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Title: Grand Challenges and Future Opportunities for Metal–Organic Frameworks

Abstract

Metal–organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Department of Chemistry
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1426158
Grant/Contract Number:  
SC0001088; SC0001299
Resource Type:
Accepted Manuscript
Journal Name:
ACS Central Science
Additional Journal Information:
Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2374-7943
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hendon, Christopher H., Rieth, Adam J., Korzyński, Maciej D., and Dincă, Mircea. Grand Challenges and Future Opportunities for Metal–Organic Frameworks. United States: N. p., 2017. Web. doi:10.1021/acscentsci.7b00197.
Hendon, Christopher H., Rieth, Adam J., Korzyński, Maciej D., & Dincă, Mircea. Grand Challenges and Future Opportunities for Metal–Organic Frameworks. United States. https://doi.org/10.1021/acscentsci.7b00197
Hendon, Christopher H., Rieth, Adam J., Korzyński, Maciej D., and Dincă, Mircea. Tue . "Grand Challenges and Future Opportunities for Metal–Organic Frameworks". United States. https://doi.org/10.1021/acscentsci.7b00197. https://www.osti.gov/servlets/purl/1426158.
@article{osti_1426158,
title = {Grand Challenges and Future Opportunities for Metal–Organic Frameworks},
author = {Hendon, Christopher H. and Rieth, Adam J. and Korzyński, Maciej D. and Dincă, Mircea},
abstractNote = {Metal–organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications.},
doi = {10.1021/acscentsci.7b00197},
journal = {ACS Central Science},
number = 6,
volume = 3,
place = {United States},
year = {Tue Jun 06 00:00:00 EDT 2017},
month = {Tue Jun 06 00:00:00 EDT 2017}
}

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  • DOI: 10.1039/c8ce00806j

Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine
journal, January 2018

  • Nagatomi, Hisanori; Yanai, Nobuhiro; Yamada, Teppei
  • Chemistry - A European Journal, Vol. 24, Issue 8
  • DOI: 10.1002/chem.201705530

Crystalline Kitaev spin liquids
journal, October 2017


Recent advances in two-dimensional-material-based sensing technology toward health and environmental monitoring applications
journal, January 2020

  • Tyagi, Deepika; Wang, Huide; Huang, Weichun
  • Nanoscale, Vol. 12, Issue 6
  • DOI: 10.1039/c9nr10178k

In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts
journal, December 2018

  • Gao, Wen‐Yang; Cardenal, Ashley D.; Wang, Chen‐Hao
  • Chemistry – A European Journal, Vol. 25, Issue 14
  • DOI: 10.1002/chem.201804490

Layer-by-layer integration of conducting polymers and metal organic frameworks onto electrode surfaces: enhancement of the oxygen reduction reaction through electrocatalytic nanoarchitectonics
journal, January 2019

  • Mártire, Ana Paula; Segovia, Gustavo M.; Azzaroni, Omar
  • Molecular Systems Design & Engineering, Vol. 4, Issue 4
  • DOI: 10.1039/c9me00007k

Catalytic Transfer Hydrogenation of Biomass-Derived Carbonyls over Hafnium-Based Metal-Organic Frameworks
journal, December 2017

  • Rojas-Buzo, Sergio; García-García, Pilar; Corma, Avelino
  • ChemSusChem, Vol. 11, Issue 2
  • DOI: 10.1002/cssc.201701708

Low‐Dimensional Metal‐Organic Frameworks and their Diverse Functional Roles in Catalysis
journal, May 2019


Robust Ultramicroporous Metal-Organic Frameworks with Benchmark Affinity for Acetylene
journal, July 2018

  • Peng, Yun-Lei; Pham, Tony; Li, Pengfei
  • Angewandte Chemie International Edition, Vol. 57, Issue 34
  • DOI: 10.1002/anie.201806732

Proton Conductivity of Composite Polyelectrolyte Membranes with Metal‐Organic Frameworks for Fuel Cell Applications
journal, December 2018

  • Escorihuela, Jorge; Narducci, Riccardo; Compañ, Vicente
  • Advanced Materials Interfaces
  • DOI: 10.1002/admi.201801146

Electrically Conducting Nanocomposites of Carbon Nanotubes and Metal‐Organic Frameworks with Strong Interactions between the two Components
journal, July 2019

  • Schulze, Hendrik A.; Hoppe, Bastian; Schäfer, Malte
  • ChemNanoMat, Vol. 5, Issue 9
  • DOI: 10.1002/cnma.201900110

Ultrafast Synthesis of Ni-MOF in One Minute by Ball Milling
journal, December 2018

  • Zhang, Ren; Tao, Cheng-An; Chen, Rui
  • Nanomaterials, Vol. 8, Issue 12
  • DOI: 10.3390/nano8121067

Metal-Organic Frameworks for the Development of Biosensors: A Current Overview
journal, October 2018


Crisscrossing coordination networks: ligand doping to control the chemomechanical properties of stimuli-responsive metallogels
journal, January 2019

  • Kim, Junghwan; Lee, Dongwhan
  • Chemical Science, Vol. 10, Issue 13
  • DOI: 10.1039/c8sc05480k

Insights into Selective Gas Sorbent Functionality Gained by Using Time-Resolved Neutron Diffraction
journal, May 2018

  • Auckett, Josie E.; Duyker, Samuel G.; Turner, David R.
  • ChemPlusChem, Vol. 83, Issue 7
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Regulation of the Degree of Interpenetration in Metal–Organic Frameworks
journal, December 2019

  • Verma, Gaurav; Butikofer, Sydney; Kumar, Sanjay
  • Topics in Current Chemistry, Vol. 378, Issue 1
  • DOI: 10.1007/s41061-019-0268-x

Metal-Organic-Framework-Derived Co 3 S 4 Hollow Nanoboxes for the Selective Reduction of Nitroarenes
journal, August 2018


Anisotropic Thermal and Guest-Induced Responses of an Ultramicroporous Framework with Rigid Linkers
journal, March 2018

  • Auckett, Josie E.; Duyker, Samuel G.; Izgorodina, Ekaterina I.
  • Chemistry - A European Journal, Vol. 24, Issue 19
  • DOI: 10.1002/chem.201800261

Two-Dimensional Co@N-Carbon Nanocomposites Facilely Derived from Metal-Organic Framework Nanosheets for Efficient Bifunctional Electrocatalysis
journal, May 2018

  • Cong, Jingkun; Xu, Hui; Lu, Mengting
  • Chemistry - An Asian Journal, Vol. 13, Issue 11
  • DOI: 10.1002/asia.201800319

Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal-Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica
journal, June 2018

  • Luz, Ignacio; Soukri, Mustapha; Lail, Marty
  • Chemistry - A European Journal, Vol. 24, Issue 42
  • DOI: 10.1002/chem.201800612

Self-adjusting binding pockets enhance H 2 and CH 4 adsorption in a uranium-based metal–organic framework
journal, January 2020

  • Halter, Dominik P.; Klein, Ryan A.; Boreen, Michael A.
  • Chemical Science
  • DOI: 10.1039/d0sc02394a

The Chemistry of Reticular Framework Nanoparticles: MOF, ZIF, and COF Materials
journal, February 2020

  • Ploetz, Evelyn; Engelke, Hanna; Lächelt, Ulrich
  • Advanced Functional Materials, Vol. 30, Issue 41
  • DOI: 10.1002/adfm.201909062

Crystal structure of catena-poly[diaqua-(μ2-1,2-bis(4-pyridinyl)ethyane-κ2N:N′)-(μ2–pyridazine-4,5-dicarboxylato-κ2O:O′)]dizinc(II) dihydrate, C12H12ZnN3O6
journal, March 2019

  • Feng-Yang, Ju; Ke-Xin, Ding; Fang, Liu
  • Zeitschrift für Kristallographie - New Crystal Structures, Vol. 234, Issue 3
  • DOI: 10.1515/ncrs-2018-0565

Aspects of semiconductivity in soft, porous metal-organic framework crystals
journal, July 2019

  • Muschielok, Christoph; Oberhofer, Harald
  • The Journal of Chemical Physics, Vol. 151, Issue 1
  • DOI: 10.1063/1.5108995

MOFs for Electrocatalysis: From Serendipity to Design Strategies
journal, December 2018

  • Aiyappa, Harshitha Barike; Masa, Justus; Andronescu, Corina
  • Small Methods, Vol. 3, Issue 8
  • DOI: 10.1002/smtd.201800415

Schalten in Metall‐organischen Gerüsten
journal, December 2019


Interpenetration Isomerism in Triptycene-Based Hydrogen-Bonded Organic Frameworks
journal, January 2019

  • Li, Penghao; Li, Peng; Ryder, Matthew R.
  • Angewandte Chemie International Edition, Vol. 58, Issue 6
  • DOI: 10.1002/anie.201811263

The role of reticular chemistry in the design of CO2 reduction catalysts
journal, February 2018


Structural Basis of CO2 Adsorption in a Flexible Metal-Organic Framework Material
journal, March 2019

  • Allen, Andrew; Wong-Ng, Winnie; Cockayne, Eric
  • Nanomaterials, Vol. 9, Issue 3
  • DOI: 10.3390/nano9030354

Metal–Organic Frameworks for Electrocatalysis
book, January 2020

  • Usman, Muhammad; Zhu, Qi-Long
  • Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 29-66
  • DOI: 10.1007/978-3-030-27161-9_2

Enhancing the photoluminescence of surface anchored metal–organic frameworks: mixed linkers and efficient acceptors
journal, January 2018

  • Oldenburg, M.; Turshatov, A.; Busko, D.
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 17
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A Metal-Organic Framework with Exceptional Activity for C−H Bond Amination
journal, December 2017


Defect Creation in HKUST-1 via Molecular Imprinting: Attaining Anionic Framework Property and Mesoporosity for Cation Exchange Applications
journal, September 2017

  • Tan, Ying Chuan; Zeng, Hua Chun
  • Advanced Functional Materials, Vol. 27, Issue 42
  • DOI: 10.1002/adfm.201703765

Coordination driven architectures based on metalloligands offering appended carboxylic acid groups
journal, July 2018


Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis
journal, January 2020

  • Zhao, Kuangmin; Zhu, Weiwei; Liu, Suqin
  • Nanoscale Advances, Vol. 2, Issue 2
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Switching in Metal–Organic Frameworks
journal, December 2019

  • Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali
  • Angewandte Chemie International Edition, Vol. 59, Issue 12
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Supramolecular organization in confined nanospaces
text, January 2021


A Metal-Organic Framework with Exceptional Activity for C−H Bond Amination
journal, December 2017

  • Wang, Le; Agnew, Douglas W.; Yu, Xiao
  • Angewandte Chemie International Edition, Vol. 57, Issue 2
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Supramolecular organization in confined nanospaces
text, January 2018


Robust Ultramicroporous Metal-Organic Frameworks with Benchmark Affinity for Acetylene
journal, July 2018


Stack the Bowls: Tailoring the Electronic Structure of Corannulene-Integrated Crystalline Materials
journal, July 2018

  • Rice, Allison M.; Dolgopolova, Ekaterina A.; Yarbrough, Brandon J.
  • Angewandte Chemie, Vol. 130, Issue 35
  • DOI: 10.1002/ange.201806202

Supramolecular organization in confined nanospaces
text, January 2021


Two-Dimensional Band Structure in Honeycomb Metal–Organic Frameworks
journal, August 2018


Host–Guest Chemistry Meets Electrocatalysis: Cucurbit[6]uril on a Au Surface as a Hybrid System in CO2 Reduction
journal, November 2019


The Future of Molecular Machines
journal, March 2020


Reticular Chemistry in All Dimensions
journal, July 2019


Metal Substitution as the Method of Modifying Electronic Structure of Metal–Organic Frameworks
journal, March 2019

  • Syzgantseva, Maria A.; Ireland, Christopher Patrick; Ebrahim, Fatmah Mish
  • Journal of the American Chemical Society, Vol. 141, Issue 15
  • DOI: 10.1021/jacs.8b13667

Metal-Organic Frameworks for the Development of Biosensors: A Current Overview
journal, October 2018


The Tuning of Optical Properties of Nanoscale MOFs-Based Thin Film through Post-Modification
journal, August 2017

  • Yin, Wenchang; Tao, Cheng-an; Zou, Xiaorong
  • Nanomaterials, Vol. 7, Issue 9
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Tunable Metal–Organic Frameworks for Heat Transformation Applications
journal, August 2018

  • Chaemchuen, Somboon; Xiao, Xuan; Klomkliang, Nikom
  • Nanomaterials, Vol. 8, Issue 9
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Ultrafast Synthesis of Ni-MOF in One Minute by Ball Milling
journal, December 2018

  • Zhang, Ren; Tao, Cheng-An; Chen, Rui
  • Nanomaterials, Vol. 8, Issue 12
  • DOI: 10.3390/nano8121067