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Title: Wittichenite Cu3BiS3: Synthesis and Physical Properties

Abstract

Polycrystalline Cu3BiS3 was synthesized and densified using hot pressing in order to investigate the physical properties of this material. Both the thermal conductivity and the Seebeck coefficient of Cu3BiS3 are reported for the first time in order to investigate the thermoelectric properties of this material. The ultralow thermal conductivity coupled with the relatively high Seebeck coefficient, 0.17 W/m-K and 540 μV/K at room temperature, respectively, suggest Cu3BiS3 may show promise for thermoelectric applications.

Authors:
 [1];  [1];  [2];  [1]
  1. Univ. of South Florida, Tampa, FL (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1427667
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Electronic Materials
Additional Journal Information:
Journal Volume: 47; Journal Issue: 4; Journal ID: ISSN 0361-5235
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Wei, Kaya, Hobbis, Dean, Wang, Hsin, and Nolas, George S. Wittichenite Cu3BiS3: Synthesis and Physical Properties. United States: N. p., 2018. Web. doi:10.1007/s11664-017-6053-0.
Wei, Kaya, Hobbis, Dean, Wang, Hsin, & Nolas, George S. Wittichenite Cu3BiS3: Synthesis and Physical Properties. United States. doi:10.1007/s11664-017-6053-0.
Wei, Kaya, Hobbis, Dean, Wang, Hsin, and Nolas, George S. Thu . "Wittichenite Cu3BiS3: Synthesis and Physical Properties". United States. doi:10.1007/s11664-017-6053-0. https://www.osti.gov/servlets/purl/1427667.
@article{osti_1427667,
title = {Wittichenite Cu3BiS3: Synthesis and Physical Properties},
author = {Wei, Kaya and Hobbis, Dean and Wang, Hsin and Nolas, George S.},
abstractNote = {Polycrystalline Cu3BiS3 was synthesized and densified using hot pressing in order to investigate the physical properties of this material. Both the thermal conductivity and the Seebeck coefficient of Cu3BiS3 are reported for the first time in order to investigate the thermoelectric properties of this material. The ultralow thermal conductivity coupled with the relatively high Seebeck coefficient, 0.17 W/m-K and 540 μV/K at room temperature, respectively, suggest Cu3BiS3 may show promise for thermoelectric applications.},
doi = {10.1007/s11664-017-6053-0},
journal = {Journal of Electronic Materials},
number = 4,
volume = 47,
place = {United States},
year = {2018},
month = {1}
}

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Cited by: 2 works
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Works referenced in this record:

The crystal structure of wittichenite, Cu3BiS3
journal, November 1973

  • Kocman, V.; Nuffield, E. W.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 29, Issue 11
  • DOI: 10.1107/S0567740873006953

Is Cu 3 SbSe 3 a promising thermoelectric material?
journal, January 2015

  • Wei, Tian-Ran; Wu, Chao-Feng; Sun, Wei
  • RSC Advances, Vol. 5, Issue 53
  • DOI: 10.1039/C5RA03953C

Enhanced thermoelectric properties of Cu2ZnSnSe4 with Ga-doping
journal, November 2015


Transient surface photovoltage of p-type Cu3BiS3
journal, February 2010

  • Mesa, F.; Gordillo, G.; Dittrich, Th.
  • Applied Physics Letters, Vol. 96, Issue 8
  • DOI: 10.1063/1.3334728

Transport Properties of Bulk Thermoelectrics: An International Round-Robin Study, Part II: Thermal Diffusivity, Specific Heat, and Thermal Conductivity
journal, March 2013

  • Wang, Hsin; Porter, Wallace D.; Böttner, Harald
  • Journal of Electronic Materials, Vol. 42, Issue 6
  • DOI: 10.1007/s11664-013-2516-0

Role of Lone-Pair Electrons in Producing Minimum Thermal Conductivity in Nitrogen-Group Chalcogenide Compounds
journal, November 2011


Formation of Cu3BiS3 thin films via sulfurization of Bi–Cu metal precursors
journal, June 2012


Semiconducting Cu 3 BiS 3 thin films formed by the solid-state reaction of CuS and bismuth thin films
journal, January 2003

  • Estrella, Ver nica; Nair, M. T. S.; Nair, P. K.
  • Semiconductor Science and Technology, Vol. 18, Issue 2
  • DOI: 10.1088/0268-1242/18/2/322

Thermoelectric performance enhancement of Cu 2 S by Se doping leading to a simultaneous power factor increase and thermal conductivity reduction
journal, January 2017

  • Yao, Yao; Zhang, Bo-Ping; Pei, Jun
  • Journal of Materials Chemistry C, Vol. 5, Issue 31
  • DOI: 10.1039/C7TC01937H

Synthesis of Cu 3 BiS 3 Thin Films by Heating Metal and Metal Sulfide Precursor Films under Hydrogen Sulfide
journal, December 2006

  • Gerein, Nathan J.; Haber, Joel A.
  • Chemistry of Materials, Vol. 18, Issue 26
  • DOI: 10.1021/cm061452z

Thermoelectric properties of Cu 3 SbSe 3 with intrinsically ultralow lattice thermal conductivity
journal, January 2014

  • Tyagi, Kriti; Gahtori, Bhasker; Bathula, Sivaiah
  • J. Mater. Chem. A, Vol. 2, Issue 38
  • DOI: 10.1039/C4TA02590C

Solvothermal Synthesis of Cu 3 BiS 3 Enabled by Precursor Complexing
journal, January 2013

  • Viezbicke, Brian D.; Birnie, Dunbar P.
  • ACS Sustainable Chemistry & Engineering, Vol. 1, Issue 3
  • DOI: 10.1021/sc3000477

Phonon Scattering through a Local Anisotropic Structural Disorder in the Thermoelectric Solid Solution Cu 2 Zn 1– x Fe x GeSe 4
journal, December 2012

  • Zeier, Wolfgang G.; Pei, Yanzhong; Pomrehn, Gregory
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja308627v

Cu 3 BiS 3 as a potential photovoltaic absorber with high optical efficiency
journal, February 2013

  • Kumar, Mukesh; Persson, Clas
  • Applied Physics Letters, Vol. 102, Issue 6
  • DOI: 10.1063/1.4792751

The phase transformations and thermal expansion of the solid electrolyte Cu3BiS3 between 25 and 300°C
journal, August 1983


The Cu-Bi-S system: results from low-temperature experiments
journal, June 1994


Synthesis and thermoelectric properties of Cu excess Cu 2 ZnSnSe 4 : Synthesis and thermoelectric properties of Cu excess Cu
journal, November 2013

  • Dong, Yongkwan; Wang, Hsin; Nolas, George S.
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 8, Issue 1
  • DOI: 10.1002/pssr.201308274

Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds
journal, April 2005


Structural effects on the lattice thermal conductivity of ternary antimony- and bismuth-containing chalcogenide semiconductors
journal, May 2010

  • Skoug, Eric J.; Cain, Jeffrey D.; Morelli, Donald T.
  • Applied Physics Letters, Vol. 96, Issue 18
  • DOI: 10.1063/1.3425886

Synthesis, Crystal Structure, and High Temperature Transport Properties of p -Type Cu 2 Zn 1– x Fe x SnSe 4
journal, November 2013

  • Dong, Yongkwan; Wang, Hsin; Nolas, George S.
  • Inorganic Chemistry, Vol. 52, Issue 24
  • DOI: 10.1021/ic402455x

Ionic conduction and thermal nature of synthetic Cu3BiS3.
journal, January 1998

  • Mizota, Tadato; Inoue, Atsushi; Yamada, Takao
  • Mineralogical Journal, Vol. 20, Issue 2
  • DOI: 10.2465/minerj.20.81