Simple size-controlled synthesis of Au nanoparticles and their size-dependent catalytic activity
Abstract
The controlled preparation of Au nanoparticles (NPs) in the size range of 6 to 22 nm is explored in this study. The Au NPs were prepared by the reduction of tetrachloroauric acid using maltose in the presence of nonionic surfactant Tween 80 at various concentrations to control the size of the resulting Au NPs. With increasing concentration of Tween 80 a decrease in the size of produced Au NPs was observed, along with a significant decrease in their size distribution. The size-dependent catalytic activity of the synthesized Au NPs was tested in the reduction of 4-nitrophenol with sodium borohydride, resulting in increasing catalytic activity with decreasing size of the prepared nanoparticles. Eley-Rideal catalytic mechanism emerges as the more probable, in contrary to the Langmuir-Hinshelwood mechanism reported for other noble metal nanocatalysts.
- Authors:
-
[1];
[1]
- Palacky University, Olomouc (Czech Republic). Department of Physical Chemistry, Regional Centre of Advanced Technologies and Materials, Faculty of Scienc
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Univ. of Chicago, IL (United States). Institute for Molecular Engineering
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1426503
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; Heterogeneous catalysts; Nanoparticles
Citation Formats
Suchomel, Petr, Kvitek, Libor, Prucek, Robert, Panacek, Ales, Halder, Avik, Vajda, Stefan, and Zboril, Radek. Simple size-controlled synthesis of Au nanoparticles and their size-dependent catalytic activity. United States: N. p., 2018.
Web. doi:10.1038/s41598-018-22976-5.
Suchomel, Petr, Kvitek, Libor, Prucek, Robert, Panacek, Ales, Halder, Avik, Vajda, Stefan, & Zboril, Radek. Simple size-controlled synthesis of Au nanoparticles and their size-dependent catalytic activity. United States. https://doi.org/10.1038/s41598-018-22976-5
Suchomel, Petr, Kvitek, Libor, Prucek, Robert, Panacek, Ales, Halder, Avik, Vajda, Stefan, and Zboril, Radek. Thu .
"Simple size-controlled synthesis of Au nanoparticles and their size-dependent catalytic activity". United States. https://doi.org/10.1038/s41598-018-22976-5. https://www.osti.gov/servlets/purl/1426503.
@article{osti_1426503,
title = {Simple size-controlled synthesis of Au nanoparticles and their size-dependent catalytic activity},
author = {Suchomel, Petr and Kvitek, Libor and Prucek, Robert and Panacek, Ales and Halder, Avik and Vajda, Stefan and Zboril, Radek},
abstractNote = {The controlled preparation of Au nanoparticles (NPs) in the size range of 6 to 22 nm is explored in this study. The Au NPs were prepared by the reduction of tetrachloroauric acid using maltose in the presence of nonionic surfactant Tween 80 at various concentrations to control the size of the resulting Au NPs. With increasing concentration of Tween 80 a decrease in the size of produced Au NPs was observed, along with a significant decrease in their size distribution. The size-dependent catalytic activity of the synthesized Au NPs was tested in the reduction of 4-nitrophenol with sodium borohydride, resulting in increasing catalytic activity with decreasing size of the prepared nanoparticles. Eley-Rideal catalytic mechanism emerges as the more probable, in contrary to the Langmuir-Hinshelwood mechanism reported for other noble metal nanocatalysts.},
doi = {10.1038/s41598-018-22976-5},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {Thu Mar 15 00:00:00 EDT 2018},
month = {Thu Mar 15 00:00:00 EDT 2018}
}
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Gold nanoparticles-based biosensing of Leishmania major kDNA genome: Visual and spectrophotometric detections
journal, November 2016
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journal, September 2014
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Size-Controlled Synthesis of Sub-10-nanometer Citrate-Stabilized Gold Nanoparticles and Related Optical Properties.
journal, February 2016
- Piella, Jordi; Bastús, Neus G.; Puntes, Victor
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Theoretical and Experimental Insights into the Origin of the Catalytic Activity of Subnanometric Gold Clusters: Attempts to Predict Reactivity with Clusters and Nanoparticles of Gold
journal, June 2013
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Polyacrylate-Assisted Size Control of Silver Nanoparticles and Their Catalytic Activity
journal, January 2014
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Catalytic Activity of Faceted Gold Nanoparticles Studied by a Model Reaction: Evidence for Substrate-Induced Surface Restructuring
journal, June 2011
- Wunder, Stefanie; Lu, Yan; Albrecht, Martin
- ACS Catalysis, Vol. 1, Issue 8
The Protease-Mediated Nucleus Shuttles of Subnanometer Gold Quantum Dots for Real-Time Monitoring of Apoptotic Cell Death
journal, June 2010
- Lin, Shu-Yi; Chen, Nai-Tzu; Sun, Shu-Pin
- Journal of the American Chemical Society, Vol. 132, Issue 24
Mechanism of Gold Nanoparticle Formation in the Classical Citrate Synthesis Method Derived from Coupled In Situ XANES and SAXS Evaluation
journal, February 2010
- Polte, Jörg; Ahner, T. Torsten; Delissen, Friedmar
- Journal of the American Chemical Society, Vol. 132, Issue 4
Kinetic Analysis of Catalytic Reduction of 4-Nitrophenol by Metallic Nanoparticles Immobilized in Spherical Polyelectrolyte Brushes
journal, April 2010
- Wunder, Stefanie; Polzer, Frank; Lu, Yan
- The Journal of Physical Chemistry C, Vol. 114, Issue 19
Seeded Growth Synthesis of Uniform Gold Nanoparticles with Diameters of 15−300 nm
journal, February 2011
- Ziegler, Christoph; Eychmüller, Alexander
- The Journal of Physical Chemistry C, Vol. 115, Issue 11
Nanosphere Lithography: Effect of the External Dielectric Medium on the Surface Plasmon Resonance Spectrum of a Periodic Array of Silver Nanoparticles
journal, November 1999
- Jensen, Traci R.; Duval, Michelle L.; Kelly, K. Lance
- The Journal of Physical Chemistry B, Vol. 103, Issue 45
Charged Gold Nanoparticles in Non-Polar Solvents: 10-min Synthesis and 2D Self-Assembly
journal, May 2010
- Martin, Matthew N.; Basham, James I.; Chando, Paul
- Langmuir, Vol. 26, Issue 10, p. 7410-7417
Understanding of the Size Control of Biocompatible Gold Nanoparticles in Millifluidic Channels
journal, October 2012
- Jun, Han; Fabienne, Testard; Florent, Malloggi
- Langmuir, Vol. 28, Issue 45
Synthesis of pH-Responsive Nanocomposite Microgels with Size-Controlled Gold Nanoparticles from Ion-Doped, Lightly Cross-Linked Poly(vinylpyridine)
journal, January 2010
- Akamatsu, Kensuke; Shimada, Megumi; Tsuruoka, Takaaki
- Langmuir, Vol. 26, Issue 2
Dynamic formation of single-atom catalytic active sites on ceria-supported gold nanoparticles
journal, March 2015
- Wang, Yang-Gang; Mei, Donghai; Glezakou, Vassiliki-Alexandra
- Nature Communications, Vol. 6, Issue 1
Supported gold nanoparticles as catalysts for organic reactions
journal, January 2008
- Corma, Avelino; Garcia, Hermenegildo
- Chemical Society Reviews, Vol. 37, Issue 9
Catalysis by metallic nanoparticles in aqueous solution: model reactions
journal, January 2012
- Hervés, Pablo; Pérez-Lorenzo, Moisés; Liz-Marzán, Luis M.
- Chemical Society Reviews, Vol. 41, Issue 17, p. 5577-5587
Gold nanoparticle (AuNPs) and gold nanopore (AuNPore) catalysts in organic synthesis
journal, January 2014
- Takale, Balaram S.; Bao, Ming; Yamamoto, Yoshinori
- Organic & Biomolecular Chemistry, Vol. 12, Issue 13
Preparation and characterization of magnetic gold shells using different sizes of gold nanoseeds and their corresponding effects on catalysis
journal, January 2014
- Rahman, Zia ur; Ma, Yanhua; Hu, Jing
- RSC Advances, Vol. 4, Issue 10
Simultaneous SERS detection and imaging of two biomarkers on the cancer cell surface by self-assembly of branched DNA–gold nanoaggregates
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A gold nanoparticle-based semi-quantitative and quantitative ultrasensitive paper sensor for the detection of twenty mycotoxins
journal, January 2016
- Kong, Dezhao; Liu, Liqiang; Song, Shanshan
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Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008
- Herzing, A. A.; Kiely, C. J.; Carley, A. F.
- Science, Vol. 321, Issue 5894
Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties
journal, September 1998
- Valden, M.
- Science, Vol. 281, Issue 5383
Size- and Structure-specificity in Catalysis by Gold Clusters
journal, April 2014
- Taketoshi, Ayako; Haruta, Masatake
- Chemistry Letters, Vol. 43, Issue 4
Size Effect of Gold Nanoparticles in Catalytic Reduction of p-Nitrophenol with NaBH4
journal, October 2013
- Lin, Chao; Tao, Kai; Hua, Dayin
- Molecules, Vol. 18, Issue 10
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Tunable synthesis of ultrathin AuAg nanowires and their catalytic applications
journal, January 2019
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Green synthesis and in situ immobilization of gold nanoparticles and their application for the reduction of p -nitrophenol in continuous-flow mode
journal, January 2019
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Lab-on-a-micromotor: catalytic Janus particles as mobile microreactors for tailored synthesis of nanoparticles
journal, January 2018
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- Chemical Science, Vol. 9, Issue 42
Enhanced surface activity of activated carbon by surfactants synergism
journal, January 2019
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Influence of the gas atmosphere during the synthesis of g-C 3 N 4 for enhanced photocatalytic H 2 production from water on Au/g-C 3 N 4 composites
journal, January 2019
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- Journal of Materials Chemistry A, Vol. 7, Issue 24
Galactose-functionalized GlycoAuNR as a photothermal conversion complex: Its binding to lectin RCA 120 and hepatoma-targeting therapy
journal, February 2020
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- Journal of Biomaterials Applications, Vol. 34, Issue 9
Synthesis of Gold Nanoparticles Using Mimosa tenuiflora Extract, Assessments of Cytotoxicity, Cellular Uptake, and Catalysis
journal, October 2019
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The di(thiourea)gold(I) complex [Au{S=C(NH2)2}2][SO3Me] as a precursor for the convenient preparation of gold nanoparticles
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Tailored Gold Nanoparticles for Cancer Imaging and Therapy
journal, September 2019
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5-Hydroxymethylfurfural and Furfural Base-Free Oxidation over AuPd Embedded Bimetallic Nanoparticles
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Increased Stability of Oligopeptidases Immobilized on Gold Nanoparticles
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Synthesis of Colloidal Au Nanoparticles through Ultrasonic Spray Pyrolysis and Their Use in the Preparation of Polyacrylate-AuNPs’ Composites
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- Materials, Vol. 12, Issue 22
The Effect of the Antioxidant Activity of Plant Extracts on the Properties of Gold Nanoparticles
journal, November 2019
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A new electrochemical sensor based on an Au-Pd/reduced graphene oxide nanocomposite for determination of Parathion
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A new electrochemical sensor based on an Au-Pd/reduced graphene oxide nanocomposite for determination of Parathion
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A new electrochemical sensor based on an Au-Pd/reduced graphene oxide nanocomposite for determination of Parathion
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Effect of size and charge asymmetry on aggregation kinetics of oppositely charged nanoparticles
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Lab-on-a-micromotor: catalytic Janus particles as mobile microreactors for tailored synthesis of nanoparticles
journal, January 2018
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- Chemical Science, Vol. 9, Issue 42
Synthesis of Gold Nanoparticles Using Mimosa tenuiflora Extract, Assessments of Cytotoxicity, Cellular Uptake, and Catalysis
journal, October 2019
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Synthesis of Colloidal Au Nanoparticles through Ultrasonic Spray Pyrolysis and Their Use in the Preparation of Polyacrylate-AuNPs’ Composites
journal, November 2019
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Metal Nanoparticles for Electrochemical Sensing: Progress and Challenges in the Clinical Transition of Point-of-Care Testing
journal, December 2020
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- Molecules, Vol. 25, Issue 24
Green Synthesis of Gold Nanoparticles Using Upland Cress and Their Biochemical Characterization and Assessment
journal, December 2021
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Ligand-Free Nano-Au Catalysts on Nitrogen-Doped Graphene Filter for Continuous Flow Catalysis
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Rapid Catalytic Reduction of 4-Nitrophenol and Clock Reaction of Methylene Blue using Copper Nanowires
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journal, November 2019
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- Nanomaterials, Vol. 9, Issue 12