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Title: Unusually large chemical potential shift in a degenerate semiconductor: Angle-resolved photoemission study of SnSe and Na-doped SnSe

In this work, we have studied the electronic structure of SnSe and Na-doped SnSe by means of angle-resolved photoemission spectroscopy. The valence-band top reaches the Fermi level by the Na doping, indicating that Na-doped SnSe can be viewed as a degenerate semiconductor. However, in the Na-doped system, the chemical potential shift with temperature is unexpectedly large and is apparently inconsistent with the degenerate semiconductor picture. Lastly, the large chemical potential shift and anomalous spectral shape are key ingredients for an understanding of the novel metallic state with the large thermoelectric performance in Na-doped SnSe.
Authors:
 [1] ;  [1] ;  [1] ;  [2] ;  [3] ;  [3] ;  [3] ;  [4] ;  [4] ;  [4]
  1. Waseda Univ., Shinjuku (Japan). Department of Applied Physics
  2. University of Roma “La Sapienza” (Italy). Department of Physics
  3. Hiroshima University (Japan). Hiroshima Synchrotron Radiation Center
  4. Northwestern Univ., Evanston, IL (United States). Department of Chemistry
Publication Date:
Grant/Contract Number:
SC0014520
Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 97; Journal Issue: 12; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Research Org:
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
OSTI Identifier:
1429263
Alternate Identifier(s):
OSTI ID: 1429142

Maeda, M., Yamamoto, K., Mizokawa, T., Saini, N. L., Arita, M., Namatame, H., Taniguchi, M., Tan, G., Zhao, L. D., and Kanatzidis, M. G.. Unusually large chemical potential shift in a degenerate semiconductor: Angle-resolved photoemission study of SnSe and Na-doped SnSe. United States: N. p., Web. doi:10.1103/PhysRevB.97.121110.
Maeda, M., Yamamoto, K., Mizokawa, T., Saini, N. L., Arita, M., Namatame, H., Taniguchi, M., Tan, G., Zhao, L. D., & Kanatzidis, M. G.. Unusually large chemical potential shift in a degenerate semiconductor: Angle-resolved photoemission study of SnSe and Na-doped SnSe. United States. doi:10.1103/PhysRevB.97.121110.
Maeda, M., Yamamoto, K., Mizokawa, T., Saini, N. L., Arita, M., Namatame, H., Taniguchi, M., Tan, G., Zhao, L. D., and Kanatzidis, M. G.. 2018. "Unusually large chemical potential shift in a degenerate semiconductor: Angle-resolved photoemission study of SnSe and Na-doped SnSe". United States. doi:10.1103/PhysRevB.97.121110.
@article{osti_1429263,
title = {Unusually large chemical potential shift in a degenerate semiconductor: Angle-resolved photoemission study of SnSe and Na-doped SnSe},
author = {Maeda, M. and Yamamoto, K. and Mizokawa, T. and Saini, N. L. and Arita, M. and Namatame, H. and Taniguchi, M. and Tan, G. and Zhao, L. D. and Kanatzidis, M. G.},
abstractNote = {In this work, we have studied the electronic structure of SnSe and Na-doped SnSe by means of angle-resolved photoemission spectroscopy. The valence-band top reaches the Fermi level by the Na doping, indicating that Na-doped SnSe can be viewed as a degenerate semiconductor. However, in the Na-doped system, the chemical potential shift with temperature is unexpectedly large and is apparently inconsistent with the degenerate semiconductor picture. Lastly, the large chemical potential shift and anomalous spectral shape are key ingredients for an understanding of the novel metallic state with the large thermoelectric performance in Na-doped SnSe.},
doi = {10.1103/PhysRevB.97.121110},
journal = {Physical Review B},
number = 12,
volume = 97,
place = {United States},
year = {2018},
month = {3}
}

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