Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks
Abstract
Abstract Multi‐component metal–organic frameworks (MOFs) with precisely controlled pore environments are highly desired owing to their potential applications in gas adsorption, separation, cooperative catalysis, and biomimetics. A series of multi‐component MOFs, namely PCN‐900(RE), were constructed from a combination of tetratopic porphyrinic linkers, linear linkers, and rare‐earth hexanuclear clusters (RE 6 ) under the guidance of thermodynamics. These MOFs exhibit high surface areas (up to 2523 cm 2 g −1 ) and unlimited tunability by modification of metal nodes and/or linker components. Post‐synthetic exchange of linear linkers and metalation of two organic linkers were realized, allowing the incorporation of a wide range of functional moieties. Two different metal sites were sequentially placed on the linear linker and the tetratopic porphyrinic linker, respectively, giving rise to an ideal platform for heterogeneous catalysis.
- Authors:
-
[2];
[3]
- College of Science China University of Petroleum (East China) Qingdao Shandong 266580 China
- Department of Chemistry Texas A&,M University College Station TX 77843 USA
- Department of Chemistry Texas A&,M University College Station TX 77843 USA, Department of Materials Science and Engineering Texas A&,M University College Station TX 77842 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1429520
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 18; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Zhang, Liangliang, Yuan, Shuai, Feng, Liang, Guo, Bingbing, Qin, Jun‐Sheng, Xu, Ben, Lollar, Christina, Sun, Daofeng, and Zhou, Hong‐Cai. Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Germany: N. p., 2018.
Web. doi:10.1002/anie.201802661.
Zhang, Liangliang, Yuan, Shuai, Feng, Liang, Guo, Bingbing, Qin, Jun‐Sheng, Xu, Ben, Lollar, Christina, Sun, Daofeng, & Zhou, Hong‐Cai. Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Germany. https://doi.org/10.1002/anie.201802661
Zhang, Liangliang, Yuan, Shuai, Feng, Liang, Guo, Bingbing, Qin, Jun‐Sheng, Xu, Ben, Lollar, Christina, Sun, Daofeng, and Zhou, Hong‐Cai. Sat .
"Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks". Germany. https://doi.org/10.1002/anie.201802661.
@article{osti_1429520,
title = {Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks},
author = {Zhang, Liangliang and Yuan, Shuai and Feng, Liang and Guo, Bingbing and Qin, Jun‐Sheng and Xu, Ben and Lollar, Christina and Sun, Daofeng and Zhou, Hong‐Cai},
abstractNote = {Abstract Multi‐component metal–organic frameworks (MOFs) with precisely controlled pore environments are highly desired owing to their potential applications in gas adsorption, separation, cooperative catalysis, and biomimetics. A series of multi‐component MOFs, namely PCN‐900(RE), were constructed from a combination of tetratopic porphyrinic linkers, linear linkers, and rare‐earth hexanuclear clusters (RE 6 ) under the guidance of thermodynamics. These MOFs exhibit high surface areas (up to 2523 cm 2 g −1 ) and unlimited tunability by modification of metal nodes and/or linker components. Post‐synthetic exchange of linear linkers and metalation of two organic linkers were realized, allowing the incorporation of a wide range of functional moieties. Two different metal sites were sequentially placed on the linear linker and the tetratopic porphyrinic linker, respectively, giving rise to an ideal platform for heterogeneous catalysis.},
doi = {10.1002/anie.201802661},
journal = {Angewandte Chemie (International Edition)},
number = 18,
volume = 57,
place = {Germany},
year = {Sat Mar 24 00:00:00 EDT 2018},
month = {Sat Mar 24 00:00:00 EDT 2018}
}
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