skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks

Authors:
 [1];  [2]; ORCiD logo [2];  [1];  [2];  [1];  [2];  [1]; ORCiD logo [3]
  1. College of Science China University of Petroleum (East China) Qingdao Shandong 266580 China
  2. Department of Chemistry Texas A&,M University College Station TX 77843 USA
  3. Department of Chemistry Texas A&,M University College Station TX 77843 USA, Department of Materials Science and Engineering Texas A&,M University College Station TX 77842 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1429518
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 18; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhang, Liangliang, Yuan, Shuai, Feng, Liang, Guo, Bingbing, Qin, Jun‐Sheng, Xu, Ben, Lollar, Christina, Sun, Daofeng, and Zhou, Hong‐Cai. Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Germany: N. p., 2018. Web. https://doi.org/10.1002/ange.201802661.
Zhang, Liangliang, Yuan, Shuai, Feng, Liang, Guo, Bingbing, Qin, Jun‐Sheng, Xu, Ben, Lollar, Christina, Sun, Daofeng, & Zhou, Hong‐Cai. Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Germany. https://doi.org/10.1002/ange.201802661
Zhang, Liangliang, Yuan, Shuai, Feng, Liang, Guo, Bingbing, Qin, Jun‐Sheng, Xu, Ben, Lollar, Christina, Sun, Daofeng, and Zhou, Hong‐Cai. Sat . "Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks". Germany. https://doi.org/10.1002/ange.201802661.
@article{osti_1429518,
title = {Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks},
author = {Zhang, Liangliang and Yuan, Shuai and Feng, Liang and Guo, Bingbing and Qin, Jun‐Sheng and Xu, Ben and Lollar, Christina and Sun, Daofeng and Zhou, Hong‐Cai},
abstractNote = {},
doi = {10.1002/ange.201802661},
journal = {Angewandte Chemie},
number = 18,
volume = 130,
place = {Germany},
year = {2018},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201802661

Save / Share:

Works referenced in this record:

Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal–Organic Frameworks
journal, March 2015

  • Yuan, Shuai; Lu, Weigang; Chen, Ying-Pin
  • Journal of the American Chemical Society, Vol. 137, Issue 9
  • DOI: 10.1021/ja512762r

Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs
journal, July 2016

  • Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng
  • Journal of the American Chemical Society, Vol. 138, Issue 28
  • DOI: 10.1021/jacs.6b04501

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability
journal, December 2016


Metal–organic frameworks: functional luminescent and photonic materials for sensing applications
journal, January 2017

  • Lustig, William P.; Mukherjee, Soumya; Rudd, Nathan D.
  • Chemical Society Reviews, Vol. 46, Issue 11
  • DOI: 10.1039/C6CS00930A

Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake
journal, May 2013

  • Xue, Dong-Xu; Cairns, Amy J.; Belmabkhout, Youssef
  • Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7660-7667
  • DOI: 10.1021/ja401429x

Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013

  • Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja408084j

Quest for Highly Connected Metal–Organic Framework Platforms: Rare-Earth Polynuclear Clusters Versatility Meets Net Topology Needs
journal, April 2015

  • Alezi, Dalal; Peedikakkal, Abdul Malik P.; Weseliński, Łukasz J.
  • Journal of the American Chemical Society, Vol. 137, Issue 16
  • DOI: 10.1021/jacs.5b00450

Ultra-Tuning of the Rare-Earth fcu-MOF Aperture Size for Selective Molecular Exclusion of Branched Paraffins
journal, October 2015

  • Assen, Ayalew H.; Belmabkhout, Youssef; Adil, Karim
  • Angewandte Chemie International Edition, Vol. 54, Issue 48
  • DOI: 10.1002/anie.201506345

Luminescent Functional Metal–Organic Frameworks
journal, June 2011

  • Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200101d

Hydrogen storage in metal–organic frameworks
journal, January 2009

  • Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
  • DOI: 10.1039/b802256a

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten
journal, January 2015

  • Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M.
  • Angewandte Chemie, Vol. 127, Issue 11
  • DOI: 10.1002/ange.201410252

Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO 2 under Ambient Conditions
journal, February 2014


Cobalt catalysts for the coupling of CO 2 and epoxides to provide polycarbonates and cyclic carbonates
journal, January 2012

  • Lu, Xiao-Bing; Darensbourg, Donald J.
  • Chem. Soc. Rev., Vol. 41, Issue 4
  • DOI: 10.1039/C1CS15142H

Luminescent metal–organic frameworks
journal, January 2009

  • Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.
  • Chemical Society Reviews, Vol. 38, Issue 5
  • DOI: 10.1039/b802352m

Systematic Ligand Modulation Enhances the Moisture Stability and Gas Sorption Characteristics of Quaternary Metal–Organic Frameworks
journal, March 2015

  • Liu, Lujia; Telfer, Shane G.
  • Journal of the American Chemical Society, Vol. 137, Issue 11
  • DOI: 10.1021/jacs.5b00365

Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability
journal, May 2016

  • Yuan, Shuai; Qin, Jun-Sheng; Zou, Lanfang
  • Journal of the American Chemical Society, Vol. 138, Issue 20
  • DOI: 10.1021/jacs.6b03263

Tunable Rare Earth fcu -MOF Platform: Access to Adsorption Kinetics Driven Gas/Vapor Separations via Pore Size Contraction
journal, April 2015

  • Xue, Dong-Xu; Belmabkhout, Youssef; Shekhah, Osama
  • Journal of the American Chemical Society, Vol. 137, Issue 15
  • DOI: 10.1021/ja5131403

Confinement of Ultrasmall Cu/ZnO x Nanoparticles in Metal–Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO 2
journal, March 2017

  • An, Bing; Zhang, Jingzheng; Cheng, Kang
  • Journal of the American Chemical Society, Vol. 139, Issue 10
  • DOI: 10.1021/jacs.7b00058

Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO 2 under Ambient Conditions
journal, February 2014

  • Gao, Wen-Yang; Chen, Yao; Niu, Youhong
  • Angewandte Chemie International Edition, Vol. 53, Issue 10
  • DOI: 10.1002/anie.201309778

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010


A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology
journal, December 2014

  • Feng, Dawei; Gu, Zhi-Yuan; Chen, Ying-Pin
  • Journal of the American Chemical Society, Vol. 136, Issue 51
  • DOI: 10.1021/ja510525s

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013

  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
  • DOI: 10.1021/ja408959g

“Heterogeneity within Order” in Metal-Organic Frameworks
journal, January 2015

  • Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M.
  • Angewandte Chemie International Edition, Vol. 54, Issue 11
  • DOI: 10.1002/anie.201410252

Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net
journal, February 2017

  • Chen, Zhijie; Weseliński, Łukasz J.; Adil, Karim
  • Journal of the American Chemical Society, Vol. 139, Issue 8
  • DOI: 10.1021/jacs.7b00219

Lanthanide-Containing Molecular and Supramolecular Polymetallic Functional Assemblies
journal, June 2002

  • Bünzli, Jean-Claude G.; Piguet, Claude
  • Chemical Reviews, Vol. 102, Issue 6
  • DOI: 10.1021/cr010299j

Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
journal, December 2015

  • Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo
  • Nature Protocols, Vol. 11, Issue 1
  • DOI: 10.1038/nprot.2016.001

Metal–Organic Frameworks in Biomedicine
journal, September 2011

  • Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek
  • Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268
  • DOI: 10.1021/cr200256v

A facile synthesis of UiO-66, UiO-67 and their derivatives
journal, January 2013

  • Katz, Michael J.; Brown, Zachary J.; Colón, Yamil J.
  • Chemical Communications, Vol. 49, Issue 82
  • DOI: 10.1039/c3cc46105j

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Exciton Migration and Amplified Quenching on Two-Dimensional Metal–Organic Layers
journal, May 2017

  • Cao, Lingyun; Lin, Zekai; Shi, Wenjie
  • Journal of the American Chemical Society, Vol. 139, Issue 20
  • DOI: 10.1021/jacs.7b02470

Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation
journal, January 2014

  • Sasan, Koroush; Lin, Qipu; Mao, ChengYu
  • Chemical Communications, Vol. 50, Issue 72
  • DOI: 10.1039/C4CC03946G

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

  • Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
  • Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456
  • DOI: 10.1002/ange.201204475

Versatile rare earth hexanuclear clusters for the design and synthesis of highly-connected ftw -MOFs
journal, January 2015

  • Luebke, Ryan; Belmabkhout, Youssef; Weseliński, Łukasz J.
  • Chemical Science, Vol. 6, Issue 7
  • DOI: 10.1039/C5SC00614G

From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999

  • Reineke, Theresa M.; Eddaoudi, Mohamed; Fehr, Michael
  • Journal of the American Chemical Society, Vol. 121, Issue 8, p. 1651-1657
  • DOI: 10.1021/ja983577d

A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
journal, October 2014

  • Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat
  • Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864
  • DOI: 10.1021/ja508626n

A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability
journal, December 2016

  • Cai, Guorui; Jiang, Hai-Long
  • Angewandte Chemie International Edition, Vol. 56, Issue 2
  • DOI: 10.1002/anie.201610914

A Five-Coordinate Heme Dioxygen Adduct Isolated within a Metal–Organic Framework
journal, November 2014

  • Anderson, John S.; Gallagher, Audrey T.; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 136, Issue 47
  • DOI: 10.1021/ja5103103

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions
journal, June 2017

  • Xia, Qingchun; Li, Zijian; Tan, Chunxia
  • Journal of the American Chemical Society, Vol. 139, Issue 24
  • DOI: 10.1021/jacs.7b03113

Programmed Pore Architectures in Modular Quaternary Metal–Organic Frameworks
journal, November 2013

  • Liu, Lujia; Konstas, Kristina; Hill, Matthew R.
  • Journal of the American Chemical Society, Vol. 135, Issue 47
  • DOI: 10.1021/ja4100244

Cooperative Bond Scission in a Soft Porous Crystal Enables Discriminatory Gate Opening for Ethylene over Ethane
journal, November 2017

  • Sen, Susan; Hosono, Nobuhiko; Zheng, Jia-Jia
  • Journal of the American Chemical Society, Vol. 139, Issue 50
  • DOI: 10.1021/jacs.7b10110

Organo Lanthanide Metal Complexes for Electroluminescent Materials
journal, June 2002

  • Kido, Junji; Okamoto, Yoshi
  • Chemical Reviews, Vol. 102, Issue 6
  • DOI: 10.1021/cr010448y

Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal–organic frameworks
journal, June 2014

  • Guillerm, Vincent; Weseliński, Łukasz J.; Belmabkhout, Youssef
  • Nature Chemistry, Vol. 6, Issue 8
  • DOI: 10.1038/nchem.1982

Ultra-Tuning of the Rare-Earth fcu-MOF Aperture Size for Selective Molecular Exclusion of Branched Paraffins
journal, October 2015

  • Assen, Ayalew H.; Belmabkhout, Youssef; Adil, Karim
  • Angewandte Chemie, Vol. 127, Issue 48
  • DOI: 10.1002/ange.201506345

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

  • Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
  • Angewandte Chemie International Edition, Vol. 51, Issue 41
  • DOI: 10.1002/anie.201204475

Synthesis of cyclic carbonates from epoxides and CO2
journal, January 2010

  • North, Michael; Pasquale, Riccardo; Young, Carl
  • Green Chemistry, Vol. 12, Issue 9
  • DOI: 10.1039/c0gc00065e