skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Weak polyelectrolyte complexation driven by associative charging

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1426342
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 148 Journal Issue: 11; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Rathee, Vikramjit S., Zervoudakis, Aristotle J., Sidky, Hythem, Sikora, Benjamin J., and Whitmer, Jonathan K. Weak polyelectrolyte complexation driven by associative charging. United States: N. p., 2018. Web. doi:10.1063/1.5017941.
Rathee, Vikramjit S., Zervoudakis, Aristotle J., Sidky, Hythem, Sikora, Benjamin J., & Whitmer, Jonathan K. Weak polyelectrolyte complexation driven by associative charging. United States. doi:10.1063/1.5017941.
Rathee, Vikramjit S., Zervoudakis, Aristotle J., Sidky, Hythem, Sikora, Benjamin J., and Whitmer, Jonathan K. Wed . "Weak polyelectrolyte complexation driven by associative charging". United States. doi:10.1063/1.5017941.
@article{osti_1426342,
title = {Weak polyelectrolyte complexation driven by associative charging},
author = {Rathee, Vikramjit S. and Zervoudakis, Aristotle J. and Sidky, Hythem and Sikora, Benjamin J. and Whitmer, Jonathan K.},
abstractNote = {},
doi = {10.1063/1.5017941},
journal = {Journal of Chemical Physics},
number = 11,
volume = 148,
place = {United States},
year = {2018},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1063/1.5017941

Citation Metrics:
Cited by: 7 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Heteroprotein complex coacervation: A generic process
journal, January 2017

  • Croguennec, Thomas; Tavares, Guilherme M.; Bouhallab, Saïd
  • Advances in Colloid and Interface Science, Vol. 239
  • DOI: 10.1016/j.cis.2016.06.009

Drug Delivery Systems: 3B. Role of Polymers in Drug Delivery
journal, February 1990


Equilibrium charge distribution on weak polyelectrolytes
journal, November 1997

  • Berghold, Gerd; van der Schoot, Paul; Seidel, Christian
  • The Journal of Chemical Physics, Vol. 107, Issue 19
  • DOI: 10.1063/1.475071

The awesome lysosome
journal, January 2016


Chitosan based in situ forming polyelectrolyte complexes: A potential sustained drug delivery polymeric carrier for high dose drugs
journal, October 2017


Layer-by-Layer Assembly of Polyelectrolyte Chains and Nanoparticles on Nanoporous Substrates: Molecular Dynamics Simulations
journal, December 2011

  • Carrillo, Jan-Michael Y.; Dobrynin, Andrey V.
  • Langmuir, Vol. 28, Issue 2
  • DOI: 10.1021/la203940w

Influence of pH on the Structure of Multilayer Films Composed of Strong and Weak Polyelectrolytes
journal, March 2009

  • Elzḃieciak, M.; Zapotoczny, S.; Nowak, P.
  • Langmuir, Vol. 25, Issue 5
  • DOI: 10.1021/la803988k

Encapsulation of active ingredients in polysaccharide–protein complex coacervates
journal, January 2017

  • Devi, Nirmala; Sarmah, Mandip; Khatun, Bably
  • Advances in Colloid and Interface Science, Vol. 239
  • DOI: 10.1016/j.cis.2016.05.009

The adhesive properties of coacervated recombinant hybrid mussel adhesive proteins
journal, May 2010


Theory of polyelectrolytes in solutions and at surfaces
journal, November 2005


Polyelectrolyte complexes: Bulk phases and colloidal systems
journal, September 2011

  • Gucht, Jasper van der; Spruijt, Evan; Lemmers, Marc
  • Journal of Colloid and Interface Science, Vol. 361, Issue 2
  • DOI: 10.1016/j.jcis.2011.05.080

Bioactive materials for antifouling coatings
journal, June 1992


Review of Monte Carlo Methods for the Prediction of Distributed Molecular and Morphological Polymer Properties
journal, January 2014

  • Meimaroglou, Dimitrios; Kiparissides, Costas
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 22
  • DOI: 10.1021/ie4033044

Molecular Dynamics Simulations of Polyelectrolyte−Polyampholyte Complexes. Effect of Solvent Quality and Salt Concentration
journal, December 2006

  • Jeon, Junhwan; Dobrynin, Andrey V.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 48
  • DOI: 10.1021/jp064288b

A Water-Borne Adhesive Modeled after the Sandcastle Glue of P. californica
journal, May 2009

  • Shao, Hui; Bachus, Kent N.; Stewart, Russell J.
  • Macromolecular Bioscience, Vol. 9, Issue 5
  • DOI: 10.1002/mabi.200800252

Preparation and antimicrobial evaluation of polyion complex (PIC) nanoparticles loaded with polymyxin B
journal, February 2017


Enzyme Multilayers on Colloid Particles:  Assembly, Stability, and Enzymatic Activity
journal, November 2000

  • Caruso, Frank; Schüler, Corinna
  • Langmuir, Vol. 16, Issue 24
  • DOI: 10.1021/la000942h

Linear polyelectrolytes in tetravalent salt solutions
journal, January 2006

  • Hsiao, Pai-Yi
  • The Journal of Chemical Physics, Vol. 124, Issue 4
  • DOI: 10.1063/1.2155484

Fast Parallel Algorithms for Short-Range Molecular Dynamics
journal, March 1995


Entropy and enthalpy of polyelectrolyte complexation: Langevin dynamics simulations
journal, April 2006

  • Ou, Zhaoyang; Muthukumar, M.
  • The Journal of Chemical Physics, Vol. 124, Issue 15
  • DOI: 10.1063/1.2178803

Complexation of a Weak Polyelectrolyte with a Charged Nanoparticle. Solution Properties and Polyelectrolyte Stiffness Influences
journal, October 2005

  • Ulrich, Serge; Laguecir, Abohachem; Stoll, Serge
  • Macromolecules, Vol. 38, Issue 21
  • DOI: 10.1021/ma051142m

Molecularly Imprinted Membranes
journal, July 2012


Influence of the Degree of Ionization on Weak Polyelectrolyte Multilayer Assembly
journal, January 2005

  • Choi, Jeeyoung; Rubner, Michael F.
  • Macromolecules, Vol. 38, Issue 1
  • DOI: 10.1021/ma048596o

Pearl-Necklace Structures in Annealed Polyelectrolytes
journal, December 2004

  • Uyaver, Sahin; Seidel, Christian
  • The Journal of Physical Chemistry B, Vol. 108, Issue 49
  • DOI: 10.1021/jp0464270

Formulation and characterization of pH sensitive drug carrier based on phosphorylated chitosan (PCS)
journal, August 2003


pH and Salt Effects on the Associative Phase Separation of Oppositely Charged Polyelectrolytes
journal, May 2014


Complexation Behavior of Polyelectrolytes and Polyampholytes
journal, August 2017

  • Narayanan Nair, Arun Kumar; Martinez Jimenez, Arturo; Sun, Shuyu
  • The Journal of Physical Chemistry B, Vol. 121, Issue 33
  • DOI: 10.1021/acs.jpcb.7b04582

Molecular dynamics (MD) simulations for polymers
journal, December 1990


Theory of polyelectrolyte complexation—Complex coacervates are self-coacervates
journal, June 2017

  • Delaney, Kris T.; Fredrickson, Glenn H.
  • The Journal of Chemical Physics, Vol. 146, Issue 22
  • DOI: 10.1063/1.4985568

pH-Responsive Poly(acrylic acid) Core Cross-Linked Star Polymers: Morphology Transitions in Solution and Multilayer Thin Films
journal, April 2008

  • Connal, Luke A.; Li, Qi; Quinn, John F.
  • Macromolecules, Vol. 41, Issue 7
  • DOI: 10.1021/ma7019557

Ideal Mixing in Polyelectrolyte Complexes and Multilayers:  Entropy Driven Assembly
journal, October 2006

  • Bucur, Claudiu B.; Sui, Zhijie; Schlenoff, Joseph B.
  • Journal of the American Chemical Society, Vol. 128, Issue 42
  • DOI: 10.1021/ja064532c

Dynamics of entangled linear polymer melts:  A molecular‐dynamics simulation
journal, April 1990

  • Kremer, Kurt; Grest, Gary S.
  • The Journal of Chemical Physics, Vol. 92, Issue 8
  • DOI: 10.1063/1.458541

Layer-by-Layer Assembly of Charged Nanoparticles on Porous Substrates: Molecular Dynamics Simulations
journal, March 2011

  • Carrillo, Jan-Michael Y.; Dobrynin, Andrey V.
  • ACS Nano, Vol. 5, Issue 4
  • DOI: 10.1021/nn200065q

Distinct effects of endosomal escape and inhibition of endosomal trafficking on gene delivery via electrotransfection
journal, February 2017


Complex coacervates as a foundation for synthetic underwater adhesives
journal, September 2011

  • Stewart, Russell J.; Wang, Ching Shuen; Shao, Hui
  • Advances in Colloid and Interface Science, Vol. 167, Issue 1-2
  • DOI: 10.1016/j.cis.2010.10.009

Phase Behavior and Coacervation of Aqueous Poly(acrylic acid)−Poly(allylamine) Solutions
journal, March 2010

  • Chollakup, Rungsima; Smitthipong, Wirasak; Eisenbach, Claus D.
  • Macromolecules, Vol. 43, Issue 5
  • DOI: 10.1021/ma902144k

Charge on a weak polyelectrolyte
journal, December 2008

  • Wang, Shengqin; Granick, Steve; Zhao, Jiang
  • The Journal of Chemical Physics, Vol. 129, Issue 24
  • DOI: 10.1063/1.3055596

Salt-Induced Collapse and Reexpansion of Highly Charged Flexible Polyelectrolytes
journal, October 2006


Current progress in the gene therapy of cancer
journal, January 1996


Annealed and Quenched Polyelectrolytes
journal, December 1990


Kinetics of Formation and Dissolution of Weak Polyelectrolyte Multilayers:  Role of Salt and Free Polyions
journal, July 2002

  • Kovacevic, D.; van der Burgh, S.; de Keizer, A.
  • Langmuir, Vol. 18, Issue 14
  • DOI: 10.1021/la025639q

Thermodynamic Characterization of Polypeptide Complex Coacervation
journal, October 2012

  • Priftis, Dimitrios; Laugel, Nicolas; Tirrell, Matthew
  • Langmuir, Vol. 28, Issue 45
  • DOI: 10.1021/la302729r

Catechol Polymers for pH-Responsive, Targeted Drug Delivery to Cancer Cells
journal, August 2011

  • Su, Jing; Chen, Feng; Cryns, Vincent L.
  • Journal of the American Chemical Society, Vol. 133, Issue 31
  • DOI: 10.1021/ja203077x

Probing the Inhomogeneous Charge Distribution on Annealed Polyelectrolyte Star Polymers in Dilute Aqueous Solutions
journal, March 2016


Stimuli-responsive weak polyelectrolyte multilayer films: A thin film platform for self triggered multi-drug delivery
journal, January 2016


Cascade of Transitions of Polyelectrolytes in Poor Solvents
journal, January 1996

  • Dobrynin, Andrey V.; Rubinstein, Michael; Obukhov, Sergei P.
  • Macromolecules, Vol. 29, Issue 8
  • DOI: 10.1021/ma9507958

One- and three-month release injectable microspheres of the LH-RH superagonist leuprorelin acetate
journal, October 1997


The effect of comb architecture on complex coacervation
journal, January 2017

  • Johnston, Brandon M.; Johnston, Cameron W.; Letteri, Rachel A.
  • Organic & Biomolecular Chemistry, Vol. 15, Issue 36
  • DOI: 10.1039/C7OB01314K

Driving Forces for Oppositely Charged Polyion Association in Aqueous Solutions: Enthalpic, Entropic, but Not Electrostatic
journal, January 2016

  • Fu, Jingcheng; Schlenoff, Joseph B.
  • Journal of the American Chemical Society, Vol. 138, Issue 3
  • DOI: 10.1021/jacs.5b11878

Layer-by-layer assembly as a versatile bottom-up nanofabrication technique for exploratory research and realistic application
journal, January 2007

  • Ariga, Katsuhiko; Hill, Jonathan P.; Ji, Qingmin
  • Physical Chemistry Chemical Physics, Vol. 9, Issue 19
  • DOI: 10.1039/b700410a

Complex coacervation: A field theoretic simulation study of polyelectrolyte complexation
journal, June 2008

  • Lee, Jonghoon; Popov, Yuri O.; Fredrickson, Glenn H.
  • The Journal of Chemical Physics, Vol. 128, Issue 22
  • DOI: 10.1063/1.2936834

A coarse-grained thermodynamic model for the predictive engineering of valence-selective membranes
journal, January 2016

  • Rathee, Vikramjit Singh; Qu, Siyi; Phillip, William A.
  • Molecular Systems Design & Engineering, Vol. 1, Issue 3
  • DOI: 10.1039/c6me00045b

Effect of Varying Salt Concentration on the Behavior of Weak Polyelectrolytes in a Poor Solvent
journal, February 2009

  • Uyaver, Sahin; Seidel, Christian
  • Macromolecules, Vol. 42, Issue 4
  • DOI: 10.1021/ma801817j

Porous Nafion membranes
journal, December 2016


Changes in lysosome shape and distribution correlated with changes in cytoplasmic pH
journal, March 1989


Simulating the thermodynamics of charging in weak polyelectrolytes: the Debye–Hückel limit
journal, January 2018

  • Rathee, Vikramjit S.; Sikora, Benjamin J.; Sidky, Hythem
  • Materials Research Express, Vol. 5, Issue 1
  • DOI: 10.1088/2053-1591/aaa049

Single Flexible Hydrophobic Polyelectrolyte Molecules Adsorbed on Solid Substrate:  Transition between a Stretched Chain, Necklace-like Conformation and a Globule
journal, April 2002

  • Minko, Sergiy; Kiriy, Anton; Gorodyska, Ganna
  • Journal of the American Chemical Society, Vol. 124, Issue 13
  • DOI: 10.1021/ja017767r

Counter-ion distribution around flexible polyelectrolytes having different molecular architecture
journal, January 2016

  • Chremos, Alexandros; Douglas, Jack F.
  • Soft Matter, Vol. 12, Issue 11
  • DOI: 10.1039/c5sm02873f

Polymers for Drug Delivery Systems
journal, June 2010


Glossary of basic terms in polymer science (IUPAC Recommendations 1996)
journal, January 1996

  • Jenkins, A. D.; Kratochvíl, P.; Stepto, R. F. T.
  • Pure and Applied Chemistry, Vol. 68, Issue 12
  • DOI: 10.1351/pac199668122287

Self assembled materials: design strategies and drug delivery perspectives
journal, January 2013

  • Verma, Gunjan; Hassan, P. A.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 40
  • DOI: 10.1039/c3cp51207j

Internal pH of human neutrophil lysosomes
journal, November 1982