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Title: Effects of crystallographic and geometric orientation on ion beam sputtering of gold nanorods

Abstract

Nanostructures may be exposed to irradiation during their manufacture, their engineering and whilst in-service. The consequences of such bombardment can be vastly different from those seen in the bulk. In this paper, we combine transmission electron microscopy with in situ ion irradiation with complementary computer modelling techniques to explore the physics governing the effects of 1.7 MeV Au ions on gold nanorods. Phenomena surrounding the sputtering and associated morphological changes caused by the ion irradiation have been explored. In both the experiments and the simulations, large variations in the sputter yields from individual nanorods were observed. These sputter yields have been shown to correlate with the strength of channelling directions close to the direction in which the ion beam was incident. Finally, craters decorated by ejecta blankets were found to form due to cluster emission thus explaining the high sputter yields.

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [3];  [4]; ORCiD logo [1]; ORCiD logo [4];  [1];  [4]
  1. Univ. of Huddersfield, Queensgate, Huddersfield (United Kingdom)
  2. Univ. of Leeds, Leeds (United Kingdom)
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  4. Univ. of Helsinki (Finland). Helsinki Inst. of Physics, Dept. of Physics
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Laboratories, null
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1426806
Report Number(s):
SAND-2018-1671J
Journal ID: ISSN 2045-2322; 660697
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Hinks, J. A., Hibberd, F., Hattar, K., Ilinov, A., Bufford, D. C., Djurabekova, F., Greaves, G., Kuronen, A., Donnelly, S. E., and Nordlund, K. Effects of crystallographic and geometric orientation on ion beam sputtering of gold nanorods. United States: N. p., 2018. Web. doi:10.1038/s41598-017-17424-9.
Hinks, J. A., Hibberd, F., Hattar, K., Ilinov, A., Bufford, D. C., Djurabekova, F., Greaves, G., Kuronen, A., Donnelly, S. E., & Nordlund, K. Effects of crystallographic and geometric orientation on ion beam sputtering of gold nanorods. United States. doi:10.1038/s41598-017-17424-9.
Hinks, J. A., Hibberd, F., Hattar, K., Ilinov, A., Bufford, D. C., Djurabekova, F., Greaves, G., Kuronen, A., Donnelly, S. E., and Nordlund, K. Thu . "Effects of crystallographic and geometric orientation on ion beam sputtering of gold nanorods". United States. doi:10.1038/s41598-017-17424-9. https://www.osti.gov/servlets/purl/1426806.
@article{osti_1426806,
title = {Effects of crystallographic and geometric orientation on ion beam sputtering of gold nanorods},
author = {Hinks, J. A. and Hibberd, F. and Hattar, K. and Ilinov, A. and Bufford, D. C. and Djurabekova, F. and Greaves, G. and Kuronen, A. and Donnelly, S. E. and Nordlund, K.},
abstractNote = {Nanostructures may be exposed to irradiation during their manufacture, their engineering and whilst in-service. The consequences of such bombardment can be vastly different from those seen in the bulk. In this paper, we combine transmission electron microscopy with in situ ion irradiation with complementary computer modelling techniques to explore the physics governing the effects of 1.7 MeV Au ions on gold nanorods. Phenomena surrounding the sputtering and associated morphological changes caused by the ion irradiation have been explored. In both the experiments and the simulations, large variations in the sputter yields from individual nanorods were observed. These sputter yields have been shown to correlate with the strength of channelling directions close to the direction in which the ion beam was incident. Finally, craters decorated by ejecta blankets were found to form due to cluster emission thus explaining the high sputter yields.},
doi = {10.1038/s41598-017-17424-9},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {2018},
month = {1}
}

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