The Journal of Chemical Physics, Vol. 140, Issue 10
DOI: 10.1063/1.4867913

Insights on the origin of the Debye process in monoalcohols from dielectric spectroscopy under extreme pressure conditions
journal, April 2010

Fragiadakis, D.; Roland, C. M.; Casalini, R.
The Journal of Chemical Physics, Vol. 132, Issue 14
DOI: 10.1063/1.3374820

Communication: Supramolecular structures in monohydroxy alcohols: Insights from shear-mechanical studies of a systematic series of octanol structural isomers
journal, September 2014

Hecksher, Tina; Jakobsen, Bo
The Journal of Chemical Physics, Vol. 141, Issue 10
DOI: 10.1063/1.4895095

Mixed Debye-type liquids studied by dielectric, shear mechanical, nuclear magnetic resonance, and near-infrared spectroscopy
journal, January 2015

Bauer, S.; Moch, K.; Münzner, P.
Journal of Non-Crystalline Solids, Vol. 407
DOI: 10.1016/j.jnoncrysol.2014.07.018

Coupling between the Thermal Evolution of the Heme Pocket and the External Matrix Structure in Trehalose Coated Carboxymyoglobin
journal, November 2003

Giuffrida, Sergio; Cottone, Grazia; Librizzi, Fabio
The Journal of Physical Chemistry B, Vol. 107, Issue 47
DOI: 10.1021/jp036194x

Influence of ionic solutes upon the conductivity of molten phosphoric acid
journal, September 1967

Munson, Ronald A.; Lazarus, Michael E.
The Journal of Physical Chemistry, Vol. 71, Issue 10
DOI: 10.1021/j100869a018

On the non-exponentiality of the dielectric Debye-like relaxation of monoalcohols
journal, March 2017

Arrese-Igor, S.; Alegría, A.; Colmenero, J.
The Journal of Chemical Physics, Vol. 146, Issue 11
DOI: 10.1063/1.4978585

Identification of Structural Relaxation in the Dielectric Response of Water
journal, June 2016

Hansen, Jesper S.; Kisliuk, Alexander; Sokolov, Alexei P.
Physical Review Letters, Vol. 116, Issue 23
DOI: 10.1103/PhysRevLett.116.237601

Dielectric Study of the Pressure Dependence of Intermolecular Association in Isomeric Octyl Alcohols
journal, June 1968

Johari, Gyan P.; Dannhauser, Walter
The Journal of Chemical Physics, Vol. 48, Issue 11
DOI: 10.1063/1.1668182

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Title: Associating Imidazoles: Elucidating the Correlation between the Static Dielectric Permittivity and Proton Conductivity

Citation Formats

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye journal, December 2014

The Bend+Libration Combination Band Is an Intrinsic, Collective, and Strongly Solute-Dependent Reporter on the Hydrogen Bonding Network of Liquid Water journal, November 2017

Transport in Proton Conductors for Fuel-Cell Applications: Simulations, Elementary Reactions, and Phenomenology journal, October 2004

Proton Transfer Properties of Imidazole journal, January 1996

Broadband dynamics in neat 4-methyl-3-heptanol and in mixtures with 2-ethyl-1-hexanol journal, October 2013

Vibrational spectra of 4-methylimidazole: assignment of modes and calculation of Raman and resonance Raman intensities at the ab initio 6-31G level journal, January 1995

Analysis of the Dielectric Permittivity of Suspensions by Means of the Logarithmic Derivative of Its Real Part journal, May 2002

Dielectric Study of Intermolecular Association in Isomeric Octyl Alcohols journal, March 1968

Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols journal, March 2013

Proton Transport in Imidazoles: Unraveling the Role of Supramolecular Structure journal, September 2015

Watching Hydrogen-Bonded Structures in an Alcohol Convert from Rings to Chains journal, October 2012

Debye Type Dielectric Relaxation and the Glass Transition of Alcohols journal, June 2005

On the relaxation between Debye and nonexponential relaxation in supercooled monohydric alcohols and water: A solution study journal, August 1989

Investigation of the shear-mechanical and dielectric relaxation processes in two monoalcohols close to the glass transition journal, November 2008

Nuclear-Magnetic-Resonance Measurements Reveal the Origin of the Debye Process in Monohydroxy Alcohols journal, December 2010

Theoretical Study of Structures, Energies, and Vibrational Spectra of the Imidazole−Imidazolium System journal, October 2003

Spectres de vibration de quelques sels d'imidazolium et d'imidazolium (D2) 1,3 journal, July 1971

Shear-Modulus Investigations of Monohydroxy Alcohols: Evidence for a Short-Chain-Polymer Rheological Response journal, March 2014

Dynamics of glass-forming liquids. XVII. Dielectric relaxation and intermolecular association in a series of isomeric octyl alcohols journal, October 2013

Protic ionic liquids: Fuel cell applications journal, July 2013

Communication: Slow supramolecular mode in amine and thiol derivatives of 2-ethyl-1-hexanol revealed by combined dielectric and shear-mechanical studies journal, November 2015

Dopant effects on 2-ethyl-1-hexanol: A dual-channel impedance spectroscopy and neutron scattering study journal, January 2015

Far‐Infrared Spectra and Hydrogen‐Bond Frequencies of Imidazole journal, April 1968

Intermediate temperature proton conductors for PEM fuel cells based on phosphonic acid as protogenic group: A progress report journal, January 2007

The water association band as a marker of hydrogen bonds in trehalose amorphous matrices journal, January 2017

Complex hydrogen bonded cations. The imdazole/imidazolium complex cation journal, August 1976

Rotation of Imidazole in the Solid State and its Significance in deciding the Nature of Charge Migration in Biological Materials journal, May 1968

Theoretical and spectroscopic study of hydrogen bond vibrations in imidazole and its deuterated derivative journal, June 2010

Infrared Spectroscopy of Imidazole Trimer in Helium Nanodroplets: Free NH Stretch Mode journal, March 2011

Dielectric relaxation of 2-ethyl-1-hexanol around the glass transition by thermally stimulated depolarization currents journal, June 2015

Enhancement of anhydrous proton transport by supramolecular nanochannels in comb polymers journal, April 2010

Substructure of the NH stretching vibrational band of imidazole journal, April 1974

412. The hydrogen bonding of imidazole in carbon tetrachloride solution journal, January 1961

Dynamics of proton transfer in imidazole hydrogen-bond chains journal, January 2016

Vibrational spectroscopy of diazoles journal, June 1999

Proton dissociation and transfer in a phosphoric acid doped imidazole system journal, January 2014

The Role of Electrical Anharmonicity in the Association Band in the Water Spectrum journal, April 2014

Solid State NMR Spectroscopic Investigations of Model Compounds for Imidazole-Based Proton Conductors journal, December 2004

Oscillatory shear and high-pressure dielectric study of 5-methyl-3-heptanol journal, June 2014

The diffusion mechanism of an excess proton in imidazole molecule chains: first results of an ab initio molecular dynamics study journal, December 2001

Vibrational Spectra and Ab Initio DFT Calculations of 4-Methylimidazole and Its Different Protonation Forms: Infrared and Raman Markers of the Protonation State of a Histidine Side Chain journal, May 2000

Communication: Linking the dielectric Debye process in mono-alcohols to density fluctuations journal, April 2016

Imidazole and pyrazole-based proton conducting polymers and liquids journal, April 1998

Observation of the slow, Debye-like relaxation in hydrogen-bonded liquids by dynamic light scattering journal, March 2014

Insights on the origin of the Debye process in monoalcohols from dielectric spectroscopy under extreme pressure conditions journal, April 2010

Communication: Supramolecular structures in monohydroxy alcohols: Insights from shear-mechanical studies of a systematic series of octanol structural isomers journal, September 2014

Mixed Debye-type liquids studied by dielectric, shear mechanical, nuclear magnetic resonance, and near-infrared spectroscopy journal, January 2015

Coupling between the Thermal Evolution of the Heme Pocket and the External Matrix Structure in Trehalose Coated Carboxymyoglobin journal, November 2003

Influence of ionic solutes upon the conductivity of molten phosphoric acid journal, September 1967

On the non-exponentiality of the dielectric Debye-like relaxation of monoalcohols journal, March 2017

Identification of Structural Relaxation in the Dielectric Response of Water journal, June 2016

Dielectric Study of the Pressure Dependence of Intermolecular Association in Isomeric Octyl Alcohols journal, June 1968

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye
journal, December 2014

The Bend+Libration Combination Band Is an Intrinsic, Collective, and Strongly Solute-Dependent Reporter on the Hydrogen Bonding Network of Liquid Water
journal, November 2017

Transport in Proton Conductors for Fuel-Cell Applications: Simulations, Elementary Reactions, and Phenomenology
journal, October 2004

Proton Transfer Properties of Imidazole
journal, January 1996

Broadband dynamics in neat 4-methyl-3-heptanol and in mixtures with 2-ethyl-1-hexanol
journal, October 2013

Vibrational spectra of 4-methylimidazole: assignment of modes and calculation of Raman and resonance Raman intensities at the ab initio 6-31G level
journal, January 1995

Analysis of the Dielectric Permittivity of Suspensions by Means of the Logarithmic Derivative of Its Real Part
journal, May 2002

Dielectric Study of Intermolecular Association in Isomeric Octyl Alcohols
journal, March 1968

Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols
journal, March 2013

Proton Transport in Imidazoles: Unraveling the Role of Supramolecular Structure
journal, September 2015

Watching Hydrogen-Bonded Structures in an Alcohol Convert from Rings to Chains
journal, October 2012

Debye Type Dielectric Relaxation and the Glass Transition of Alcohols
journal, June 2005

On the relaxation between Debye and nonexponential relaxation in supercooled monohydric alcohols and water: A solution study
journal, August 1989

Investigation of the shear-mechanical and dielectric relaxation processes in two monoalcohols close to the glass transition
journal, November 2008

Nuclear-Magnetic-Resonance Measurements Reveal the Origin of the Debye Process in Monohydroxy Alcohols
journal, December 2010

Theoretical Study of Structures, Energies, and Vibrational Spectra of the Imidazole−Imidazolium System
journal, October 2003

Spectres de vibration de quelques sels d'imidazolium et d'imidazolium (D2) 1,3
journal, July 1971

Shear-Modulus Investigations of Monohydroxy Alcohols: Evidence for a Short-Chain-Polymer Rheological Response
journal, March 2014

Dynamics of glass-forming liquids. XVII. Dielectric relaxation and intermolecular association in a series of isomeric octyl alcohols
journal, October 2013

Protic ionic liquids: Fuel cell applications
journal, July 2013

Communication: Slow supramolecular mode in amine and thiol derivatives of 2-ethyl-1-hexanol revealed by combined dielectric and shear-mechanical studies
journal, November 2015

Dopant effects on 2-ethyl-1-hexanol: A dual-channel impedance spectroscopy and neutron scattering study
journal, January 2015

Far‐Infrared Spectra and Hydrogen‐Bond Frequencies of Imidazole
journal, April 1968

Intermediate temperature proton conductors for PEM fuel cells based on phosphonic acid as protogenic group: A progress report
journal, January 2007

The water association band as a marker of hydrogen bonds in trehalose amorphous matrices
journal, January 2017

Complex hydrogen bonded cations. The imdazole/imidazolium complex cation
journal, August 1976

Rotation of Imidazole in the Solid State and its Significance in deciding the Nature of Charge Migration in Biological Materials
journal, May 1968

Theoretical and spectroscopic study of hydrogen bond vibrations in imidazole and its deuterated derivative
journal, June 2010

Infrared Spectroscopy of Imidazole Trimer in Helium Nanodroplets: Free NH Stretch Mode
journal, March 2011

Dielectric relaxation of 2-ethyl-1-hexanol around the glass transition by thermally stimulated depolarization currents
journal, June 2015

Enhancement of anhydrous proton transport by supramolecular nanochannels in comb polymers
journal, April 2010

Substructure of the NH stretching vibrational band of imidazole
journal, April 1974

412. The hydrogen bonding of imidazole in carbon tetrachloride solution
journal, January 1961

Dynamics of proton transfer in imidazole hydrogen-bond chains
journal, January 2016

Vibrational spectroscopy of diazoles
journal, June 1999

Proton dissociation and transfer in a phosphoric acid doped imidazole system
journal, January 2014

The Role of Electrical Anharmonicity in the Association Band in the Water Spectrum
journal, April 2014

Solid State NMR Spectroscopic Investigations of Model Compounds for Imidazole-Based Proton Conductors
journal, December 2004

Oscillatory shear and high-pressure dielectric study of 5-methyl-3-heptanol
journal, June 2014

The diffusion mechanism of an excess proton in imidazole molecule chains: first results of an ab initio molecular dynamics study
journal, December 2001

Vibrational Spectra and Ab Initio DFT Calculations of 4-Methylimidazole and Its Different Protonation Forms: Infrared and Raman Markers of the Protonation State of a Histidine Side Chain
journal, May 2000

Communication: Linking the dielectric Debye process in mono-alcohols to density fluctuations
journal, April 2016

Imidazole and pyrazole-based proton conducting polymers and liquids
journal, April 1998

Observation of the slow, Debye-like relaxation in hydrogen-bonded liquids by dynamic light scattering
journal, March 2014

Insights on the origin of the Debye process in monoalcohols from dielectric spectroscopy under extreme pressure conditions
journal, April 2010

Communication: Supramolecular structures in monohydroxy alcohols: Insights from shear-mechanical studies of a systematic series of octanol structural isomers
journal, September 2014

Mixed Debye-type liquids studied by dielectric, shear mechanical, nuclear magnetic resonance, and near-infrared spectroscopy
journal, January 2015

Coupling between the Thermal Evolution of the Heme Pocket and the External Matrix Structure in Trehalose Coated Carboxymyoglobin
journal, November 2003

Influence of ionic solutes upon the conductivity of molten phosphoric acid
journal, September 1967

On the non-exponentiality of the dielectric Debye-like relaxation of monoalcohols
journal, March 2017

Identification of Structural Relaxation in the Dielectric Response of Water
journal, June 2016

Dielectric Study of the Pressure Dependence of Intermolecular Association in Isomeric Octyl Alcohols
journal, June 1968