Ion distribution in dry polyelectrolyte multilayers: a neutron reflectometry study
Abstract
Counterions were found to be uniformly distributed in polycation-terminated films of poly(diallyldimethylammonium) and poly(styrenesulfonate) prepared on silicon wafers using layer-by-layer adsorption.
- Authors:
-
- Florida State Univ., Tallahassee, FL (United States)
- Technische Univ. Berlin (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
- Technische Univ. Berlin (Germany); Technische Univ. Darmstadt (Germany)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1429185
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Soft Matter
- Additional Journal Information:
- Journal Volume: 14; Journal Issue: 9; Journal ID: ISSN 1744-683X
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS
Citation Formats
Ghoussoub, Yara E., Zerball, Maximilian, Fares, Hadi M., Ankner, John F., von Klitzing, Regine, and Schlenoff, Joseph B. Ion distribution in dry polyelectrolyte multilayers: a neutron reflectometry study. United States: N. p., 2018.
Web. doi:10.1039/c7sm02461d.
Ghoussoub, Yara E., Zerball, Maximilian, Fares, Hadi M., Ankner, John F., von Klitzing, Regine, & Schlenoff, Joseph B. Ion distribution in dry polyelectrolyte multilayers: a neutron reflectometry study. United States. https://doi.org/10.1039/c7sm02461d
Ghoussoub, Yara E., Zerball, Maximilian, Fares, Hadi M., Ankner, John F., von Klitzing, Regine, and Schlenoff, Joseph B. Fri .
"Ion distribution in dry polyelectrolyte multilayers: a neutron reflectometry study". United States. https://doi.org/10.1039/c7sm02461d. https://www.osti.gov/servlets/purl/1429185.
@article{osti_1429185,
title = {Ion distribution in dry polyelectrolyte multilayers: a neutron reflectometry study},
author = {Ghoussoub, Yara E. and Zerball, Maximilian and Fares, Hadi M. and Ankner, John F. and von Klitzing, Regine and Schlenoff, Joseph B.},
abstractNote = {Counterions were found to be uniformly distributed in polycation-terminated films of poly(diallyldimethylammonium) and poly(styrenesulfonate) prepared on silicon wafers using layer-by-layer adsorption.},
doi = {10.1039/c7sm02461d},
journal = {Soft Matter},
number = 9,
volume = 14,
place = {United States},
year = {Fri Feb 09 00:00:00 EST 2018},
month = {Fri Feb 09 00:00:00 EST 2018}
}
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Cited by: 25 works
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Figures / Tables:
Scheme 1: A) Stoichiometric polyelectrolyte complex films contain only polymer/polymer interactions – intrinsic sites, while B) overcharged or overcompensated films, in addition to these sites, also contain extrinsic sites, polymer/counterion interactions, stemming from the excess of one polyelectrolyte. For simplicity, the scheme shows idealized layering in a cross-section.
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Works referencing / citing this record:
Ionic conductivity of solid polyelectrolyte complexes with varying water content: application of the dynamic structure model
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