Fluorine substituted (Mn,Ir)O2:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis

Ghadge, Shrinath Dattatray; Patel, Prasad Prakash; Datta, Moni Kanchan; Velikokhatnyi, Oleg I.; Kuruba, Ramalinga; Shanthi, Pavithra M.; Kumta, Prashant N.

doi:10.1039/c6ra27354h

Title: Fluorine substituted (Mn,Ir)O₂:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis

Abstract

Identification and development of high performance with reduced overpotential (i.e. reduced operating electricity cost) oxygen evolution reaction (OER) electrocatalysts for proton exchange membrane (PEM) based water electrolysis with ultra-low noble metal content (i.e. reduced materials cost) is of significant interest for economic hydrogen production, thus increasing the commercialization potential of PEM water electrolysis. Accordingly, a novel electrocatalyst should exhibit low overpotential, excellent electrochemical activity and durability superior to state of the art noble metal based electro-catalysts (e.g. Pt, IrO₂, RuO₂). Here in this paper, for the very first time to the best of our knowledge, exploiting first-principles theoretical calculations of the total energies and electronic structures, we have identified a reduced noble metal content fluorine doped solid solution of MnO₂ and IrO₂, denoted as (Mn_1-xIr_x)O₂:F (x = 0.2, 0.3, 0.4), OER electrocatalyst system exhibiting lower overpotential and higher current density than the state of the art IrO₂ and other previously reported systems for PEM water electrolysis. The doped solid solution displays an excellent electrochemical performance with a lowest reported onset potential to date of ~1.35 V (vs. RHE), ~80 mV lower than that of IrO₂ (~1.43 V vs. RHE) and ~15 fold (x = 0.3 and 0.4) higher electrochemical activitymore »« less

Authors:

Ghadge, Shrinath Dattatray ^[1]; Patel, Prasad Prakash ^[1]; Datta, Moni Kanchan ^[2]; Velikokhatnyi, Oleg I. ^[2]; Kuruba, Ramalinga ^[3]; Shanthi, Pavithra M. ^[1];

^[4]

Univ. of Pittsburgh, PA (United States). Chemical and Petroleum Engineering, Swanson School of Engineering
Univ. of Pittsburgh, PA (United States). Swanson School of Engineering, Dept. of Bioengineering; Univ. of Pittsburgh, PA (United States). Center for Complex Engineered Multifunctional Materials
Univ. of Pittsburgh, PA (United States). Swanson School of Engineering, Dept. of Bioengineering
Univ. of Pittsburgh, PA (United States). Chemical and Petroleum Engineering, Swanson School of Engineering; Univ. of Pittsburgh, PA (United States). Swanson School of Engineering, Dept. of Bioengineering; Univ. of Pittsburgh, PA (United States). Center for Complex Engineered Multifunctional Materials; Univ. of Pittsburgh, PA (United States). Mechanical Engineering and Materials Science; Univ. of Pittsburgh, PA (United States). School of Dental Medicine

Publication Date:: 2017-03-20

Research Org.:: Univ. of Pittsburgh, PA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1426497

Grant/Contract Number:: SC0001531

Resource Type:: Accepted Manuscript

Journal Name:: RSC Advances

Additional Journal Information:: Journal Volume: 7; Journal Issue: 28; Journal ID: ISSN 2046-2069

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 08 HYDROGEN

Citation Formats


                    Ghadge, Shrinath Dattatray, Patel, Prasad Prakash, Datta, Moni Kanchan, Velikokhatnyi, Oleg I., Kuruba, Ramalinga, Shanthi, Pavithra M., and Kumta, Prashant N. Fluorine substituted (Mn,Ir)O2:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis.  United States: N. p., 2017. 
Web.  doi:10.1039/c6ra27354h.

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                    Ghadge, Shrinath Dattatray, Patel, Prasad Prakash, Datta, Moni Kanchan, Velikokhatnyi, Oleg I., Kuruba, Ramalinga, Shanthi, Pavithra M., & Kumta, Prashant N. Fluorine substituted (Mn,Ir)O2:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis.  United States.  https://doi.org/10.1039/c6ra27354h

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                    Ghadge, Shrinath Dattatray, Patel, Prasad Prakash, Datta, Moni Kanchan, Velikokhatnyi, Oleg I., Kuruba, Ramalinga, Shanthi, Pavithra M., and Kumta, Prashant N. Mon .  
"Fluorine substituted (Mn,Ir)O2:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis".  United States.  https://doi.org/10.1039/c6ra27354h.  https://www.osti.gov/servlets/purl/1426497.

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@article{osti_1426497,

  title        = {Fluorine substituted (Mn,Ir)O2:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis},

  author       = {Ghadge, Shrinath Dattatray and Patel, Prasad Prakash and Datta, Moni Kanchan and Velikokhatnyi, Oleg I. and Kuruba, Ramalinga and Shanthi, Pavithra M. and Kumta, Prashant N.},

  abstractNote = {Identification and development of high performance with reduced overpotential (i.e. reduced operating electricity cost) oxygen evolution reaction (OER) electrocatalysts for proton exchange membrane (PEM) based water electrolysis with ultra-low noble metal content (i.e. reduced materials cost) is of significant interest for economic hydrogen production, thus increasing the commercialization potential of PEM water electrolysis. Accordingly, a novel electrocatalyst should exhibit low overpotential, excellent electrochemical activity and durability superior to state of the art noble metal based electro-catalysts (e.g. Pt, IrO2, RuO2). Here in this paper, for the very first time to the best of our knowledge, exploiting first-principles theoretical calculations of the total energies and electronic structures, we have identified a reduced noble metal content fluorine doped solid solution of MnO2 and IrO2, denoted as (Mn1-xIrx)O2:F (x = 0.2, 0.3, 0.4), OER electrocatalyst system exhibiting lower overpotential and higher current density than the state of the art IrO2 and other previously reported systems for PEM water electrolysis. The doped solid solution displays an excellent electrochemical performance with a lowest reported onset potential to date of ~1.35 V (vs. RHE), ~80 mV lower than that of IrO2 (~1.43 V vs. RHE) and ~15 fold (x = 0.3 and 0.4) higher electrochemical activity compared to pure IrO2. In addition, the system displays excellent long term electrochemical durability, similar to that of IrO2 in harsh acidic OER operating conditions. Our study therefore demonstrates remarkable, ~60–80% reduction in noble metal content along with lower overpotential and excellent electrochemical performance clearly demonstrating the potential of the (Mn1-xIrx)O2:F system as an OER electro-catalyst for PEM water electrolysis.},

  doi          = {10.1039/c6ra27354h},

  journal      = {RSC Advances},

  number       = 28,

  volume       = 7,

  place        = {United States},

  year         = {2017},

  month        = {3}

}

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Identification and development of non-noble metal based electro-catalysts or electro-catalysts comprising compositions with significantly reduced amounts of expensive noble metal contents (e.g. IrO{sub 2}, Pt) with comparable electrochemical performance to the standard noble metal/metal oxide for proton exchange membrane (PEM) based water electrolysis would signify a major breakthrough in hydrogen generation via water electrolysis. Development of such systems would lead to two primary outcomes: first, a reduction in the overall capital costs of PEM based water electrolyzers, and second, attainment of the targeted hydrogen production costs (<$3.00/gge delivered by 2015) comparable to conventional liquid fuels. In line with these goals,more »« less
https://doi.org/10.1039/c3ta01458d
Self-Supported Hydrous Iridium–Nickel Oxide Two-Dimensional Nanoframes for High Activity Oxygen Evolution Electrocatalysts

Journal Article Godínez-Salomón, Fernando ; Albiter, Luis ; Alia, Shaun M. ; ... - ACS Catalysis

Oxygen evolution reaction (OER) electrocatalysts with high activity, high stability, and low costs are needed for proton-exchange membrane (PEM) electrolyzers. Based on the high cost and limited supply of iridium, approaches that result in iridium-based OER catalysts with increased catalytic activity are of significant interest. Here, we report a carbon-free, self-supported hydrous iridium-nickel oxide two-dimensional nanoframe structure synthesized by thermal treatment of iridium-decorated nickel oxide nanosheets under reducing conditions and subsequent chemical leaching in acid. The catalyst nanoarchitecture contains an interconnected network of metallic iridium-nickel alloy domains with hydrous iridium oxide and nickel oxide located in the surface region. Themore »« less
Cited by 10
https://doi.org/10.1021/acscatal.8b02171

Full Text Available
Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction

Journal Article Peng, Rui-Li ; Li, Jia-Luo ; Wang, Xiao-Ning ; ... - Inorganic Chemistry Frontiers (Online)

The exploration of novel electrochemical energy conversion and storage devices has been extensively studied in recent decades for their specific advantages. Therefore, the design of highly efficient, stable, and noble-metal-free electrocatalysts for oxygen-related reactions (OER) is critical but challenging and is still worth improving. Herein, a facile and controllable synthesis strategy for bimetallic electrocatalysts for the OER from a two-dimensional iron-based metal–organic framework (HUST-8, HUST = Huazhong University of Science and Technology) precursor has been reported. The unoccupied porphyrin center has been disposed into the layer structure of HUST-8, which is very facile for the introduction of a second typemore »« less
https://doi.org/10.1039/d0qi00812e

Full Text Available

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Title: Fluorine substituted (Mn,Ir)O2:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis

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Citation Formats

Nanostructured robust cobalt metal alloy based anode electro-catalysts exhibiting remarkably high performance and durability for proton exchange membrane fuel cells journal, January 2015

Oxygen evolution in Co-doped RuO2 and IrO2: Experimental and theoretical insights to diminish electrolysis overpotential journal, December 2014

Nanostructured MnO2 for Li batteries journal, June 2003

Refinement of Macromolecular Structures by the Maximum-Likelihood Method journal, May 1997

Heterogeneous photocatalytic hydrogen production from water and biomass derivatives journal, January 2011

Recent progress in alkaline water electrolysis for hydrogen production and applications journal, June 2010

The physical–chemical properties and electrocatalytic performance of iridium oxide in oxygen evolution journal, November 2011

Evaluation of carbon-supported Pt and Pd nanoparticles for the hydrogen evolution reaction in PEM water electrolysers journal, March 2008

An overview of polymer electrolyte membrane electrolyzer for hydrogen production: Modeling and mass transport journal, March 2016

Accurate and simple density functional for the electronic exchange energy: Generalized gradient approximation journal, June 1986

The electrocatalytic properties of an IrO2/SnO2 catalyst using SnO2 as a support and an assisting reagent for the oxygen evolution reaction journal, January 2012

Role of Cu-Ion Doping in Cu-α-MnO 2 Nanowire Electrocatalysts for the Oxygen Reduction Reaction journal, July 2014

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Electrochemical controlled synthesis and characterization of well-aligned IrO2 nanotube arrays with enhanced electrocatalytic activity toward oxygen evolution reaction journal, January 2013

Vertically aligned nitrogen doped (Sn,Nb)O2 nanotubes – Robust photoanodes for hydrogen generation by photoelectrochemical water splitting journal, June 2016

MnO 2 by XPS journal, January 1999

Batteries: Higher energy density than gasoline? journal, July 2009

Data Reduction and Error Analysis for Accurate Single Crystal Diffraction Intensities journal, January 1987

XSEDE: Accelerating Scientific Discovery journal, September 2014

Nitrogen and cobalt co-doped zinc oxide nanowires – Viable photoanodes for hydrogen generation via photoelectrochemical water splitting journal, December 2015

MnO 2 -Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media † journal, February 2010

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles journal, October 2011

Ligand effects in heterogeneous catalysis and electrochemistry journal, May 2007

Fluorine-Doped IrO 2 : A Potential Electrocatalyst for Water Electrolysis journal, September 2013

Green process for hydrogen production from cellulose derivative using visible light-harvesting function of Mg chlorophyll-a journal, January 2005

The anodic characteristics of manganese dioxide electrodes prepared by thermal decomposition of manganese nitrate journal, April 1977

Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion journal, December 2013

Electrocatalysis by nanoparticles: Optimization of the loading level and operating pH for the oxygen evolution at crystallographically oriented manganese oxide nanorods modified electrodes journal, May 2008

Flexible graphene/MnO2 composite papers for supercapacitor electrodes journal, January 2011

Novel F-doped IrO2 oxygen evolution electrocatalyst for PEM based water electrolysis journal, January 2013

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal, July 1996

Proton exchange membrane water electrolysis with short-side-chain Aquivion® membrane and IrO2 anode catalyst journal, April 2014

High performance robust F-doped tin oxide based oxygen evolution electro-catalysts for PEM based water electrolysis journal, January 2013

Electrolysis of water on oxide surfaces journal, September 2007

Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities journal, March 2015

Nanostructured (Ir,Sn)O 2 :F – Oxygen Evolution Reaction Anode Electro-Catalyst Powders for PEM Based Water Electrolysis journal, January 2014

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Interpretation of XPS Mn(2p) spectra of Mn oxyhydroxides and constraints on the mechanism of MnO 2 precipitation journal, April 1998

High performance and durable nanostructured TiN supported Pt50–Ru50 anode catalyst for direct methanol fuel cell (DMFC) journal, October 2015

Dynamic potential–pH diagrams application to electrocatalysts for wateroxidation journal, January 2012

Hydrothermal Synthesis and Pseudocapacitance Properties of MnO 2 Nanostructures journal, November 2005

A highly efficient polysulfide mediator for lithium–sulfur batteries journal, January 2015

Molecular Insight in Structure and Activity of Highly Efficient, Low-Ir Ir–Ni Oxide Catalysts for Electrochemical Water Splitting (OER) journal, September 2015

Nanostructured F doped IrO2 electro-catalyst powders for PEM based water electrolysis journal, December 2014

The future of hydrogen – opportunities and challenges☆ journal, January 2009

WO 3 based solid solution oxide – promising proton exchange membrane fuel cell anode electro-catalyst journal, January 2015

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction journal, October 2013

Electrochemical performances of PEM water electrolysis cells and perspectives journal, March 2011

Conversion of inert cryptomelane-type manganese oxide into a highly efficient oxygen evolution catalyst via limited Ir doping journal, January 2016

Structural and electrochemical studies of α-manganese dioxide (α-MnO2) journal, October 1997

Electrochemical surface characterization of IrO2 + SnO2 mixed oxide electrocatalysts journal, October 1995

Pure hydrogen production by PEM electrolysis for hydrogen energy journal, February 2006

Performance of a PEM water electrolysis cell using IrxRuyTazO2IrxRuyTazO2 electrocatalysts for the oxygen evolution electrode journal, September 2007

Degradation mechanism of long service life Ti/IrO2–Ta2O5 oxide anodes in sulphuric acid journal, August 2002

Hydrogen production in single-chamber tubular microbial electrolysis cells using non-precious-metal catalysts journal, October 2009

Fluorine doped (Ir,Sn,Nb)O2 anode electro-catalyst for oxygen evolution via PEM based water electrolysis journal, January 2014

High performance fluorine doped (Sn,Ru)O2 oxygen evolution reaction electro-catalysts for proton exchange membrane based water electrolysis journal, January 2014

Synthesis and characterization of electrocatalysts for the oxygen evolution in PEM water electrolysis journal, August 2011

Electrocatalytic properties of transition metal oxides for oxygen evolution reaction journal, May 1986

Synthesis, Characterization, Electronic Structure, and Photocatalytic Activity of Nitrogen-Doped TiO 2 Nanocatalyst journal, December 2005

Noble metal-free bifunctional oxygen evolution and oxygen reduction acidic media electro-catalysts journal, July 2016

Oxygen‐Deficient Ti 0.9 Nb 0.1 O 2‐x as an Efficient Anodic Catalyst Support for PEM Water Electrolyzer journal, April 2019

Probing the active sites of Co 3 O 4 for the acidic oxygen evolution reaction by modulating the Co 2+ /Co 3+ ratio journal, January 2018

Mesoporous Co x Sn (1– x ) O 2 as an efficient oxygen evolution catalyst support for SPE water electrolyzer journal, April 2019

Earth-Abundant Electrocatalysts in Proton Exchange Membrane Electrolyzers journal, December 2018

Effect of Electronic Conductivities of Iridium Oxide/Doped SnO2 Oxygen-Evolving Catalysts on the Polarization Properties in Proton Exchange Membrane Water Electrolysis journal, January 2019

Title: Fluorine substituted (Mn,Ir)O₂:F high performance solid solution oxygen evolution reaction electro-catalysts for PEM water electrolysis

Nanostructured robust cobalt metal alloy based anode electro-catalysts exhibiting remarkably high performance and durability for proton exchange membrane fuel cells
journal, January 2015

Oxygen evolution in Co-doped RuO2 and IrO2: Experimental and theoretical insights to diminish electrolysis overpotential
journal, December 2014

Nanostructured MnO2 for Li batteries
journal, June 2003

Refinement of Macromolecular Structures by the Maximum-Likelihood Method
journal, May 1997

Heterogeneous photocatalytic hydrogen production from water and biomass derivatives
journal, January 2011

Recent progress in alkaline water electrolysis for hydrogen production and applications
journal, June 2010

The physical–chemical properties and electrocatalytic performance of iridium oxide in oxygen evolution
journal, November 2011

Evaluation of carbon-supported Pt and Pd nanoparticles for the hydrogen evolution reaction in PEM water electrolysers
journal, March 2008

An overview of polymer electrolyte membrane electrolyzer for hydrogen production: Modeling and mass transport
journal, March 2016

Accurate and simple density functional for the electronic exchange energy: Generalized gradient approximation
journal, June 1986

The electrocatalytic properties of an IrO2/SnO2 catalyst using SnO2 as a support and an assisting reagent for the oxygen evolution reaction
journal, January 2012

Role of Cu-Ion Doping in Cu-α-MnO ₂ Nanowire Electrocatalysts for the Oxygen Reduction Reaction
journal, July 2014

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Electrochemical controlled synthesis and characterization of well-aligned IrO2 nanotube arrays with enhanced electrocatalytic activity toward oxygen evolution reaction
journal, January 2013

Vertically aligned nitrogen doped (Sn,Nb)O2 nanotubes – Robust photoanodes for hydrogen generation by photoelectrochemical water splitting
journal, June 2016

MnO ₂ by XPS
journal, January 1999

Batteries: Higher energy density than gasoline?
journal, July 2009

Data Reduction and Error Analysis for Accurate Single Crystal Diffraction Intensities
journal, January 1987

XSEDE: Accelerating Scientific Discovery
journal, September 2014

Nitrogen and cobalt co-doped zinc oxide nanowires – Viable photoanodes for hydrogen generation via photoelectrochemical water splitting
journal, December 2015

MnO ₂ -Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media ^†
journal, February 2010

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
journal, October 2011

Ligand effects in heterogeneous catalysis and electrochemistry
journal, May 2007

Fluorine-Doped IrO ₂ : A Potential Electrocatalyst for Water Electrolysis
journal, September 2013

Green process for hydrogen production from cellulose derivative using visible light-harvesting function of Mg chlorophyll-a
journal, January 2005

The anodic characteristics of manganese dioxide electrodes prepared by thermal decomposition of manganese nitrate
journal, April 1977

Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion
journal, December 2013

Electrocatalysis by nanoparticles: Optimization of the loading level and operating pH for the oxygen evolution at crystallographically oriented manganese oxide nanorods modified electrodes
journal, May 2008

Flexible graphene/MnO2 composite papers for supercapacitor electrodes
journal, January 2011

Novel F-doped IrO₂ oxygen evolution electrocatalyst for PEM based water electrolysis
journal, January 2013

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

Proton exchange membrane water electrolysis with short-side-chain Aquivion® membrane and IrO2 anode catalyst
journal, April 2014

High performance robust F-doped tin oxide based oxygen evolution electro-catalysts for PEM based water electrolysis
journal, January 2013

Electrolysis of water on oxide surfaces
journal, September 2007

Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities
journal, March 2015

Nanostructured (Ir,Sn)O ₂ :F – Oxygen Evolution Reaction Anode Electro-Catalyst Powders for PEM Based Water Electrolysis
journal, January 2014

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Interpretation of XPS Mn(2p) spectra of Mn oxyhydroxides and constraints on the mechanism of MnO ₂ precipitation
journal, April 1998

High performance and durable nanostructured TiN supported Pt50–Ru50 anode catalyst for direct methanol fuel cell (DMFC)
journal, October 2015

Dynamic potential–pH diagrams application to electrocatalysts for wateroxidation
journal, January 2012

Hydrothermal Synthesis and Pseudocapacitance Properties of MnO ₂ Nanostructures
journal, November 2005

A highly efficient polysulfide mediator for lithium–sulfur batteries
journal, January 2015

Molecular Insight in Structure and Activity of Highly Efficient, Low-Ir Ir–Ni Oxide Catalysts for Electrochemical Water Splitting (OER)
journal, September 2015

Nanostructured F doped IrO2 electro-catalyst powders for PEM based water electrolysis
journal, December 2014

The future of hydrogen – opportunities and challenges☆
journal, January 2009

WO ₃ based solid solution oxide – promising proton exchange membrane fuel cell anode electro-catalyst
journal, January 2015

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

Electrochemical performances of PEM water electrolysis cells and perspectives
journal, March 2011

Conversion of inert cryptomelane-type manganese oxide into a highly efficient oxygen evolution catalyst via limited Ir doping
journal, January 2016

Structural and electrochemical studies of α-manganese dioxide (α-MnO2)
journal, October 1997

Electrochemical surface characterization of IrO2 + SnO2 mixed oxide electrocatalysts
journal, October 1995

Pure hydrogen production by PEM electrolysis for hydrogen energy
journal, February 2006

Performance of a PEM water electrolysis cell using IrxRuyTazO2IrxRuyTazO2 electrocatalysts for the oxygen evolution electrode
journal, September 2007

Degradation mechanism of long service life Ti/IrO2–Ta2O5 oxide anodes in sulphuric acid
journal, August 2002

Hydrogen production in single-chamber tubular microbial electrolysis cells using non-precious-metal catalysts
journal, October 2009

Fluorine doped (Ir,Sn,Nb)O2 anode electro-catalyst for oxygen evolution via PEM based water electrolysis
journal, January 2014

High performance fluorine doped (Sn,Ru)O₂ oxygen evolution reaction electro-catalysts for proton exchange membrane based water electrolysis
journal, January 2014

Synthesis and characterization of electrocatalysts for the oxygen evolution in PEM water electrolysis
journal, August 2011

Electrocatalytic properties of transition metal oxides for oxygen evolution reaction
journal, May 1986

Synthesis, Characterization, Electronic Structure, and Photocatalytic Activity of Nitrogen-Doped TiO ₂ Nanocatalyst
journal, December 2005

Noble metal-free bifunctional oxygen evolution and oxygen reduction acidic media electro-catalysts
journal, July 2016

Oxygen‐Deficient Ti _0.9 Nb _0.1 O _2‐x as an Efficient Anodic Catalyst Support for PEM Water Electrolyzer
journal, April 2019

Probing the active sites of Co ₃ O ₄ for the acidic oxygen evolution reaction by modulating the Co ²⁺ /Co ³⁺ ratio
journal, January 2018

Mesoporous Co _x Sn _{(1– x )} O ₂ as an efficient oxygen evolution catalyst support for SPE water electrolyzer
journal, April 2019

Earth-Abundant Electrocatalysts in Proton Exchange Membrane Electrolyzers
journal, December 2018

Effect of Electronic Conductivities of Iridium Oxide/Doped SnO2 Oxygen-Evolving Catalysts on the Polarization Properties in Proton Exchange Membrane Water Electrolysis
journal, January 2019