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Title: High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2];  [2];  [2];  [1];  [1];  [1]; ORCiD logo [1]
  1. Energy and Environment Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99352 USA
  2. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99352 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1429524
Grant/Contract Number:  
AC02-05CH11231; AC05-76RL01830
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 30 Journal Issue: 21; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Chen, Shuru, Zheng, Jianming, Mei, Donghai, Han, Kee Sung, Engelhard, Mark H., Zhao, Wengao, Xu, Wu, Liu, Jun, and Zhang, Ji-Guang. High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes. Germany: N. p., 2018. Web. doi:10.1002/adma.201706102.
Chen, Shuru, Zheng, Jianming, Mei, Donghai, Han, Kee Sung, Engelhard, Mark H., Zhao, Wengao, Xu, Wu, Liu, Jun, & Zhang, Ji-Guang. High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes. Germany. doi:10.1002/adma.201706102.
Chen, Shuru, Zheng, Jianming, Mei, Donghai, Han, Kee Sung, Engelhard, Mark H., Zhao, Wengao, Xu, Wu, Liu, Jun, and Zhang, Ji-Guang. Sun . "High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes". Germany. doi:10.1002/adma.201706102.
@article{osti_1429524,
title = {High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes},
author = {Chen, Shuru and Zheng, Jianming and Mei, Donghai and Han, Kee Sung and Engelhard, Mark H. and Zhao, Wengao and Xu, Wu and Liu, Jun and Zhang, Ji-Guang},
abstractNote = {},
doi = {10.1002/adma.201706102},
journal = {Advanced Materials},
number = 21,
volume = 30,
place = {Germany},
year = {2018},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adma.201706102

Citation Metrics:
Cited by: 28 works
Citation information provided by
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Works referenced in this record:

Dilution of Highly Concentrated LiBF 4 /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi 0.5 Mn 1.5 O 4 Positive Electrodes
journal, January 2017

  • Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0611701jes

Ionic-Liquid-Nanoparticle Hybrid Electrolytes: Applications in Lithium Metal Batteries
journal, November 2013

  • Lu, Yingying; Korf, Kevin; Kambe, Yu
  • Angewandte Chemie International Edition, Vol. 53, Issue 2
  • DOI: 10.1002/anie.201307137

Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015

  • Yamada, Yuki; Yamada, Atsuo
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0041514jes

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017


Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016

  • Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12032

Anode-Free Rechargeable Lithium Metal Batteries
journal, August 2016

  • Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming
  • Advanced Functional Materials, Vol. 26, Issue 39
  • DOI: 10.1002/adfm.201602353

Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode
journal, January 2013

  • Ding, Fei; Xu, Wu; Chen, Xilin
  • Journal of The Electrochemical Society, Vol. 160, Issue 10
  • DOI: 10.1149/2.100310jes

A reversible dendrite-free high-areal-capacity lithium metal electrode
journal, April 2017

  • Wang, Hui; Matsui, Masaki; Kuwata, Hiroko
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15106

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

  • Lin, Dingchang; Liu, Yayuan; Cui, Yi
  • Nature Nanotechnology, Vol. 12, Issue 3
  • DOI: 10.1038/nnano.2017.16

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications
journal, March 2017

  • Zheng, Jianming; Lochala, Joshua A.; Kwok, Alexander
  • Advanced Science, Vol. 4, Issue 8
  • DOI: 10.1002/advs.201700032

Li + Solvation and Ionic Transport in Lithium Solvate Ionic Liquids Diluted by Molecular Solvents
journal, December 2015

  • Ueno, Kazuhide; Murai, Junichi; Ikeda, Kohei
  • The Journal of Physical Chemistry C, Vol. 120, Issue 29
  • DOI: 10.1021/acs.jpcc.5b11642

Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994


Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
journal, October 2017

  • Adams, Brian D.; Zheng, Jianming; Ren, Xiaodi
  • Advanced Energy Materials, Vol. 8, Issue 7
  • DOI: 10.1002/aenm.201702097

Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries
journal, March 2014

  • Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro
  • Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046
  • DOI: 10.1021/ja412807w

Solvent Activity in Electrolyte Solutions Controls Electrochemical Reactions in Li-Ion and Li-Sulfur Batteries
journal, February 2015

  • Moon, Heejoon; Mandai, Toshihiko; Tatara, Ryoichi
  • The Journal of Physical Chemistry C, Vol. 119, Issue 8
  • DOI: 10.1021/jp5128578

The Application of Atomic Force Microscopy for the Study of Li Deposition Processes
journal, January 1996

  • Aurbach, Doron
  • Journal of The Electrochemical Society, Vol. 143, Issue 11
  • DOI: 10.1149/1.1837248

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

  • Ding, Fei; Xu, Wu; Graff, Gordon L.
  • Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
  • DOI: 10.1021/ja312241y

Stabilization of Li Metal Anode in DMSO-Based Electrolytes via Optimization of Salt-Solvent Coordination for Li-O 2 Batteries
journal, March 2017


"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015


Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017


Ab initiomolecular dynamics for liquid metals
journal, January 1993


High-energy cathode material for long-life and safe lithium batteries
journal, March 2009

  • Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun
  • Nature Materials, Vol. 8, Issue 4
  • DOI: 10.1038/nmat2418

Solvate Ionic Liquid Electrolyte for Li–S Batteries
journal, January 2013

  • Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.111308jes

Suppression of dendritic lithium formation by using concentrated electrolyte solutions
journal, April 2008


Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013

  • Suo, Liumin; Hu, Yong-Sheng; Li, Hong
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2513

History, Evolution, and Future Status of Energy Storage
journal, May 2012


Li–O2 and Li–S batteries with high energy storage
journal, January 2012

  • Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
  • Nature Materials, Vol. 11, Issue 1, p. 19-29
  • DOI: 10.1038/nmat3191

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer
journal, March 2017

  • Liu, Kai; Pei, Allen; Lee, Hye Ryoung
  • Journal of the American Chemical Society, Vol. 139, Issue 13
  • DOI: 10.1021/jacs.6b13314

A Design Approach to Lithium-Ion Battery Electrolyte Based on Diluted Solvate Ionic Liquids
journal, October 2016

  • Ueno, Kazuhide; Murai, Junichi; Moon, Heejoon
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0121701jes

Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016

  • Lin, Dingchang; Liu, Yayuan; Liang, Zheng
  • Nature Nanotechnology, Vol. 11, Issue 7
  • DOI: 10.1038/nnano.2016.32

Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014

  • Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
  • Nature Materials, Vol. 13, Issue 10
  • DOI: 10.1038/nmat4041

Comparative thermal stability of carbon intercalation anodes and lithium metal anodes for rechargeable lithium batteries
journal, April 1995


High rate and stable cycling of lithium metal anode
journal, February 2015

  • Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7362