Oligoanilines as a suppressor of polysulfide shuttling in lithium–sulfur batteries

Chang, Chi-Hao; Chung, Sheng-Heng; Han, Pauline; Manthiram, Arumugam

doi:10.1039/c7mh00510e

Title: Oligoanilines as a suppressor of polysulfide shuttling in lithium–sulfur batteries

Journal Article · 24 July 2017 · Materials Horizons

DOI: https://doi.org/10.1039/c7mh00510e · OSTI ID:1429330

Chang, Chi-Hao ^[1]; Chung, Sheng-Heng ^[2]; Han, Pauline ^[2];

^[2]

Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program & Texas Materials Institute; University of Texas at Austin
Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program & Texas Materials Institute

The migration of small polysulfide (LiPS) chains through the porous polymeric separators seriously jeopardizes the cycle life and energy density of lithium–sulfur (Li–S) batteries. Herein, we present a new concept in which an organic oligoaniline, amine-capped aniline trimer (ACAT), serves as an effective suppressor of the LiPS migration in Li–S cells. The strong interaction between LiPS and ACAT facilitates the formation of bulky ACAT–LiPS complexes (organoLiPS complexes), which are then size-selectively sieved by the porous polymeric separators employed in Li–S cells. Thus, the addition of ACAT significantly ameliorates the electrochemical performances of Li–S batteries due to suppressed LiPS migration. This new concept offers a viable strategy to achieve practically viable Li–S batteries.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007218

OSTI ID:: 1429330

Alternate ID(s):: OSTI ID: 1430185; OSTI ID: 1487267

Journal Information:: Materials Horizons, Journal Name: Materials Horizons Journal Issue: 5 Vol. 4; ISSN 2051-6347; ISSN MHAOAL

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Progress on the Critical Parameters for Lithium-Sulfur Batteries to be Practically Viable Chung, Sheng-Heng; Chang, Chi-Hao; Manthiram, Arumugam Advanced Functional Materials, Vol. 28, Issue 28 https://doi.org/10.1002/adfm.201801188	journal	May 2018
Polyaniline: an effective suppressor against diffusion and dissolution of polysulfides in Li-S battery Yao, Yujie; Zhang, Hongming; Wang, Xianhong Journal of Solid State Electrochemistry, Vol. 23, Issue 8 https://doi.org/10.1007/s10008-019-04340-3	journal	July 2019
A three-dimensional self-assembled SnS ₂ -nano-dots@graphene hybrid aerogel as an efficient polysulfide reservoir for high-performance lithium–sulfur batteries Luo, Liu; Chung, Sheng-Heng; Manthiram, Arumugam Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta01089g	journal	January 2018
Current Status and Future Prospects of Metal–Sulfur Batteries Chung, Sheng‐Heng; Manthiram, Arumugam Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201901125	journal	May 2019
A robust and ion-conductive protein-based binder enabling strong polysulfide anchoring for high-energy lithium–sulfur batteries Fu, Xuewei; Scudiero, Louis; Zhong, Wei-Hong Journal of Materials Chemistry A, Vol. 7, Issue 4 https://doi.org/10.1039/c8ta11384j	journal	January 2019
Toward Better Lithium–Sulfur Batteries: Functional Non-aqueous Liquid Electrolytes Xiong, Shizhao; Regula, Michael; Wang, Donghai Electrochemical Energy Reviews, Vol. 1, Issue 3 https://doi.org/10.1007/s41918-018-0015-y	journal	August 2018

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