Continuous plating/stripping behavior of solid-state lithium metal anode in a 3D ion-conductive framework

Yang, Chunpeng; Zhang, Lei; Liu, Boyang; Xu, Shaomao; Hamann, Tanner; McOwen, Dennis; Dai, Jiaqi; Luo, Wei; Gong, Yunhui; Wachsman, Eric D.; Hu, Liangbing

doi:10.1073/pnas.1719758115

Title: Continuous plating/stripping behavior of solid-state lithium metal anode in a 3D ion-conductive framework

Journal Article · 25 March 2018 · Proceedings of the National Academy of Sciences of the United States of America

DOI: https://doi.org/10.1073/pnas.1719758115 · OSTI ID:1429586

Yang, Chunpeng ^[1]; Zhang, Lei ^[1]; Liu, Boyang ^[1]; Xu, Shaomao ^[1]; Hamann, Tanner ^[1]; McOwen, Dennis ^[1]; Dai, Jiaqi ^[1]; Luo, Wei ^[1]; Gong, Yunhui ^[1]; Wachsman, Eric D. ^[1]; Hu, Liangbing ^[1]

Department of Materials Science and Engineering, University of Maryland, College Park, MD 20742

Significance Solid-state lithium metal anode possesses great promise owing to its high energy density and improved safety. This work introduces a strategy for constructing a 3D Li metal anode, which is hosted in a solid-state ion-conducting host and shows a safe and dendrite-free plating/stripping behavior. The host is based on a garnet-type ion-conductive framework and a bottom-deposited Cu current collector. The Li anode is plated within the solid garnet framework from the bottom Cu layer and shows a dendrite-free deposition behavior, effectively averting the dendrite penetration issue. Owing to the 3D ion-conductive host, the volume change and interface contact problem of the Li anode have been significantly mitigated, realizing a high-capacity and safe Li metal anode for solid-state high-energy-density batteries.

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Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0000384; EE0006860

OSTI ID:: 1429586

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 15 Vol. 115; ISSN 0027-8424

Publisher:: Proceedings of the National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
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Title: Continuous plating/stripping behavior of solid-state lithium metal anode in a 3D ion-conductive framework

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