Three-dimensional localization of nanoscale battery reactions using soft X-ray tomography
Abstract
Battery function is determined by the efficiency and reversibility of the electrochemical phase transformations at solid electrodes. The microscopic tools available to study the chemical states of matter with the required spatial resolution and chemical specificity are intrinsically limited when studying complex architectures by their reliance on two-dimensional projections of thick material. Here in this paper, we report the development of soft X-ray ptychographic tomography, which resolves chemical states in three dimensions at 11 nm spatial resolution. We study an ensemble of nano-plates of lithium iron phosphate extracted from a battery electrode at 50% state of charge. Using a set of nanoscale tomograms, we quantify the electrochemical state and resolve phase boundaries throughout the volume of individual nanoparticles. These observations reveal multiple reaction points, intra-particle heterogeneity, and size effects that highlight the importance of multi-dimensional analytical tools in providing novel insight to the design of the next generation of high-performance devices.
- Authors:
-
[4];
[2];
[8];
[2];
[8];
[10];
[2]
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry; Chungnam National Univ., Daejeon (South Korea). Dept. of Materials Science and Engineering
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
- Univ. of Cambridge (United Kingdom). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Chemistry
- Univ. of Cambridge (United Kingdom). Dept. of Chemistry
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Engineering Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Computational Research Division
- Uppsala Univ. (Sweden). Dept. of Cell and Molecular Biology
- Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Research Foundation of Korea (NRF); USDOE Office of Science (SC), Advanced Scientific Computing Research (ASCR)
- OSTI Identifier:
- 1427169
- Alternate Identifier(s):
- OSTI ID: 1433136
- Grant/Contract Number:
- AC02-76SF00515; AC02-05CH11231; SC0012583
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Batteries; Imaging
Citation Formats
Yu, Young-Sang, Farmand, Maryam, Kim, Chunjoong, Liu, Yijin, Grey, Clare P., Strobridge, Fiona C., Tyliszczak, Tolek, Celestre, Rich, Denes, Peter, Joseph, John, Krishnan, Harinarayan, Maia, Filipe R. N. C., Kilcoyne, A. L. David, Marchesini, Stefano, Leite, Talita Perciano Costa, Warwick, Tony, Padmore, Howard, Cabana, Jordi, and Shapiro, David A. Three-dimensional localization of nanoscale battery reactions using soft X-ray tomography. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-03401-x.
Yu, Young-Sang, Farmand, Maryam, Kim, Chunjoong, Liu, Yijin, Grey, Clare P., Strobridge, Fiona C., Tyliszczak, Tolek, Celestre, Rich, Denes, Peter, Joseph, John, Krishnan, Harinarayan, Maia, Filipe R. N. C., Kilcoyne, A. L. David, Marchesini, Stefano, Leite, Talita Perciano Costa, Warwick, Tony, Padmore, Howard, Cabana, Jordi, & Shapiro, David A. Three-dimensional localization of nanoscale battery reactions using soft X-ray tomography. United States. https://doi.org/10.1038/s41467-018-03401-x
Yu, Young-Sang, Farmand, Maryam, Kim, Chunjoong, Liu, Yijin, Grey, Clare P., Strobridge, Fiona C., Tyliszczak, Tolek, Celestre, Rich, Denes, Peter, Joseph, John, Krishnan, Harinarayan, Maia, Filipe R. N. C., Kilcoyne, A. L. David, Marchesini, Stefano, Leite, Talita Perciano Costa, Warwick, Tony, Padmore, Howard, Cabana, Jordi, and Shapiro, David A. Fri .
"Three-dimensional localization of nanoscale battery reactions using soft X-ray tomography". United States. https://doi.org/10.1038/s41467-018-03401-x. https://www.osti.gov/servlets/purl/1427169.
@article{osti_1427169,
title = {Three-dimensional localization of nanoscale battery reactions using soft X-ray tomography},
author = {Yu, Young-Sang and Farmand, Maryam and Kim, Chunjoong and Liu, Yijin and Grey, Clare P. and Strobridge, Fiona C. and Tyliszczak, Tolek and Celestre, Rich and Denes, Peter and Joseph, John and Krishnan, Harinarayan and Maia, Filipe R. N. C. and Kilcoyne, A. L. David and Marchesini, Stefano and Leite, Talita Perciano Costa and Warwick, Tony and Padmore, Howard and Cabana, Jordi and Shapiro, David A.},
abstractNote = {Battery function is determined by the efficiency and reversibility of the electrochemical phase transformations at solid electrodes. The microscopic tools available to study the chemical states of matter with the required spatial resolution and chemical specificity are intrinsically limited when studying complex architectures by their reliance on two-dimensional projections of thick material. Here in this paper, we report the development of soft X-ray ptychographic tomography, which resolves chemical states in three dimensions at 11 nm spatial resolution. We study an ensemble of nano-plates of lithium iron phosphate extracted from a battery electrode at 50% state of charge. Using a set of nanoscale tomograms, we quantify the electrochemical state and resolve phase boundaries throughout the volume of individual nanoparticles. These observations reveal multiple reaction points, intra-particle heterogeneity, and size effects that highlight the importance of multi-dimensional analytical tools in providing novel insight to the design of the next generation of high-performance devices.},
doi = {10.1038/s41467-018-03401-x},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {Fri Mar 02 00:00:00 EST 2018},
month = {Fri Mar 02 00:00:00 EST 2018}
}
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Works referenced in this record:
Chemically sensitive structure-imaging with a scanning transmission electron microscope
journal, December 1988
- Pennycook, S. J.; Boatner, L. A.
- Nature, Vol. 336, Issue 6199
Atomic-resolution chemical analysis using a scanning transmission electron microscope
journal, November 1993
- Browning, N. D.; Chisholm, M. F.; Pennycook, S. J.
- Nature, Vol. 366, Issue 6451
Room-temperature miscibility gap in LixFePO4
journal, April 2006
- Yamada, Atsuo; Koizumi, Hiroshi; Nishimura, Shin-ichi
- Nature Materials, Vol. 5, Issue 5
Configurational Electronic Entropy and the Phase Diagram of Mixed-Valence Oxides: The Case of
journal, October 2006
- Zhou, Fei; Maxisch, Thomas; Ceder, Gerbrand
- Physical Review Letters, Vol. 97, Issue 15
Confirmation of the Domino-Cascade Model by LiFePO 4 /FePO 4 Precession Electron Diffraction
journal, October 2011
- Brunetti, G.; Robert, D.; Bayle-Guillemaud, P.
- Chemistry of Materials, Vol. 23, Issue 20
Lithium Batteries and Cathode Materials
journal, October 2004
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
Dichotomy in the Lithiation Pathway of Ellipsoidal and Platelet LiFePO 4 Particles Revealed through Nanoscale Operando State-of-Charge Imaging
journal, May 2015
- Li, Yiyang; Weker, Johanna Nelson; Gent, William E.
- Advanced Functional Materials, Vol. 25, Issue 24
Highly ordered staging structural interface between LiFePO4 and FePO4
journal, January 2012
- Suo, Liumin; Han, Wenze; Lu, Xia
- Physical Chemistry Chemical Physics, Vol. 14, Issue 16
Overview of olivines in lithium batteries for green transportation and energy storage
journal, January 2012
- Zaghib, K.; Mauger, A.; Julien, C. M.
- Journal of Solid State Electrochemistry, Vol. 16, Issue 3
Beyond crystallography: Diffractive imaging using coherent x-ray light sources
journal, April 2015
- Miao, J.; Ishikawa, T.; Robinson, I. K.
- Science, Vol. 348, Issue 6234
Coherency Strain and the Kinetics of Phase Separation in LiFePO 4 Nanoparticles
journal, February 2012
- Cogswell, Daniel A.; Bazant, Martin Z.
- ACS Nano, Vol. 6, Issue 3
Theory of Coherent Nucleation in Phase-Separating Nanoparticles
journal, May 2013
- Cogswell, Daniel A.; Bazant, Martin Z.
- Nano Letters, Vol. 13, Issue 7
Kinetics of non-equilibrium lithium incorporation in LiFePO4
journal, July 2011
- Malik, Rahul; Zhou, Fei; Ceder, G.
- Nature Materials, Vol. 10, Issue 8
Rate-Induced Solubility and Suppression of the First-Order Phase Transition in Olivine LiFePO 4
journal, April 2014
- Zhang, Xiaoyu; van Hulzen, Martijn; Singh, Deepak P.
- Nano Letters, Vol. 14, Issue 5
Large Impact of Particle Size on Insertion Reactions. A Case for Anatase Li x TiO 2
journal, April 2007
- Wagemaker, Marnix; Borghols, Wouter J. H.; Mulder, Fokko M.
- Journal of the American Chemical Society, Vol. 129, Issue 14
Relaxed averaged alternating reflections for diffraction imaging
journal, November 2004
- Luke, D. Russell
- Inverse Problems, Vol. 21, Issue 1
Chemical composition mapping with nanometre resolution by soft X-ray microscopy
journal, September 2014
- Shapiro, David A.; Yu, Young-Sang; Tyliszczak, Tolek
- Nature Photonics, Vol. 8, Issue 10
Study of the Li-insertion/extraction process in LiFePO4/FePO4
journal, February 2009
- Ramana, C. V.; Mauger, A.; Gendron, F.
- Journal of Power Sources, Vol. 187, Issue 2
Local Electronic Structure of Olivine Phases of Li x FePO 4
journal, May 2007
- Miao, Shu; Kocher, Michael; Rez, Peter
- The Journal of Physical Chemistry A, Vol. 111, Issue 20
The thermodynamic stability of intermediate solid solutions in LiFePO 4 nanoparticles
journal, January 2016
- Abdellahi, A.; Akyildiz, O.; Malik, R.
- Journal of Materials Chemistry A, Vol. 4, Issue 15
Nanoscale X-ray imaging
journal, December 2010
- Sakdinawat, Anne; Attwood, David
- Nature Photonics, Vol. 4, Issue 12, p. 840-848
Nanoscale Morphological and Chemical Changes of High Voltage Lithium–Manganese Rich NMC Composite Cathodes with Cycling
journal, July 2014
- Yang, Feifei; Liu, Yijin; Martha, Surendra K.
- Nano Letters, Vol. 14, Issue 8
Aging Mechanisms of LiFePO 4 // Graphite Cells Studied by XPS: Redox Reaction and Electrode/Electrolyte Interfaces
journal, January 2012
- Castro, L.; Dedryvère, R.; Ledeuil, J. -B.
- Journal of The Electrochemical Society, Vol. 159, Issue 4
Electronic structure of phospho-olivines LixFePO4 (x=0,1) from soft-x-ray-absorption and -emission spectroscopies
journal, November 2005
- Augustsson, A.; Zhuang, G. V.; Butorin, S. M.
- The Journal of Chemical Physics, Vol. 123, Issue 18
Three-dimensional chemical mapping by scanning transmission X-ray spectromicroscopy
journal, August 2007
- Johansson, Göran A.; Tyliszczak, Tolek; Mitchell, Gary E.
- Journal of Synchrotron Radiation, Vol. 14, Issue 5
Phase Transformation and Lithiation Effect on Electronic Structure of Li x FePO 4 : An In-Depth Study by Soft X-ray and Simulations
journal, August 2012
- Liu, Xiaosong; Liu, Jun; Qiao, Ruimin
- Journal of the American Chemical Society, Vol. 134, Issue 33
Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 114, Issue 23
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997
- Padhi, A. K.
- Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
Combined operando X-ray diffraction–electrochemical impedance spectroscopy detecting solid solution reactions of LiFePO4 in batteries
journal, September 2015
- Hess, Michael; Sasaki, Tsuyoshi; Villevieille, Claire
- Nature Communications, Vol. 6, Issue 1
The source of first-cycle capacity loss in LiFePO4
journal, July 2001
- Andersson, A. S.; Thomas, J. O.
- Journal of Power Sources, Vol. 97-98
The existence of a temperature-driven solid solution in LixFePO4 for 0 ≤ x ≤ 1
journal, February 2005
- Delacourt, Charles; Poizot, Philippe; Tarascon, Jean-Marie
- Nature Materials, Vol. 4, Issue 3
Three-dimensional imaging of chemical phase transformations at the nanoscale with full-field transmission X-ray microscopy
journal, July 2011
- Meirer, Florian; Cabana, Jordi; Liu, Yijin
- Journal of Synchrotron Radiation, Vol. 18, Issue 5
Algebraic Reconstruction Techniques (ART) for three-dimensional electron microscopy and X-ray photography
journal, December 1970
- Gordon, Richard; Bender, Robert; Herman, Gabor T.
- Journal of Theoretical Biology, Vol. 29, Issue 3
Dynamic Solubility Limits in Nanosized Olivine LiFePO 4
journal, July 2011
- Wagemaker, Marnix; Singh, Deepak P.; Borghols, Wouter J. H.
- Journal of the American Chemical Society, Vol. 133, Issue 26
Direct Observation of a Metastable Crystal Phase of Li x FePO 4 under Electrochemical Phase Transition
journal, April 2013
- Orikasa, Yuki; Maeda, Takehiro; Koyama, Yukinori
- Journal of the American Chemical Society, Vol. 135, Issue 15
Nanoscale elemental sensitivity study of Nd 2 Fe 14 B using absorption correlation tomography : Nanoscale Elemental Sensitivity Study of N
journal, August 2013
- Kao, Thomas L.; Shi, Crystal Y.; Wang, Junyue
- Microscopy Research and Technique, Vol. 76, Issue 11
Visualization of Charge Distribution in a Lithium Battery Electrode
journal, June 2010
- Liu, Jun; Kunz, Martin; Chen, Kai
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
3D electron microscopy in the physical sciences: the development of Z-contrast and EFTEM tomography
journal, September 2003
- Midgley, P. A.; Weyland, M.
- Ultramicroscopy, Vol. 96, Issue 3-4
Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model
journal, July 2008
- Delmas, C.; Maccario, M.; Croguennec, L.
- Nature Materials, Vol. 7, Issue 8
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles
journal, August 2016
- Lim, Jongwoo; Li, Yiyang; Alsem, Daan Hein
- Science, Vol. 353, Issue 6299
Dependence on Crystal Size of the Nanoscale Chemical Phase Distribution and Fracture in Li x FePO 4
journal, June 2015
- Yu, Young-Sang; Kim, Chunjoong; Shapiro, David A.
- Nano Letters, Vol. 15, Issue 7
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
journal, June 2014
- Liu, H.; Strobridge, F. C.; Borkiewicz, O. J.
- Science, Vol. 344, Issue 6191
Intercalation Pathway in Many-Particle LiFePO 4 Electrode Revealed by Nanoscale State-of-Charge Mapping
journal, February 2013
- Chueh, William C.; El Gabaly, Farid; Sugar, Joshua D.
- Nano Letters, Vol. 13, Issue 3
Crystal Orientation Tuning of LiFePO 4 Nanoplates for High Rate Lithium Battery Cathode Materials
journal, October 2012
- Wang, Li; He, Xiangming; Sun, Wenting
- Nano Letters, Vol. 12, Issue 11
The thermodynamic origin of hysteresis in insertion batteries
journal, April 2010
- Dreyer, Wolfgang; Jamnik, Janko; Guhlke, Clemens
- Nature Materials, Vol. 9, Issue 5
Soft X-ray microscopy at a spatial resolution better than 15 nm
journal, June 2005
- Chao, Weilun; Harteneck, Bruce D.; Liddle, J. Alexander
- Nature, Vol. 435, Issue 7046
Study of the LiFePO 4 /FePO 4 Two-Phase System by High-Resolution Electron Energy Loss Spectroscopy
journal, November 2006
- Laffont, L.; Delacourt, C.; Gibot, P.
- Chemistry of Materials, Vol. 18, Issue 23
Sub-ångstrom resolution using aberration corrected electron optics
journal, August 2002
- Batson, P. E.; Dellby, N.; Krivanek, O. L.
- Nature, Vol. 418, Issue 6898
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes
journal, September 2014
- Li, Yiyang; El Gabaly, Farid; Ferguson, Todd R.
- Nature Materials, Vol. 13, Issue 12
Miscibility Gap Closure, Interface Morphology, and Phase Microstructure of 3D Li x FePO 4 Nanoparticles from Surface Wetting and Coherency Strain
journal, September 2015
- Welland, Michael J.; Karpeyev, Dmitry; O’Connor, Devin T.
- ACS Nano, Vol. 9, Issue 10
Direct view on the phase evolution in individual LiFePO4 nanoparticles during Li-ion battery cycling
journal, September 2015
- Zhang, Xiaoyu; van Hulzen, Martijn; Singh, Deepak P.
- Nature Communications, Vol. 6, Issue 1
Lithium Batteries and Cathode Materials
journal, December 2004
- Whittingham, M. Stanley
- ChemInform, Vol. 35, Issue 50
Local Electronic Structure of Olivine Phases of LixFePO4.
journal, August 2007
- Miao, Shu; Kocher, Michael; Rez, Peter
- ChemInform, Vol. 38, Issue 33
Combined operando X-ray diffraction–electrochemical impedance spectroscopy detecting solid solution reactions of LiFePO4 in batteries
text, January 2015
- Hess, Michael; Sasaki, Tsuyoshi; Villevieille, Claire
- ETH Zurich
Relaxed averaged alternating reflections for diffraction imaging
journal, August 2008
- Luke, R.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue a1
Relaxed Averaged Alternating Reflections for Diffraction Imaging
text, January 2004
- Luke, D. Russell
- arXiv
Dichotomy in the Lithiation Pathway of Ellipsoidal and Platelet LiFePO 4 Particles Revealed through Nanoscale Operando State-of-Charge Imaging
journal, May 2015
- Li, Yiyang; Weker, Johanna Nelson; Gent, William E.
- Advanced Functional Materials, Vol. 25, Issue 24
Lithium Batteries and Cathode Materials
journal, December 2004
- Whittingham, M. Stanley
- ChemInform, Vol. 35, Issue 50
Nanoscale elemental sensitivity study of Nd 2 Fe 14 B using absorption correlation tomography : Nanoscale Elemental Sensitivity Study of N
journal, August 2013
- Kao, Thomas L.; Shi, Crystal Y.; Wang, Junyue
- Microscopy Research and Technique, Vol. 76, Issue 11
Overview of olivines in lithium batteries for green transportation and energy storage
journal, January 2012
- Zaghib, K.; Mauger, A.; Julien, C. M.
- Journal of Solid State Electrochemistry, Vol. 16, Issue 3
Algebraic Reconstruction Techniques (ART) for three-dimensional electron microscopy and X-ray photography
journal, December 1970
- Gordon, Richard; Bender, Robert; Herman, Gabor T.
- Journal of Theoretical Biology, Vol. 29, Issue 3
Miscibility Gap Closure, Interface Morphology, and Phase Microstructure of 3D Li x FePO 4 Nanoparticles from Surface Wetting and Coherency Strain
journal, September 2015
- Welland, Michael J.; Karpeyev, Dmitry; O’Connor, Devin T.
- ACS Nano, Vol. 9, Issue 10
Study of the LiFePO 4 /FePO 4 Two-Phase System by High-Resolution Electron Energy Loss Spectroscopy
journal, November 2006
- Laffont, L.; Delacourt, C.; Gibot, P.
- Chemistry of Materials, Vol. 18, Issue 23
Confirmation of the Domino-Cascade Model by LiFePO 4 /FePO 4 Precession Electron Diffraction
journal, October 2011
- Brunetti, G.; Robert, D.; Bayle-Guillemaud, P.
- Chemistry of Materials, Vol. 23, Issue 20
Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 114, Issue 23
Large Impact of Particle Size on Insertion Reactions. A Case for Anatase Li x TiO 2
journal, April 2007
- Wagemaker, Marnix; Borghols, Wouter J. H.; Mulder, Fokko M.
- Journal of the American Chemical Society, Vol. 129, Issue 14
Phase Transformation and Lithiation Effect on Electronic Structure of Li x FePO 4 : An In-Depth Study by Soft X-ray and Simulations
journal, August 2012
- Liu, Xiaosong; Liu, Jun; Qiao, Ruimin
- Journal of the American Chemical Society, Vol. 134, Issue 33
Local Electronic Structure of Olivine Phases of Li x FePO 4
journal, May 2007
- Miao, Shu; Kocher, Michael; Rez, Peter
- The Journal of Physical Chemistry A, Vol. 111, Issue 20
Visualization of Charge Distribution in a Lithium Battery Electrode
journal, June 2010
- Liu, Jun; Kunz, Martin; Chen, Kai
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
Crystal Orientation Tuning of LiFePO 4 Nanoplates for High Rate Lithium Battery Cathode Materials
journal, October 2012
- Wang, Li; He, Xiangming; Sun, Wenting
- Nano Letters, Vol. 12, Issue 11
Rate-Induced Solubility and Suppression of the First-Order Phase Transition in Olivine LiFePO 4
journal, April 2014
- Zhang, Xiaoyu; van Hulzen, Martijn; Singh, Deepak P.
- Nano Letters, Vol. 14, Issue 5
Nanoscale Morphological and Chemical Changes of High Voltage Lithium–Manganese Rich NMC Composite Cathodes with Cycling
journal, July 2014
- Yang, Feifei; Liu, Yijin; Martha, Surendra K.
- Nano Letters, Vol. 14, Issue 8
Coherency Strain and the Kinetics of Phase Separation in LiFePO 4 Nanoparticles
journal, February 2012
- Cogswell, Daniel A.; Bazant, Martin Z.
- ACS Nano, Vol. 6, Issue 3
Chemically sensitive structure-imaging with a scanning transmission electron microscope
journal, December 1988
- Pennycook, S. J.; Boatner, L. A.
- Nature, Vol. 336, Issue 6199
Atomic-resolution chemical analysis using a scanning transmission electron microscope
journal, November 1993
- Browning, N. D.; Chisholm, M. F.; Pennycook, S. J.
- Nature, Vol. 366, Issue 6451
Sub-ångstrom resolution using aberration corrected electron optics
journal, August 2002
- Batson, P. E.; Dellby, N.; Krivanek, O. L.
- Nature, Vol. 418, Issue 6898
Erratum: corrigendum: Sub-ångstrom resolution using aberration corrected electron optics
journal, September 2002
- Batson, P. E.; Dellby, N.; Krivanek, O. L.
- Nature, Vol. 419, Issue 6902
Soft X-ray microscopy at a spatial resolution better than 15 nm
journal, June 2005
- Chao, Weilun; Harteneck, Bruce D.; Liddle, J. Alexander
- Nature, Vol. 435, Issue 7046
Direct view on the phase evolution in individual LiFePO4 nanoparticles during Li-ion battery cycling
journal, September 2015
- Zhang, Xiaoyu; van Hulzen, Martijn; Singh, Deepak P.
- Nature Communications, Vol. 6, Issue 1
The existence of a temperature-driven solid solution in LixFePO4 for 0 ≤ x ≤ 1
journal, February 2005
- Delacourt, Charles; Poizot, Philippe; Tarascon, Jean-Marie
- Nature Materials, Vol. 4, Issue 3
Room-temperature miscibility gap in LixFePO4
journal, April 2006
- Yamada, Atsuo; Koizumi, Hiroshi; Nishimura, Shin-ichi
- Nature Materials, Vol. 5, Issue 5
Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model
journal, July 2008
- Delmas, C.; Maccario, M.; Croguennec, L.
- Nature Materials, Vol. 7, Issue 8
The thermodynamic origin of hysteresis in insertion batteries
journal, April 2010
- Dreyer, Wolfgang; Jamnik, Janko; Guhlke, Clemens
- Nature Materials, Vol. 9, Issue 5
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes
journal, September 2014
- Li, Yiyang; El Gabaly, Farid; Ferguson, Todd R.
- Nature Materials, Vol. 13, Issue 12
Nanoscale X-ray imaging
journal, December 2010
- Sakdinawat, Anne; Attwood, David
- Nature Photonics, Vol. 4, Issue 12, p. 840-848
Chemical composition mapping with nanometre resolution by soft X-ray microscopy
journal, September 2014
- Shapiro, David A.; Yu, Young-Sang; Tyliszczak, Tolek
- Nature Photonics, Vol. 8, Issue 10
Highly ordered staging structural interface between LiFePO4 and FePO4
journal, January 2012
- Suo, Liumin; Han, Wenze; Lu, Xia
- Physical Chemistry Chemical Physics, Vol. 14, Issue 16
Electronic structure of phospho-olivines LixFePO4 (x=0,1) from soft-x-ray-absorption and -emission spectroscopies
journal, November 2005
- Augustsson, A.; Zhuang, G. V.; Butorin, S. M.
- The Journal of Chemical Physics, Vol. 123, Issue 18
Relaxed averaged alternating reflections for diffraction imaging
journal, November 2004
- Luke, D. Russell
- Inverse Problems, Vol. 21, Issue 1
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
journal, June 2014
- Liu, H.; Strobridge, F. C.; Borkiewicz, O. J.
- Science, Vol. 344, Issue 6191
Beyond crystallography: Diffractive imaging using coherent x-ray light sources
journal, April 2015
- Miao, J.; Ishikawa, T.; Robinson, I. K.
- Science, Vol. 348, Issue 6234
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles
journal, August 2016
- Lim, Jongwoo; Li, Yiyang; Alsem, Daan Hein
- Science, Vol. 353, Issue 6299
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997
- Padhi, A. K.
- Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
Theory of Nucleation in Phase-separating Nanoparticles
text, January 2013
- Cogswell, Daniel A.; Bazant, Martin Z.
- arXiv
Configurational electronic entropy and the phase diagram of mixed-valence oxides: the case of Li$_x$FePO$_4$
text, January 2006
- Zhou, Fei; Maxisch, Thomas; Ceder, Gerbrand
- arXiv
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- Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
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- Xu, Zhengrui; Jiang, Zhisen; Kuai, Chunguang
- Nature Communications, Vol. 11, Issue 1
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- Scientific Reports, Vol. 9, Issue 1
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journal, March 2019
- Shi, Xiaowen; Burdet, Nicolas; Chen, Bo
- Applied Physics Reviews, Vol. 6, Issue 1
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journal, November 2019
- Nathanael, Jan; Wünsche, Martin; Fuchs, Silvio
- Review of Scientific Instruments, Vol. 90, Issue 11
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journal, January 2019
- Ma, Limei; Zhang, Xiangzhi; Xu, Zijian
- Optics Express, Vol. 27, Issue 5
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text, January 2019
- Chang, Huibin; Enfedaque, Pablo; Zhang, Jie
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Coupled ptychography and tomography algorithm improves reconstruction of experimental data
text, January 2019
- Kahnt, Maik; Becher, Johannes; Brückner, Dennis
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Advanced denoising for X-ray ptychography
journal, January 2019
- Chang, Huibin; Enfedaque, Pablo; Zhang, Jie
- Optics Express, Vol. 27, Issue 8
X-ray microscopy
journal, July 1965
- Cosslett, V. E.
- Reports on Progress in Physics, Vol. 28, Issue 1
Charge distribution guided by grain crystallographic orientations in polycrystalline battery materials
journal, January 2020
- Xu, Zhengrui; Jiang, Zhisen; Kuai, Chunguang
- Nature Communications, Vol. 11, Issue 1
3D Analysis of Ordered Porous Polymeric Particles using Complementary Electron Microscopy Methods
journal, September 2019
- Alvarez, Juan; Saudino, Giovanni; Musteata, Valentina
- Scientific Reports, Vol. 9, Issue 1