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Title: Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review

Abstract

Unlike the revolutionary advances in the anodes of lithium-ion batteries from Li intercalation materials to Li alloy and/or conversion reaction materials, the development of the cathode is still dominated by the Li intercalation compounds. Transition metal ions are essential in these cathodes as the rapid redox reaction centers, and one of the biggest challenges for the TM-based cathodes is the capacity and power fading especially at an elevated temperature, which is directly associated with the dissolution–migration–deposition (DMD) process of TMs from the cathode materials. This process not only alters the surface structure of the cathode materials, but more importantly, changes the SEI composition at the anode side. There is no doubt that the TM-DMD issue should be addressed thoroughly to unlock the potential of these compounds to enable a prolonged battery lifetime. This review article mainly focuses on research activities with regard to the DMD process in TM-based cathode materials. In the first four sections, we choose Mn-based cathodes as an example to discuss how Mn DMD relates to the capacity fade of the cell, and what possible approaches might suppress the DMD process by modification of the electrode or electrolyte. In the fifth section, we discuss the TM DMDmore » process in Ni-, Co-, Fe- and V-containing cathode materials. Furthermore, this article reviews the frontier electrochemical research on TM-based cathodes and summarizes the progress and challenges, thereby helping to advance future R&D of LIBs.« less

Authors:
 [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1426189
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 11; Journal Issue: 2; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Zhan, Chun, Wu, Tianpin, Lu, Jun, and Amine, Khalil. Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review. United States: N. p., 2017. Web. doi:10.1039/c7ee03122j.
Zhan, Chun, Wu, Tianpin, Lu, Jun, & Amine, Khalil. Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review. United States. doi:10.1039/c7ee03122j.
Zhan, Chun, Wu, Tianpin, Lu, Jun, and Amine, Khalil. Thu . "Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review". United States. doi:10.1039/c7ee03122j. https://www.osti.gov/servlets/purl/1426189.
@article{osti_1426189,
title = {Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review},
author = {Zhan, Chun and Wu, Tianpin and Lu, Jun and Amine, Khalil},
abstractNote = {Unlike the revolutionary advances in the anodes of lithium-ion batteries from Li intercalation materials to Li alloy and/or conversion reaction materials, the development of the cathode is still dominated by the Li intercalation compounds. Transition metal ions are essential in these cathodes as the rapid redox reaction centers, and one of the biggest challenges for the TM-based cathodes is the capacity and power fading especially at an elevated temperature, which is directly associated with the dissolution–migration–deposition (DMD) process of TMs from the cathode materials. This process not only alters the surface structure of the cathode materials, but more importantly, changes the SEI composition at the anode side. There is no doubt that the TM-DMD issue should be addressed thoroughly to unlock the potential of these compounds to enable a prolonged battery lifetime. This review article mainly focuses on research activities with regard to the DMD process in TM-based cathode materials. In the first four sections, we choose Mn-based cathodes as an example to discuss how Mn DMD relates to the capacity fade of the cell, and what possible approaches might suppress the DMD process by modification of the electrode or electrolyte. In the fifth section, we discuss the TM DMD process in Ni-, Co-, Fe- and V-containing cathode materials. Furthermore, this article reviews the frontier electrochemical research on TM-based cathodes and summarizes the progress and challenges, thereby helping to advance future R&D of LIBs.},
doi = {10.1039/c7ee03122j},
journal = {Energy & Environmental Science},
number = 2,
volume = 11,
place = {United States},
year = {2017},
month = {12}
}

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    Works referencing / citing this record:

    Three-dimensional SWCNT and MWCNT hybrid networks for extremely high-loading and high rate cathode materials
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    • Journal of Materials Chemistry A, Vol. 7, Issue 29
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    Three-dimensional SWCNT and MWCNT hybrid networks for extremely high-loading and high rate cathode materials
    journal, January 2019

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    • Journal of Materials Chemistry A, Vol. 7, Issue 29
    • DOI: 10.1039/c9ta03870a