The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering

Wei, Xialu; Rechtin, Jack; Olevsky, Eugene

doi:10.3390/met7090372

Title: The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering

Abstract

Spark plasma sintering (SPS) has been successfully used to produce all-solid-state lithium-ion batteries (ASSLibs). Both regular and functionally graded electrodes are implemented into novel three-layer and five-layer battery designs together with solid-state composite electrolyte. The electrical capacities and the conductivities of the SPS-processed ASSLibs are evaluated using the galvanostatic charge-discharge test. Experimental results have shown that, compared to the three-layer battery, the five-layer battery is able to improve energy and power densities. Scanning electron microscopy (SEM) is employed to examine the microstructures of the batteries especially at the electrode–electrolyte interfaces. It reveals that the functionally graded structure can eliminate the delamination effect at the electrode–electrolyte interface and, therefore, retains better performance.

Authors:

^[1]; Rechtin, Jack ^[1]; Olevsky, Eugene ^[2]

San Diego State Univ., CA (United States)
San Diego State Univ., CA (United States); Univ. of California, San Diego, CA (United States)

Publication Date:: 2017-09-14

Research Org.:: San Diego State Univ., CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1426194

Grant/Contract Number:: SC0008581

Resource Type:: Accepted Manuscript

Journal Name:: Metals

Additional Journal Information:: Journal Volume: 7; Journal Issue: 12; Journal ID: ISSN 2075-4701

Publisher:: MDPI

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Wei, Xialu, Rechtin, Jack, and Olevsky, Eugene. The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering.  United States: N. p., 2017. 
Web.  doi:10.3390/met7090372.

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                    Wei, Xialu, Rechtin, Jack, & Olevsky, Eugene. The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering.  United States.  https://doi.org/10.3390/met7090372

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                    Wei, Xialu, Rechtin, Jack, and Olevsky, Eugene. Thu .  
"The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering".  United States.  https://doi.org/10.3390/met7090372.  https://www.osti.gov/servlets/purl/1426194.

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@article{osti_1426194,

  title        = {The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering},

  author       = {Wei, Xialu and Rechtin, Jack and Olevsky, Eugene},

  abstractNote = {Spark plasma sintering (SPS) has been successfully used to produce all-solid-state lithium-ion batteries (ASSLibs). Both regular and functionally graded electrodes are implemented into novel three-layer and five-layer battery designs together with solid-state composite electrolyte. The electrical capacities and the conductivities of the SPS-processed ASSLibs are evaluated using the galvanostatic charge-discharge test. Experimental results have shown that, compared to the three-layer battery, the five-layer battery is able to improve energy and power densities. Scanning electron microscopy (SEM) is employed to examine the microstructures of the batteries especially at the electrode–electrolyte interfaces. It reveals that the functionally graded structure can eliminate the delamination effect at the electrode–electrolyte interface and, therefore, retains better performance.},

  doi          = {10.3390/met7090372},

  journal      = {Metals},

  number       = 12,

  volume       = 7,

  place        = {United States},

  year         = {2017},

  month        = {9}

}

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Works referencing / citing this record:

Digital Printing of Solid‐State Lithium‐Ion Batteries
journal, October 2019

Deiner, L. Jay; Bezerra, Carlos André Gomes; Howell, Thomas G.
Advanced Engineering Materials, Vol. 21, Issue 11
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Spark Plasma Sintering of Lithium Aluminum Germanium Phosphate Solid Electrolyte and its Electrochemical Properties
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Spark Plasma Sintering of Lithium Aluminum Germanium Phosphate Solid Electrolyte and its Electrochemical Properties
text, January 2019

Zhu, Hongzheng; Prasad, Anil; Doja, Somi
Multidisciplinary Digital Publishing Institute
DOI: 10.14288/1.0380661

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Title: The Fabrication of All-Solid-State Lithium-Ion Batteries via Spark Plasma Sintering

Abstract

Citation Formats

Role of amorphous boundary layer in enhancing ionic conductivity of lithium–lanthanum–titanate electrolyte journal, March 2010

Li6ALa2Ta2O12 (A = Sr, Ba): Novel Garnet-Like Oxides for Fast Lithium Ion Conduction journal, January 2005

Stability of lithium ion conductor NASICON structure glass ceramic in acid and alkaline aqueous solution journal, January 2014

A microcontact impedance study on NASICON-type Li 1+x Al x Ti 2−x (PO 4 ) 3 (0 ≤ x ≤ 0.5) single crystals journal, January 2016

The Stone Age Revisited: Building a Monolithic Inorganic Lithium-Ion Battery journal, February 2012

Ga-substituted Li7La3Zr2O12: An investigation based on grain coarsening in garnet-type lithium ion conductors journal, February 2017

A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries journal, February 2011

Effect of sintering temperature on structure and ionic conductivity of Li7−xLa3Zr2O12−0.5x (x=0.5~0.7) ceramics journal, December 2011

All-solid-state lithium battery with a three-dimensionally ordered Li1.5Al0.5Ti1.5(PO4)3 electrode journal, September 2010

Densification of LiTi2(PO4)3-based solid electrolytes by spark-plasma-sintering journal, September 1999

High lithium ion conduction in garnet-type Li6La3ZrTaO12 journal, December 2011

Spark plasma sintered/synthesized dense and nanostructured materials for solid-state Li-ion batteries: Overview and perspective journal, February 2014

Current understanding and future research directions at the onset of the next century of sintering science and technology journal, May 2017

Ceramic and polymeric solid electrolytes for lithium-ion batteries journal, August 2010

Comparative study of solid-state reaction and sol-gel process for synthesis of Zr-doped Li0.5La0.5TiO3 solid electrolytes journal, June 2016

Very fast bulk Li ion diffusivity in crystalline Li 1.5 Al 0.5 Ti 1.5 (PO 4 ) 3 as seen using NMR relaxometry journal, January 2015

Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte journal, September 2011

Li-ion battery materials: present and future journal, June 2015

Recent progress in cathode materials research for advanced lithium ion batteries journal, May 2012

Poly(vinylidene fluoride-hexafluoropropylene) polymer electrolyte for paper-based and flexible battery applications journal, June 2016

High ionic conductivity in lithium lanthanum titanate journal, June 1993

Study on lithium/air secondary batteries—Stability of NASICON-type lithium ion conducting glass–ceramics with water journal, April 2009

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries journal, March 2014

Local Structure and Dynamics of Lithium Garnet Ionic Conductors: A Model Material Li 5 La 3 Ta 2 O 12 journal, September 2014

Lithium conductivity and lithium diffusion in NASICON-type Li1+xTi2–xAlx(PO4)3 (x= 0; 0.3) prepared by mechanical activation journal, January 2008

Lithium ion conduction in LiTi2(PO4)3 journal, February 2001

Transport properties of LiCoPO4 and Fe-substituted LiCoPO4 journal, May 2014

Facile proton conduction in H+/Li+ ion-exchanged garnet-type fast Li-ion conducting Li5La3Nb2O12 journal, January 2013

Integrated study of first principles calculations and experimental measurements for Li-ionic conductivity in Al-doped solid-state LiGe2(PO4)3 electrolyte journal, October 2015

Candidate compounds with perovskite structure for high lithium ionic conductivity journal, May 1994

Spark Plasma Sintering of LiTi2(PO4)3-Based Solid Electrolytes journal, July 2005

Instability of the Lithium Garnet Li 7 La 3 Sn 2 O 12 : Li + /H + Exchange and Structural Study journal, April 2011

Dense nanostructured solid electrolyte with high Li-ion conductivity by spark plasma sintering technique journal, August 2008

Crystal Chemistry and Stability of “Li7La3Zr2O12 ” Garnet: A Fast Lithium-Ion Conductor journal, February 2011

Lithium Ion-Conducting Glass?Ceramics of Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 ?xLi 2 O (x=0.0?0.20) with Good Electrical and Electrochemical Properties journal, September 2007

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Role of amorphous boundary layer in enhancing ionic conductivity of lithium–lanthanum–titanate electrolyte
journal, March 2010

Li6ALa2Ta2O12 (A = Sr, Ba): Novel Garnet-Like Oxides for Fast Lithium Ion Conduction
journal, January 2005

Stability of lithium ion conductor NASICON structure glass ceramic in acid and alkaline aqueous solution
journal, January 2014

A microcontact impedance study on NASICON-type Li _1+x Al _x Ti _2−x (PO ₄ ) ₃ (0 ≤ x ≤ 0.5) single crystals
journal, January 2016

The Stone Age Revisited: Building a Monolithic Inorganic Lithium-Ion Battery
journal, February 2012

Ga-substituted Li7La3Zr2O12: An investigation based on grain coarsening in garnet-type lithium ion conductors
journal, February 2017

A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries
journal, February 2011

Effect of sintering temperature on structure and ionic conductivity of Li7−xLa3Zr2O12−0.5x (x=0.5~0.7) ceramics
journal, December 2011

All-solid-state lithium battery with a three-dimensionally ordered Li1.5Al0.5Ti1.5(PO4)3 electrode
journal, September 2010

Densification of LiTi2(PO4)3-based solid electrolytes by spark-plasma-sintering
journal, September 1999

High lithium ion conduction in garnet-type Li6La3ZrTaO12
journal, December 2011

Spark plasma sintered/synthesized dense and nanostructured materials for solid-state Li-ion batteries: Overview and perspective
journal, February 2014

Current understanding and future research directions at the onset of the next century of sintering science and technology
journal, May 2017

Ceramic and polymeric solid electrolytes for lithium-ion batteries
journal, August 2010

Comparative study of solid-state reaction and sol-gel process for synthesis of Zr-doped Li0.5La0.5TiO3 solid electrolytes
journal, June 2016

Very fast bulk Li ion diffusivity in crystalline Li _1.5 Al _0.5 Ti _1.5 (PO ₄ ) ₃ as seen using NMR relaxometry
journal, January 2015

Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte
journal, September 2011

Li-ion battery materials: present and future
journal, June 2015

Recent progress in cathode materials research for advanced lithium ion batteries
journal, May 2012

Poly(vinylidene fluoride-hexafluoropropylene) polymer electrolyte for paper-based and flexible battery applications
journal, June 2016

High ionic conductivity in lithium lanthanum titanate
journal, June 1993

Study on lithium/air secondary batteries—Stability of NASICON-type lithium ion conducting glass–ceramics with water
journal, April 2009

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries
journal, March 2014

Local Structure and Dynamics of Lithium Garnet Ionic Conductors: A Model Material Li ₅ La ₃ Ta ₂ O ₁₂
journal, September 2014

Lithium conductivity and lithium diffusion in NASICON-type Li1+xTi2–xAlx(PO4)3 (x= 0; 0.3) prepared by mechanical activation
journal, January 2008

Lithium ion conduction in LiTi2(PO4)3
journal, February 2001

Transport properties of LiCoPO4 and Fe-substituted LiCoPO4
journal, May 2014

Facile proton conduction in H+/Li+ ion-exchanged garnet-type fast Li-ion conducting Li5La3Nb2O12
journal, January 2013

Integrated study of first principles calculations and experimental measurements for Li-ionic conductivity in Al-doped solid-state LiGe2(PO4)3 electrolyte
journal, October 2015

Candidate compounds with perovskite structure for high lithium ionic conductivity
journal, May 1994

Spark Plasma Sintering of LiTi2(PO4)3-Based Solid Electrolytes
journal, July 2005

Instability of the Lithium Garnet Li ₇ La ₃ Sn ₂ O ₁₂ : Li ⁺ /H ⁺ Exchange and Structural Study
journal, April 2011

Dense nanostructured solid electrolyte with high Li-ion conductivity by spark plasma sintering technique
journal, August 2008

Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

Lithium Ion-Conducting Glass?Ceramics of Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ ?xLi ₂ O (x=0.0?0.20) with Good Electrical and Electrochemical Properties
journal, September 2007

Synthesis and electrochemical performance of Li4Ti5O12 submicrospheres coated with TiN as anode materials for lithium-ion battery
journal, November 2016

Digital Printing of Solid‐State Lithium‐Ion Batteries
journal, October 2019

Plasma Enabled Synthesis and Processing of Materials for Lithium-Ion Batteries
journal, July 2018

Spark Plasma Sintering of Lithium Aluminum Germanium Phosphate Solid Electrolyte and its Electrochemical Properties
journal, July 2019

Spark Plasma Sintering of Lithium Aluminum Germanium Phosphate Solid Electrolyte and its Electrochemical Properties
text, January 2019