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Title: Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write

Abstract

In controlling the thermal properties of the surrounding environment, we provide insight into the underlying mechanisms driving the widely used laser direct write method for additive manufacturing. In this study, we find that the onset of silver nitrate reduction for the formation of direct write structures directly corresponds to the calculated steady-state temperature rises associated with both continuous wave and high-repetition rate, ultrafast pulsed laser systems. Furthermore, varying the geometry of the heat affected zone, which is controllable based on in-plane thermal diffusion in the substrate, and laser power, allows for control of the written geometries without any prior substrate preparation. In conclusion, these findings allow for the advance of rapid manufacturing of micro- and nanoscale structures with minimal material constraints through consideration of the laser-controllable thermal transport in ionic liquid/substrate media.

Authors:
 [1];  [2]; ORCiD logo [2]; ORCiD logo [1];  [3];  [4]
+ Show Author Affiliations
  1. Univ. of Virginia, Charlottesville, VA (United States). Department of Materials Science and Engineering
  2. Univ. of Virginia, Charlottesville, VA (United States). Department of Mechanical and Aerospace Engineering
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Materials Laboratory
  4. Univ. of Virginia, Charlottesville, VA (United States). Department of Materials Science and Engineering, Department of Mechanical and Aerospace Engineering and Department of Physics
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1426810
Report Number(s):
SAND-2018-1917J
Journal ID: ISSN 0003-6951; 660850; TRN: US1802575
Grant/Contract Number:  
AC04-94AL85000; NA0003525
Resource Type:
Accepted Manuscript
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 112; Journal Issue: 5; Journal ID: ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Tomko, John A., Olson, David H., Braun, Jeffrey L., Kelliher, Andrew P., Kaehr, Bryan, and Hopkins, Patrick E.. Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write. United States: N. p., 2018. Web. doi:10.1063/1.5016073.
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Tomko, John A., Olson, David H., Braun, Jeffrey L., Kelliher, Andrew P., Kaehr, Bryan, & Hopkins, Patrick E.. Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write. United States. https://doi.org/10.1063/1.5016073
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Tomko, John A., Olson, David H., Braun, Jeffrey L., Kelliher, Andrew P., Kaehr, Bryan, and Hopkins, Patrick E.. Tue . "Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write". United States. https://doi.org/10.1063/1.5016073. https://www.osti.gov/servlets/purl/1426810.
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@article{osti_1426810,
title = {Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write},
author = {Tomko, John A. and Olson, David H. and Braun, Jeffrey L. and Kelliher, Andrew P. and Kaehr, Bryan and Hopkins, Patrick E.},
abstractNote = {In controlling the thermal properties of the surrounding environment, we provide insight into the underlying mechanisms driving the widely used laser direct write method for additive manufacturing. In this study, we find that the onset of silver nitrate reduction for the formation of direct write structures directly corresponds to the calculated steady-state temperature rises associated with both continuous wave and high-repetition rate, ultrafast pulsed laser systems. Furthermore, varying the geometry of the heat affected zone, which is controllable based on in-plane thermal diffusion in the substrate, and laser power, allows for control of the written geometries without any prior substrate preparation. In conclusion, these findings allow for the advance of rapid manufacturing of micro- and nanoscale structures with minimal material constraints through consideration of the laser-controllable thermal transport in ionic liquid/substrate media.},
doi = {10.1063/1.5016073},
journal = {Applied Physics Letters},
number = 5,
volume = 112,
place = {United States},
year = {2018},
month = {1}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1063/1.5016073
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Cited by: 3 works
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Figures / Tables:

Figure 1 Figure 1: Measured line-width for Ag microstructures at an absorbed power density of ~350 MW m-2 for substrates of varying substrate thermal conducitivity; these were synthesized with a CW 532 nm beam.
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Works referenced in this record:

Highly conductive lines by plasma-induced conversion of inkjet-printed silver nitrate traces
journal, January 2013

  • Bromberg, Vadim; Ma, Siyuan; Egitto, Frank D.
  • Journal of Materials Chemistry C, Vol. 1, Issue 41
  • DOI: 10.1039/c3tc31361a

Direct laser writing of three-dimensional photonic-crystal templates for telecommunications
journal, June 2004

  • Deubel, Markus; von Freymann, Georg; Wegener, Martin
  • Nature Materials, Vol. 3, Issue 7
  • DOI: 10.1038/nmat1155

Effect of Surfactants and Polymers on Stability and Antibacterial Activity of Silver Nanoparticles (NPs)
journal, April 2008

  • Kvítek, Libor; Panáček, Aleš; Soukupová, Jana
  • The Journal of Physical Chemistry C, Vol. 112, Issue 15
  • DOI: 10.1021/jp711616v

Cavitation bubble dynamics and nanoparticle size distributions in laser ablation in liquids
journal, June 2017

  • Tomko, J.; O’Malley, S. M.; Trout, Cory
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 522
  • DOI: 10.1016/j.colsurfa.2017.03.030

Application of Silver Nitrate Solution and Inkjet Printing in the Fabrication of Microstructural Patterns on Glass Substrates
journal, February 2012

  • Chang, Hung-Ju; Tsai, Ming-Hsiu; Hwang, Weng-Sing
  • The Journal of Physical Chemistry C, Vol. 116, Issue 7
  • DOI: 10.1021/jp209523w

Wet Chemical Synthesis of Monodisperse Colloidal Silver Nanocrystals Using Digestive Ripening
journal, February 2010

  • Shankar, Ravi; Wu, Bin Bin; Bigioni, Terry P.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 38
  • DOI: 10.1021/jp911316e

Chemical Synthesis and Structural Characterization of Highly Disordered Ni Colloidal Nanoparticles
journal, May 2008

  • Winnischofer, Herbert; Rocha, Tulio C. R.; Nunes, Wallace C.
  • ACS Nano, Vol. 2, Issue 6
  • DOI: 10.1021/nn700152w

Recent advances in 3D printing of biomaterials
journal, March 2015

Irradiation with visible light enhances the antibacterial toxicity of silver nanoparticles produced by laser ablation
journal, March 2016

Femtosecond laser direct writing of metallic microstructures by photoreduction of silver nitrate in a polymer matrix
journal, January 2008

Analysis of heat flow in layered structures for time-domain thermoreflectance
journal, December 2004

  • Cahill, David G.
  • Review of Scientific Instruments, Vol. 75, Issue 12
  • DOI: 10.1063/1.1819431

High-resolution insights into the early stages of silver nucleation and growth
journal, January 2015

  • Völkle, Cornelia M.; Gebauer, Denis; Cölfen, Helmut
  • Faraday Discussions, Vol. 179
  • DOI: 10.1039/C4FD00269E

Laser direct writing of micro- and nano-scale medical devices
journal, May 2010

  • Gittard, Shaun D.; Narayan, Roger J.
  • Expert Review of Medical Devices, Vol. 7, Issue 3
  • DOI: 10.1586/erd.10.14

Direct selective laser sintering of metals
journal, March 1995

Pulse accumulation, radial heat conduction, and anisotropic thermal conductivity in pump-probe transient thermoreflectance
journal, November 2008

  • Schmidt, Aaron J.; Chen, Xiaoyuan; Chen, Gang
  • Review of Scientific Instruments, Vol. 79, Issue 11
  • DOI: 10.1063/1.3006335

Laser powder-bed fusion additive manufacturing: Physics of complex melt flow and formation mechanisms of pores, spatter, and denudation zones
journal, April 2016

Laser Direct Writing of Silver Nanowire with Amino Acids-Assisted Multiphoton Photoreduction
journal, November 2016

  • Ren, Xue-Liang; Zheng, Mei-Ling; Jin, Feng
  • The Journal of Physical Chemistry C, Vol. 120, Issue 46
  • DOI: 10.1021/acs.jpcc.6b08395

Laser-Direct Writing of Silver Metal Electrodes on Transparent Flexible Substrates with High-Bonding Strength
journal, September 2016

  • Zhou, Weiping; Bai, Shi; Ma, Ying
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 37
  • DOI: 10.1021/acsami.6b07696

Laser Direct Write Synthesis of Lead Halide Perovskites
journal, September 2016

  • Chou, Stanley S.; Swartzentruber, Brian S.; Janish, Matthew T.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 19
  • DOI: 10.1021/acs.jpclett.6b01557

Upper limit to the thermal penetration depth during modulated heating of multilayer thin films with pulsed and continuous wave lasers: A numerical study
journal, May 2017

  • Braun, Jeffrey L.; Hopkins, Patrick E.
  • Journal of Applied Physics, Vol. 121, Issue 17
  • DOI: 10.1063/1.4982915

Dynamics of silver nanoparticle formation and agglomeration inside the cavitation bubble after pulsed laser ablation in liquid
journal, January 2013

  • Wagener, Philipp; Ibrahimkutty, Shyjumon; Menzel, Andreas
  • Phys. Chem. Chem. Phys., Vol. 15, Issue 9
  • DOI: 10.1039/C2CP42592K

Direct writing of Ag-lines on Mn-Zn ferrite by laser-induced thermal decomposition by CH3COOAg
journal, January 1992

  • Lu, Y. -F.; Takai, M.; Nagatomo, S.
  • Applied Physics A Solids and Surfaces, Vol. 54, Issue 1
  • DOI: 10.1007/BF00348130

Laser Direct-Write Techniques for Printing of Complex Materials
journal, January 2007

  • Arnold, Craig B.; Serra, Pere; Piqué, Alberto
  • MRS Bulletin, Vol. 32, Issue 1
  • DOI: 10.1557/mrs2007.11

Accessing Ultrashort Reaction Times in Particle Formation with SAXS Experiments: ZnS Precipitation on the Microsecond Time Scale
journal, May 2010

  • Schmidt, Wolfgang; Bussian, Patrick; Lindén, Mika
  • Journal of the American Chemical Society, Vol. 132, Issue 19
  • DOI: 10.1021/ja101519z

Colloidal nanoparticle clusters: functional materials by design
journal, January 2012

  • Lu, Zhenda; Yin, Yadong
  • Chemical Society Reviews, Vol. 41, Issue 21
  • DOI: 10.1039/c2cs35197h

Using Laser-Induced Thermal Voxels to Pattern Diverse Materials at the Solid–Liquid Interface
journal, August 2016

  • Zarzar, Lauren D.; Swartzentruber, B. S.; Donovan, Brian F.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 33
  • DOI: 10.1021/acsami.6b06625

Femtosecond laser-induced two-photon polymerization of inorganic–organic hybrid materials for applications in photonics
journal, January 2003

[INVITED] Laser-induced forward transfer: A high resolution additive manufacturing technology
journal, April 2016

Wet-Chemical Synthesis of Doped Colloidal Nanoparticles:  YVO 4 :Ln (Ln = Eu, Sm, Dy)
journal, December 1998

  • Riwotzki, K.; Haase, M.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 50
  • DOI: 10.1021/jp982293c

Laser-assisted direct ink writing of planar and 3D metal architectures
journal, May 2016

  • Skylar-Scott, Mark A.; Gunasekaran, Suman; Lewis, Jennifer A.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 22
  • DOI: 10.1073/pnas.1525131113

Multiphoton laser direct writing of two-dimensional silver structures
journal, January 2005

  • Baldacchini, Tommaso; Pons, Anne-Cécile; Pons, Josefina
  • Optics Express, Vol. 13, Issue 4
  • DOI: 10.1364/OPEX.13.001275

Colloidal Chemical Synthesis and Formation Kinetics of Uniformly Sized Nanocrystals of Metals, Oxides, and Chalcogenides
journal, December 2008

  • Kwon, Soon Gu; Hyeon, Taeghwan
  • Accounts of Chemical Research, Vol. 41, Issue 12
  • DOI: 10.1021/ar8000537

A novel laser transfer process for direct writing of electronic and sensor materials
journal, December 1999

  • Piqué, A.; Chrisey, D. B.; Auyeung, R. C. Y.
  • Applied Physics A: Materials Science & Processing, Vol. 69, Issue 7
  • DOI: 10.1007/s003390051400

Femtosecond laser direct writing of monocrystalline hexagonal silver prisms
journal, October 2014

  • Vora, Kevin; Kang, SeungYeon; Moebius, Michael
  • Applied Physics Letters, Vol. 105, Issue 14
  • DOI: 10.1063/1.4897545

Direct-write of sensor devices by a laser forward transfer technique
conference, June 2002

  • Pique, Alberto; Weir, David W.; Wu, Peter K.
  • High-Power Lasers and Applications, SPIE Proceedings
  • DOI: 10.1117/12.470642

Size-Selective Formation of Hexagonal Silver Nanoprisms in Silver Citrate Solution by Monochromatic-Visible-Light Irradiation
journal, July 2012

  • Tanimoto, Hisanori; Ohmura, Satoru; Maeda, Yoshitaka
  • The Journal of Physical Chemistry C, Vol. 116, Issue 29
  • DOI: 10.1021/jp304504c

Direct laser writing: Principles and materials for scaffold 3D printing
journal, January 2015

  • Selimis, Alexandros; Mironov, Vladimir; Farsari, Maria
  • Microelectronic Engineering, Vol. 132
  • DOI: 10.1016/j.mee.2014.10.001

Ultrafast and steady-state laser heating effects on electron relaxation and phonon coupling mechanisms in thin gold films
journal, November 2013

  • Hopkins, Patrick E.; Duda, John C.; Kaehr, Bryan
  • Applied Physics Letters, Vol. 103, Issue 21
  • DOI: 10.1063/1.4833415

Preparation of functional DNA microarrays through laser-induced forward transfer
journal, August 2004

  • Serra, P.; Colina, M.; Fernández-Pradas, J. M.
  • Applied Physics Letters, Vol. 85, Issue 9
  • DOI: 10.1063/1.1787614

Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication
journal, March 1999

  • Cumpston, Brian H.; Ananthavel, Sundaravel P.; Barlow, Stephen
  • Nature, Vol. 398, Issue 6722, p. 51-54
  • DOI: 10.1038/17989

Irradiation with visible light enhances the antibacterial toxicity of silver nanoparticles produced by laser ablation
text, January 2016

  • Tan, Yuying; Griepenburg, Julianne C.; Ratti, Matthew
  • Rutgers University
  • DOI: 10.7282/t3c53nxb
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    Works referencing / citing this record:

    Nanostructure and Mechanism of Metal Deposition by a Laser‐Induced Photothermal Reaction
    journal, May 2019

    • Greenberg, Ehud; Armon, Nina; Kapon, Omree
    • Advanced Materials Interfaces, Vol. 6, Issue 14
    • DOI: 10.1002/admi.201900541
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