Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature
Abstract
In this report VTEC™ PI-1388 and 20 wt% (Al) NH2-MIL-53/VTEC™ PI-1388 mixed-matrix membranes (MMMs) with different thicknesses were tested for gas permeation of H2 and CO2 from 5 to 30 bar and from 35 to 300 °C. 50/50 H2/CO2 mixtures were also tested at 30 bar and 250 °C with stage cuts that ranged from 0.05 to 1. Gas permeation data show that the affinity of (Al) NH2-MIL-53 for VTEC™ PI-1388 is strong enough to perform gas separations under these conditions. At 30 bar and at temperatures above 200 °C, the performance of the MMMs for H2/CO2 separation improved significantly with increasing temperature. Specifically, the H2 permeability of the MMM at 300 °C increased by 70% with respect to that of VTEC™ PI-1388 (VTEC™ PI-1388: H2 = 85 Barrer, H2/CO2 = 4.0; MMM: H2 = 144 Barrer, H2/CO2 = 5.8). Gas mixture separations using VTEC™ PI-1388 and the MMM depended on the stage cut and reached a maximum H2/CO2 separation of 7.2 for VTEC™ PI-1388 and 7.5 for the MMM at a stage cut of 0.05.
- Authors:
-
- University of Texas at Dallas, Richardson, TX (United States)
- Publication Date:
- Research Org.:
- Univ. of Texas at Dallas, Richardson, TX (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)
- OSTI Identifier:
- 1534104
- Alternate Identifier(s):
- OSTI ID: 1426304
- Grant/Contract Number:
- FE0001293; NT0007636; CBET-0933563; CBET-1403950
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Membrane Science
- Additional Journal Information:
- Journal Volume: 530; Journal Issue: C; Journal ID: ISSN 0376-7388
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Perez, Edson V., Kalaw, Grace J.D., Ferraris, John P., Balkus, Kenneth J., and Musselman, Inga H. Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature. United States: N. p., 2017.
Web. doi:10.1016/j.memsci.2017.02.003.
Perez, Edson V., Kalaw, Grace J.D., Ferraris, John P., Balkus, Kenneth J., & Musselman, Inga H. Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature. United States. https://doi.org/10.1016/j.memsci.2017.02.003
Perez, Edson V., Kalaw, Grace J.D., Ferraris, John P., Balkus, Kenneth J., and Musselman, Inga H. Thu .
"Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature". United States. https://doi.org/10.1016/j.memsci.2017.02.003. https://www.osti.gov/servlets/purl/1534104.
@article{osti_1534104,
title = {Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature},
author = {Perez, Edson V. and Kalaw, Grace J.D. and Ferraris, John P. and Balkus, Kenneth J. and Musselman, Inga H.},
abstractNote = {In this report VTEC™ PI-1388 and 20 wt% (Al) NH2-MIL-53/VTEC™ PI-1388 mixed-matrix membranes (MMMs) with different thicknesses were tested for gas permeation of H2 and CO2 from 5 to 30 bar and from 35 to 300 °C. 50/50 H2/CO2 mixtures were also tested at 30 bar and 250 °C with stage cuts that ranged from 0.05 to 1. Gas permeation data show that the affinity of (Al) NH2-MIL-53 for VTEC™ PI-1388 is strong enough to perform gas separations under these conditions. At 30 bar and at temperatures above 200 °C, the performance of the MMMs for H2/CO2 separation improved significantly with increasing temperature. Specifically, the H2 permeability of the MMM at 300 °C increased by 70% with respect to that of VTEC™ PI-1388 (VTEC™ PI-1388: H2 = 85 Barrer, H2/CO2 = 4.0; MMM: H2 = 144 Barrer, H2/CO2 = 5.8). Gas mixture separations using VTEC™ PI-1388 and the MMM depended on the stage cut and reached a maximum H2/CO2 separation of 7.2 for VTEC™ PI-1388 and 7.5 for the MMM at a stage cut of 0.05.},
doi = {10.1016/j.memsci.2017.02.003},
journal = {Journal of Membrane Science},
number = C,
volume = 530,
place = {United States},
year = {Thu Feb 02 00:00:00 EST 2017},
month = {Thu Feb 02 00:00:00 EST 2017}
}
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