Grand Challenges and Future Opportunities for Metal–Organic Frameworks
Abstract
Metal–organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications.
- Authors:
-
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Department of Chemistry
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1426158
- Grant/Contract Number:
- SC0001088; SC0001299
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Central Science
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2374-7943
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Hendon, Christopher H., Rieth, Adam J., Korzyński, Maciej D., and Dincă, Mircea. Grand Challenges and Future Opportunities for Metal–Organic Frameworks. United States: N. p., 2017.
Web. doi:10.1021/acscentsci.7b00197.
Hendon, Christopher H., Rieth, Adam J., Korzyński, Maciej D., & Dincă, Mircea. Grand Challenges and Future Opportunities for Metal–Organic Frameworks. United States. https://doi.org/10.1021/acscentsci.7b00197
Hendon, Christopher H., Rieth, Adam J., Korzyński, Maciej D., and Dincă, Mircea. Tue .
"Grand Challenges and Future Opportunities for Metal–Organic Frameworks". United States. https://doi.org/10.1021/acscentsci.7b00197. https://www.osti.gov/servlets/purl/1426158.
@article{osti_1426158,
title = {Grand Challenges and Future Opportunities for Metal–Organic Frameworks},
author = {Hendon, Christopher H. and Rieth, Adam J. and Korzyński, Maciej D. and Dincă, Mircea},
abstractNote = {Metal–organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications.},
doi = {10.1021/acscentsci.7b00197},
journal = {ACS Central Science},
number = 6,
volume = 3,
place = {United States},
year = {Tue Jun 06 00:00:00 EDT 2017},
month = {Tue Jun 06 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Nanochemistry: Synthesis in diminishing dimensions
journal, October 1992
- Ozin, Geoffrey A.
- Advanced Materials, Vol. 4, Issue 10
New vistas in zeolite and molecular sieve catalysis
journal, March 1993
- Davis, Mark E.
- Accounts of Chemical Research, Vol. 26, Issue 3
Investigation of internal silanol groups as structural defects in ZSM-5-type zeolites
journal, January 1987
- Hunger, Michael; Kärger, Jörg; Pfeifer, Harry
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 83, Issue 11
Defect sites in highly siliceous HZSM-5 zeolites: a study performed by alumination and IR spectroscopy
journal, January 1991
- Yamagishi, Kouji; Namba, Seitaro; Yashima, Tatsuaki
- The Journal of Physical Chemistry, Vol. 95, Issue 2
Electroactive Nanoporous Metal Oxides and Chalcogenides by Chemical Design
journal, April 2017
- Hendon, Christopher H.; Butler, Keith T.; Ganose, Alex M.
- Chemistry of Materials, Vol. 29, Issue 8
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Band alignment at metal/organic and metal/oxide/organic interfaces
journal, November 2008
- Helander, M. G.; Wang, Z. B.; Qiu, J.
- Applied Physics Letters, Vol. 93, Issue 19
Energy level alignment at metal/organic semiconductor interfaces: “Pillow” effect, induced density of interface states, and charge neutrality level
journal, April 2007
- Vázquez, H.; Dappe, Y. J.; Ortega, J.
- The Journal of Chemical Physics, Vol. 126, Issue 14
Surface Chemistry of Metal-Organic Frameworks at the Liquid-Solid Interface
journal, December 2010
- Zacher, Denise; Schmid, Rochus; Wöll, Christof
- Angewandte Chemie International Edition, Vol. 50, Issue 1
Postsynthetic tuning of hydrophilicity in pyrazolate MOFs to modulate water adsorption properties
journal, January 2013
- Wade, Casey R.; Corrales-Sanchez, Tachmajal; Narayan, Tarun C.
- Energy & Environmental Science, Vol. 6, Issue 7
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
Gas storage in porous metal–organic frameworks for clean energy applications
journal, January 2010
- Ma, Shengqian; Zhou, Hong-Cai
- Chem. Commun., Vol. 46, Issue 1
Tuning MOF CO 2 Adsorption Properties via Cation Exchange
journal, April 2010
- An, Jihyun; Rosi, Nathaniel L.
- Journal of the American Chemical Society, Vol. 132, Issue 16
Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009
- Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
Separation of Hydrocarbons with a Microporous Metal-Organic Framework
journal, January 2006
- Pan, Long; Olson, David H.; Ciemnolonski, Lauren R.
- Angewandte Chemie, Vol. 118, Issue 4, p. 632-635
Can Metal-Organic Framework Materials Play a Useful Role in Large-Scale Carbon Dioxide Separations?
journal, August 2010
- Keskin, Seda; van Heest, Timothy M.; Sholl, David S.
- ChemSusChem, Vol. 3, Issue 8
Installing Heterobimetallic Cobalt–Aluminum Single Sites on a Metal Organic Framework Support
journal, September 2016
- Thompson, Anthony B.; Pahls, Dale R.; Bernales, Varinia
- Chemistry of Materials, Vol. 28, Issue 18
An Exceptionally Stable Metal–Organic Framework Supported Molybdenum(VI) Oxide Catalyst for Cyclohexene Epoxidation
journal, October 2016
- Noh, Hyunho; Cui, Yuexing; Peters, Aaron W.
- Journal of the American Chemical Society, Vol. 138, Issue 44
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016
- Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J.
- ACS Central Science, Vol. 2, Issue 3
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
journal, June 2015
- Yang, Dong; Odoh, Samuel O.; Wang, Timothy C.
- Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396
Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework
journal, August 2016
- Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J.
- Journal of the American Chemical Society, Vol. 138, Issue 32
Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation
journal, February 2012
- Lu, Guang; Li, Shaozhou; Guo, Zhen
- Nature Chemistry, Vol. 4, Issue 4, p. 310-316
Semiconductor Behavior of a Metal-Organic Framework (MOF)
journal, June 2007
- Alvaro, Mercedes; Carbonell, Esther; Ferrer, Belén
- Chemistry - A European Journal, Vol. 13, Issue 18
Conductive metal–organic frameworks and networks: fact or fantasy?
journal, January 2012
- Hendon, Christopher H.; Tiana, Davide; Walsh, Aron
- Physical Chemistry Chemical Physics, Vol. 14, Issue 38, p. 13120-13132
Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015
- Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
- Angewandte Chemie International Edition, Vol. 54, Issue 14
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Supercapacitors of Nanocrystalline Metal–Organic Frameworks
journal, June 2014
- Choi, Kyung Min; Jeong, Hyung Mo; Park, Jung Hyo
- ACS Nano, Vol. 8, Issue 7
Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016
- Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.
- Nature Materials, Vol. 16, Issue 2
Bottom-up construction of a superstructure in a porous uranium-organic crystal
journal, April 2017
- Li, Peng; Vermeulen, Nicolaas A.; Malliakas, Christos D.
- Science, Vol. 356, Issue 6338
Principles of Designing Extra-Large Pore Openings and Cages in Zeolitic Imidazolate Frameworks
journal, April 2017
- Yang, Jingjing; Zhang, Yue-Biao; Liu, Qi
- Journal of the American Chemical Society, Vol. 139, Issue 18
A supermolecular building approach for the design and construction of metal–organic frameworks
journal, January 2014
- Guillerm, Vincent; Kim, Dongwook; Eubank, Jarrod F.
- Chem. Soc. Rev., Vol. 43, Issue 16
Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013
- Kong, X.; Deng, H.; Yan, F.
- Science, Vol. 341, Issue 6148, p. 882-885
Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015
- Brozek, Carl K.; Michaelis, Vladimir K.; Ong, Ta-Chung
- ACS Central Science, Vol. 1, Issue 5
Synthesis and Characterization of Metal–Organic Framework-74 Containing 2, 4, 6, 8, and 10 Different Metals
journal, May 2014
- Wang, Lisa J.; Deng, Hexiang; Furukawa, Hiroyasu
- Inorganic Chemistry, Vol. 53, Issue 12, p. 5881-5883
Shape-selective catalysis in zeolites
journal, July 1984
- Csicsery, Sigmund M.
- Zeolites, Vol. 4, Issue 3
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009
- Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
Microporous Brookite-Phase Titania Made by Replication of a Metal–Organic Framework
journal, October 2013
- Hall, Anthony Shoji; Kondo, Atsushi; Maeda, Kazuyuki
- Journal of the American Chemical Society, Vol. 135, Issue 44
Metal-Organic Framework as a Template for Porous Carbon Synthesis
journal, April 2008
- Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki
- Journal of the American Chemical Society, Vol. 130, Issue 16
Thermal Stabilization of Metal–Organic Framework-Derived Single-Site Catalytic Clusters through Nanocasting
journal, February 2016
- Malonzo, Camille D.; Shaker, Sammy M.; Ren, Limin
- Journal of the American Chemical Society, Vol. 138, Issue 8
Synthesis and applications of metal-organic framework–quantum dot (QD@MOF) composites
journal, January 2016
- Aguilera-Sigalat, Jordi; Bradshaw, Darren
- Coordination Chemistry Reviews, Vol. 307
Energy Transfer Dynamics in Metal−Organic Frameworks
journal, September 2010
- Kent, Caleb A.; Mehl, Brian P.; Ma, Liqing
- Journal of the American Chemical Society, Vol. 132, Issue 37
Amplified Luminescence Quenching of Phosphorescent Metal–Organic Frameworks
journal, February 2012
- Kent, Caleb A.; Liu, Demin; Meyer, Thomas J.
- Journal of the American Chemical Society, Vol. 134, Issue 9
Pt Nanoparticles@Photoactive Metal–Organic Frameworks: Efficient Hydrogen Evolution via Synergistic Photoexcitation and Electron Injection
journal, April 2012
- Wang, Cheng; deKrafft, Kathryn E.; Lin, Wenbin
- Journal of the American Chemical Society, Vol. 134, Issue 17
Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission
journal, December 2011
- Shustova, Natalia B.; McCarthy, Brian D.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 133, Issue 50
Benchmark C 2 H 2 /CO 2 and CO 2 /C 2 H 2 Separation by Two Closely Related Hybrid Ultramicroporous Materials
journal, November 2016
- Chen, Kai-Jie; Scott, Hayley S.; Madden, David G.
- Chem, Vol. 1, Issue 5
Guest Shape-Responsive Fitting of Porous Coordination Polymer with Shrinkable Framework
journal, November 2004
- Matsuda, Ryotaro; Kitaura, Ryo; Kitagawa, Susumu
- Journal of the American Chemical Society, Vol. 126, Issue 43
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013
- Herm, Z. R.; Wiers, B. M.; Mason, J. A.
- Science, Vol. 340, Issue 6135, p. 960-964
Hybrid Zeolitic Imidazolate Frameworks: Controlling Framework Porosity and Functionality by Mixed-Linker Synthesis
journal, April 2012
- Thompson, Joshua A.; Blad, Catherine R.; Brunelli, Nicholas A.
- Chemistry of Materials, Vol. 24, Issue 10
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010
- Deng, H.; Doonan, C. J.; Furukawa, H.
- Science, Vol. 327, Issue 5967, p. 846-850
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Evaluating metal–organic frameworks for natural gas storage
journal, January 2014
- Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R.
- Chemical Science, Vol. 5, Issue 1, p. 32-51
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
journal, May 2016
- Cui, X.; Chen, K.; Xing, H.
- Science, Vol. 353, Issue 6295
Strong H 2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg 3 (O 2 C-C 10 H 6 -CO 2 ) 3
journal, July 2005
- Dincǎ, Mircea; Long, Jeffrey R.
- Journal of the American Chemical Society, Vol. 127, Issue 26
Selective nitrogen capture by porous hybrid materials containing accessible transition metal ion sites
journal, December 2016
- Yoon, Ji Woong; Chang, Hyunju; Lee, Seung-Joon
- Nature Materials, Vol. 16, Issue 5
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015
- McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
- Nature, Vol. 519, Issue 7543
Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization
journal, July 2013
- Hendon, Christopher H.; Tiana, Davide; Fontecave, Marc
- Journal of the American Chemical Society, Vol. 135, Issue 30
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
journal, May 2009
- Couck, Sarah; Denayer, Joeri F. M.; Baron, Gino V.
- Journal of the American Chemical Society, Vol. 131, Issue 18
Direct Observation and Quantification of CO 2 Binding Within an Amine-Functionalized Nanoporous Solid
journal, October 2010
- Vaidhyanathan, Ramanathan; Iremonger, Simon S.; Shimizu, George K. H.
- Science, Vol. 330, Issue 6004
An amine-functionalized metal organic framework for preferential CO2 adsorption at low pressures
journal, January 2009
- Vaidhyanathan, Ramanathan; Iremonger, Simon S.; Dawson, Karl W.
- Chemical Communications, Issue 35
Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?
journal, June 2012
- Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim
- Journal of the American Chemical Society, Vol. 134, Issue 24
Benchmarking Quantum Chemical Methods for the Calculation of Molecular Dipole Moments and Polarizabilities
journal, May 2014
- Hickey, A. Leif; Rowley, Christopher N.
- The Journal of Physical Chemistry A, Vol. 118, Issue 20
Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
journal, January 2012
- Wade, Casey R.; Dincă, Mircea
- Dalton Transactions, Vol. 41, Issue 26
Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization
journal, October 2012
- Cmarik, Gregory E.; Kim, Min; Cohen, Seth M.
- Langmuir, Vol. 28, Issue 44
Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010
- Garibay, Sergio J.; Cohen, Seth M.
- Chemical Communications, Vol. 46, Issue 41, p. 7700-7702
Supercapacitive Swing Adsorption of Carbon Dioxide
journal, February 2014
- Kokoszka, Berenika; Jarrah, Nina K.; Liu, Cong
- Angewandte Chemie International Edition, Vol. 53, Issue 14
A study of the electrochemical behaviour of electrodes in operating solid-state supercapacitors
journal, December 2007
- Staiti, P.; Lufrano, F.
- Electrochimica Acta, Vol. 53, Issue 2
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
journal, October 2015
- Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M.
- Journal of the American Chemical Society, Vol. 137, Issue 43
Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
journal, February 2007
- Huang, B. L.; Ni, Z.; Millward, A.
- International Journal of Heat and Mass Transfer, Vol. 50, Issue 3-4, p. 405-411
Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity
journal, April 2015
- Erickson, Kristopher J.; Léonard, François; Stavila, Vitalie
- Advanced Materials, Vol. 27, Issue 22
Lewis Acid–Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries
journal, April 2014
- Zheng, Jianming; Tian, Jian; Wu, Dangxin
- Nano Letters, Vol. 14, Issue 5
Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties
journal, April 2007
- Férey, Gérard; Millange, Franck; Morcrette, Mathieu
- Angewandte Chemie International Edition, Vol. 46, Issue 18
MOF-based electronic and opto-electronic devices
journal, January 2014
- Stavila, V.; Talin, A. A.; Allendorf, M. D.
- Chem. Soc. Rev., Vol. 43, Issue 16
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
journal, March 2016
- Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis
- Nature Communications, Vol. 7, Issue 1
Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
journal, January 2017
- Wang, Wei; Xu, Xiaomin; Zhou, Wei
- Advanced Science, Vol. 4, Issue 4
A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
journal, September 2011
- Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie
- Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388
Frontier Orbital Engineering of Metal–Organic Frameworks with Extended Inorganic Connectivity: Porous Alkaline-Earth Oxides
journal, June 2016
- Hendon, Christopher H.; Walsh, Aron; Dincă, Mircea
- Inorganic Chemistry, Vol. 55, Issue 15
Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016
- Sun, Lei; Park, Sarah S.; Sheberla, Dennis
- Journal of the American Chemical Society, Vol. 138, Issue 44
Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
journal, May 2015
- Liu, Jinxuan; Zhou, Wencai; Liu, Jianxi
- Angewandte Chemie International Edition, Vol. 54, Issue 25
Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016
- Sun, Lei; Campbell, Michael G.; Dincă, Mircea
- Angewandte Chemie International Edition, Vol. 55, Issue 11
Is iron unique in promoting electrical conductivity in MOFs?
journal, January 2017
- Sun, Lei; Hendon, Christopher H.; Park, Sarah S.
- Chemical Science, Vol. 8, Issue 6
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012
- Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
- Journal of the American Chemical Society, Vol. 134, Issue 31
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015
- Park, Sarah S.; Hontz, Eric R.; Sun, Lei
- Journal of the American Chemical Society, Vol. 137, Issue 5
High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014
- Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
- Journal of the American Chemical Society, Vol. 136, Issue 25
Chemical principles for electroactive metal–organic frameworks
journal, November 2016
- Walsh, Aron; Butler, Keith T.; Hendon, Christopher H.
- MRS Bulletin, Vol. 41, Issue 11
Electronic Structure Modulation of Metal–Organic Frameworks for Hybrid Devices
journal, December 2014
- Butler, Keith T.; Hendon, Christopher H.; Walsh, Aron
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism
journal, December 2013
- Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E.
- Chemistry of Materials, Vol. 25, Issue 24
Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films
journal, October 2013
- Wade, Casey R.; Li, Minyuan; Dincă, Mircea
- Angewandte Chemie International Edition, Vol. 52, Issue 50
Million-Fold Electrical Conductivity Enhancement in Fe 2 (DEBDC) versus Mn 2 (DEBDC) (E = S, O)
journal, May 2015
- Sun, Lei; Hendon, Christopher H.; Minier, Mikael A.
- Journal of the American Chemical Society, Vol. 137, Issue 19
Electronic Chemical Potentials of Porous Metal–Organic Frameworks
journal, February 2014
- Butler, Keith T.; Hendon, Christopher H.; Walsh, Aron
- Journal of the American Chemical Society, Vol. 136, Issue 7
Computational Screening of All Stoichiometric Inorganic Materials
journal, October 2016
- Davies, Daniel W.; Butler, Keith T.; Jackson, Adam J.
- Chem, Vol. 1, Issue 4
Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011
- Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
- Nature Chemistry, Vol. 4, Issue 2, p. 83-89
Correlated defect nanoregions in a metal–organic framework
journal, June 2014
- Cliffe, Matthew J.; Wan, Wei; Zou, Xiaodong
- Nature Communications, Vol. 5, Issue 1
A Highly Active Well-Defined Rhenium Heterogeneous Catalyst for Olefin Metathesis Prepared via Surface Organometallic Chemistry
journal, March 2001
- Chabanas, Mathieu; Baudouin, Anne; Copéret, Christophe
- Journal of the American Chemical Society, Vol. 123, Issue 9
Spectroscopic and structural characterization of Cr(II)/SiO2 active site precursors in model Phillips polymerization catalysts
journal, September 2012
- Zhong, Lei; Lee, Ming-Yung; Liu, Zhen
- Journal of Catalysis, Vol. 293
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Structural Transitions of the Metal-Oxide Nodes within Metal–Organic Frameworks: On the Local Structures of NU-1000 and UiO-66
journal, March 2016
- Platero-Prats, Ana E.; Mavrandonakis, Andreas; Gallington, Leighanne C.
- Journal of the American Chemical Society, Vol. 138, Issue 12
Post-synthetic metalation of metal–organic frameworks
journal, January 2014
- Evans, Jack D.; Sumby, Christopher J.; Doonan, Christian J.
- Chem. Soc. Rev., Vol. 43, Issue 16
Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation
journal, April 2014
- Guo, Zhiyong; Xiao, Chaoxian; Maligal-Ganesh, Raghu V.
- ACS Catalysis, Vol. 4, Issue 5, p. 1340-1348
Facile synthesis of multiple enzyme-containing metal–organic frameworks in a biomolecule-friendly environment
journal, January 2015
- Wu, Xiaoling; Ge, Jun; Yang, Cheng
- Chemical Communications, Vol. 51, Issue 69
Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013
- Brozek, Carl K.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 135, Issue 34
Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks
journal, March 2009
- Das, Sunirban; Kim, Hyunuk; Kim, Kimoon
- Journal of the American Chemical Society, Vol. 131, Issue 11
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012
- Kim, Min; Cahill, John F.; Fei, Honghan
- Journal of the American Chemical Society, Vol. 134, Issue 43
A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts
journal, April 2009
- Shultz, Abraham M.; Farha, Omar K.; Hupp, Joseph T.
- Journal of the American Chemical Society, Vol. 131, Issue 12, p. 4204-4205
Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks
journal, December 2012
- Son, Ho-Jin; Jin, Shengye; Patwardhan, Sameer
- Journal of the American Chemical Society, Vol. 135, Issue 2
Heterogeneous Epoxide Carbonylation by Cooperative Ion-Pair Catalysis in Co(CO) 4 – -Incorporated Cr-MIL-101
journal, March 2017
- Park, Hoyoung D.; Dincă, Mircea; Román-Leshkov, Yuriy
- ACS Central Science, Vol. 3, Issue 5
Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperature
journal, November 2016
- Li, Zhanyong; Peters, Aaron W.; Bernales, Varinia
- ACS Central Science, Vol. 3, Issue 1
Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014
- Brozek, C. K.; Dincă, M.
- Chem. Soc. Rev., Vol. 43, Issue 16
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework
journal, February 2016
- Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B.
- Journal of the American Chemical Society, Vol. 138, Issue 6
Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions
journal, October 2016
- Gallington, Leighanne C.; Kim, In Soo; Liu, Wei-Guang
- Journal of the American Chemical Society, Vol. 138, Issue 41
Metal–Organic Framework Nodes Support Single-Site Magnesium–Alkyl Catalysts for Hydroboration and Hydroamination Reactions
journal, June 2016
- Manna, Kuntal; Ji, Pengfei; Greene, Francis X.
- Journal of the American Chemical Society, Vol. 138, Issue 24
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
journal, May 2014
- Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena
- Angewandte Chemie International Edition, Vol. 53, Issue 23
Structural models for the metal centers in the nitrogenase molybdenum-iron protein
journal, September 1992
- Kim, J.; Rees, D.
- Science, Vol. 257, Issue 5077
Electrically Induced Breathing of the MIL-53(Cr) Metal–Organic Framework
journal, April 2017
- Ghoufi, Aziz; Benhamed, Karima; Boukli-Hacene, Leila
- ACS Central Science, Vol. 3, Issue 5
A pressure-amplifying framework material with negative gas adsorption transitions
journal, April 2016
- Krause, Simon; Bon, Volodymyr; Senkovska, Irena
- Nature, Vol. 532, Issue 7599
Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
journal, March 2007
- Serre, C.; Mellot-Draznieks, C.; Surble, S.
- Science, Vol. 315, Issue 5820
Monodentate hydroxide as a super strong yet reversible active site for CO 2 capture from high-humidity flue gas
journal, January 2015
- Liao, Pei-Qin; Chen, Huayao; Zhou, Dong-Dong
- Energy & Environmental Science, Vol. 8, Issue 3
Non-Heme Fe(IV)–Oxo Intermediates
journal, July 2007
- Krebs, Carsten; Galonić Fujimori, Danica; Walsh, Christopher T.
- Accounts of Chemical Research, Vol. 40, Issue 7
Heterogeneous Catalytic Oxidation by MFU-1: A Cobalt(II)-Containing Metal-Organic Framework
journal, September 2009
- Tonigold, Markus; Lu, Ying; Bredenkötter, Björn
- Angewandte Chemie International Edition, Vol. 48, Issue 41
Pyrazolate-Based Cobalt(II)-Containing Metal-Organic Frameworks in Heterogeneous Catalytic Oxidation Reactions: Elucidating the Role of Entatic States for Biomimetic Oxidation Processes
journal, June 2011
- Tonigold, Markus; Lu, Ying; Mavrandonakis, Andreas
- Chemistry - A European Journal, Vol. 17, Issue 31
Nanochemistry: Synthesis in diminishing dimensions
journal, October 1992
- Ozin, Geoffrey A.
- Advanced Materials, Vol. 4, Issue 10
Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity
journal, April 2015
- Erickson, Kristopher J.; Léonard, François; Stavila, Vitalie
- Advanced Materials, Vol. 27, Issue 22
Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
journal, January 2017
- Wang, Wei; Xu, Xiaomin; Zhou, Wei
- Advanced Science, Vol. 4, Issue 4
Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties
journal, April 2007
- Férey, Gérard; Millange, Franck; Morcrette, Mathieu
- Angewandte Chemie, Vol. 119, Issue 18
Supercapacitive Swing Adsorption of Carbon Dioxide
journal, February 2014
- Kokoszka, Berenika; Jarrah, Nina K.; Liu, Cong
- Angewandte Chemie, Vol. 126, Issue 14
Separation of Hydrocarbons with a Microporous Metal-Organic Framework
journal, January 2006
- Pan, Long; Olson, David H.; Ciemnolonski, Lauren R.
- Angewandte Chemie International Edition, Vol. 45, Issue 4
Heterogeneous Catalytic Oxidation by MFU-1: A Cobalt(II)-Containing Metal-Organic Framework
journal, September 2009
- Tonigold, Markus; Lu, Ying; Bredenkötter, Björn
- Angewandte Chemie International Edition, Vol. 48, Issue 41
Surface Chemistry of Metal-Organic Frameworks at the Liquid-Solid Interface
journal, December 2010
- Zacher, Denise; Schmid, Rochus; Wöll, Christof
- Angewandte Chemie International Edition, Vol. 50, Issue 1
Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
journal, May 2015
- Liu, Jinxuan; Zhou, Wencai; Liu, Jianxi
- Angewandte Chemie International Edition, Vol. 54, Issue 25
Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016
- Sun, Lei; Campbell, Michael G.; Dincă, Mircea
- Angewandte Chemie International Edition, Vol. 55, Issue 11
Semiconductor Behavior of a Metal-Organic Framework (MOF)
journal, June 2007
- Alvaro, Mercedes; Carbonell, Esther; Ferrer, Belén
- Chemistry - A European Journal, Vol. 13, Issue 18
Pyrazolate-Based Cobalt(II)-Containing Metal-Organic Frameworks in Heterogeneous Catalytic Oxidation Reactions: Elucidating the Role of Entatic States for Biomimetic Oxidation Processes
journal, June 2011
- Tonigold, Markus; Lu, Ying; Mavrandonakis, Andreas
- Chemistry - A European Journal, Vol. 17, Issue 31
A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
journal, September 2011
- Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie
- Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388
Can Metal-Organic Framework Materials Play a Useful Role in Large-Scale Carbon Dioxide Separations?
journal, August 2010
- Keskin, Seda; van Heest, Timothy M.; Sholl, David S.
- ChemSusChem, Vol. 3, Issue 8
Shape-selective catalysis in zeolites
journal, July 1984
- Csicsery, Sigmund M.
- Zeolites, Vol. 4, Issue 3
Synthesis and applications of metal-organic framework–quantum dot (QD@MOF) composites
journal, January 2016
- Aguilera-Sigalat, Jordi; Bradshaw, Darren
- Coordination Chemistry Reviews, Vol. 307
Computational Screening of All Stoichiometric Inorganic Materials
journal, October 2016
- Davies, Daniel W.; Butler, Keith T.; Jackson, Adam J.
- Chem, Vol. 1, Issue 4
Benchmark C 2 H 2 /CO 2 and CO 2 /C 2 H 2 Separation by Two Closely Related Hybrid Ultramicroporous Materials
journal, November 2016
- Chen, Kai-Jie; Scott, Hayley S.; Madden, David G.
- Chem, Vol. 1, Issue 5
A study of the electrochemical behaviour of electrodes in operating solid-state supercapacitors
journal, December 2007
- Staiti, P.; Lufrano, F.
- Electrochimica Acta, Vol. 53, Issue 2
Spectroscopic and structural characterization of Cr(II)/SiO2 active site precursors in model Phillips polymerization catalysts
journal, September 2012
- Zhong, Lei; Lee, Ming-Yung; Liu, Zhen
- Journal of Catalysis, Vol. 293
All solid electric double layer capacitors based on Nafion ionomer
journal, July 2002
- Staiti, P.; Minutoli, M.; Lufrano, F.
- Electrochimica Acta, Vol. 47, Issue 17
Electroactive Nanoporous Metal Oxides and Chalcogenides by Chemical Design
journal, April 2017
- Hendon, Christopher H.; Butler, Keith T.; Ganose, Alex M.
- Chemistry of Materials, Vol. 29, Issue 8
Frontier Orbital Engineering of Metal–Organic Frameworks with Extended Inorganic Connectivity: Porous Alkaline-Earth Oxides
journal, June 2016
- Hendon, Christopher H.; Walsh, Aron; Dincă, Mircea
- Inorganic Chemistry, Vol. 55, Issue 15
Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015
- Brozek, Carl K.; Michaelis, Vladimir K.; Ong, Ta-Chung
- ACS Central Science, Vol. 1, Issue 5
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016
- Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J.
- ACS Central Science, Vol. 2, Issue 3
Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperature
journal, November 2016
- Li, Zhanyong; Peters, Aaron W.; Bernales, Varinia
- ACS Central Science, Vol. 3, Issue 1
Heterogeneous Epoxide Carbonylation by Cooperative Ion-Pair Catalysis in Co(CO) 4 – -Incorporated Cr-MIL-101
journal, March 2017
- Park, Hoyoung D.; Dincă, Mircea; Román-Leshkov, Yuriy
- ACS Central Science, Vol. 3, Issue 5
Electronic Structure Modulation of Metal–Organic Frameworks for Hybrid Devices
journal, December 2014
- Butler, Keith T.; Hendon, Christopher H.; Walsh, Aron
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
Non-Heme Fe(IV)–Oxo Intermediates
journal, July 2007
- Krebs, Carsten; Galonić Fujimori, Danica; Walsh, Christopher T.
- Accounts of Chemical Research, Vol. 40, Issue 7
Hybrid Zeolitic Imidazolate Frameworks: Controlling Framework Porosity and Functionality by Mixed-Linker Synthesis
journal, April 2012
- Thompson, Joshua A.; Blad, Catherine R.; Brunelli, Nicholas A.
- Chemistry of Materials, Vol. 24, Issue 10
Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism
journal, December 2013
- Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E.
- Chemistry of Materials, Vol. 25, Issue 24
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation
journal, April 2014
- Guo, Zhiyong; Xiao, Chaoxian; Maligal-Ganesh, Raghu V.
- ACS Catalysis, Vol. 4, Issue 5, p. 1340-1348
Synthesis and Characterization of Metal–Organic Framework-74 Containing 2, 4, 6, 8, and 10 Different Metals
journal, May 2014
- Wang, Lisa J.; Deng, Hexiang; Furukawa, Hiroyasu
- Inorganic Chemistry, Vol. 53, Issue 12, p. 5881-5883
Defect sites in highly siliceous HZSM-5 zeolites: a study performed by alumination and IR spectroscopy
journal, January 1991
- Yamagishi, Kouji; Namba, Seitaro; Yashima, Tatsuaki
- The Journal of Physical Chemistry, Vol. 95, Issue 2
A Highly Active Well-Defined Rhenium Heterogeneous Catalyst for Olefin Metathesis Prepared via Surface Organometallic Chemistry
journal, March 2001
- Chabanas, Mathieu; Baudouin, Anne; Copéret, Christophe
- Journal of the American Chemical Society, Vol. 123, Issue 9
Tuning MOF CO 2 Adsorption Properties via Cation Exchange
journal, April 2010
- An, Jihyun; Rosi, Nathaniel L.
- Journal of the American Chemical Society, Vol. 132, Issue 16
Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission
journal, December 2011
- Shustova, Natalia B.; McCarthy, Brian D.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 133, Issue 50
Amplified Luminescence Quenching of Phosphorescent Metal–Organic Frameworks
journal, February 2012
- Kent, Caleb A.; Liu, Demin; Meyer, Thomas J.
- Journal of the American Chemical Society, Vol. 134, Issue 9
Pt Nanoparticles@Photoactive Metal–Organic Frameworks: Efficient Hydrogen Evolution via Synergistic Photoexcitation and Electron Injection
journal, April 2012
- Wang, Cheng; deKrafft, Kathryn E.; Lin, Wenbin
- Journal of the American Chemical Society, Vol. 134, Issue 17
Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?
journal, June 2012
- Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim
- Journal of the American Chemical Society, Vol. 134, Issue 24
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012
- Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
- Journal of the American Chemical Society, Vol. 134, Issue 31
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012
- Kim, Min; Cahill, John F.; Fei, Honghan
- Journal of the American Chemical Society, Vol. 134, Issue 43
Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks
journal, December 2012
- Son, Ho-Jin; Jin, Shengye; Patwardhan, Sameer
- Journal of the American Chemical Society, Vol. 135, Issue 2
Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization
journal, July 2013
- Hendon, Christopher H.; Tiana, Davide; Fontecave, Marc
- Journal of the American Chemical Society, Vol. 135, Issue 30
Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013
- Brozek, Carl K.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 135, Issue 34
High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014
- Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
- Journal of the American Chemical Society, Vol. 136, Issue 25
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015
- Park, Sarah S.; Hontz, Eric R.; Sun, Lei
- Journal of the American Chemical Society, Vol. 137, Issue 5
Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks
journal, March 2009
- Das, Sunirban; Kim, Hyunuk; Kim, Kimoon
- Journal of the American Chemical Society, Vol. 131, Issue 11
A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts
journal, April 2009
- Shultz, Abraham M.; Farha, Omar K.; Hupp, Joseph T.
- Journal of the American Chemical Society, Vol. 131, Issue 12, p. 4204-4205
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
journal, June 2015
- Yang, Dong; Odoh, Samuel O.; Wang, Timothy C.
- Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
journal, October 2015
- Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M.
- Journal of the American Chemical Society, Vol. 137, Issue 43
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework
journal, February 2016
- Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B.
- Journal of the American Chemical Society, Vol. 138, Issue 6
Thermal Stabilization of Metal–Organic Framework-Derived Single-Site Catalytic Clusters through Nanocasting
journal, February 2016
- Malonzo, Camille D.; Shaker, Sammy M.; Ren, Limin
- Journal of the American Chemical Society, Vol. 138, Issue 8
Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions
journal, October 2016
- Gallington, Leighanne C.; Kim, In Soo; Liu, Wei-Guang
- Journal of the American Chemical Society, Vol. 138, Issue 41
An Exceptionally Stable Metal–Organic Framework Supported Molybdenum(VI) Oxide Catalyst for Cyclohexene Epoxidation
journal, October 2016
- Noh, Hyunho; Cui, Yuexing; Peters, Aaron W.
- Journal of the American Chemical Society, Vol. 138, Issue 44
Principles of Designing Extra-Large Pore Openings and Cages in Zeolitic Imidazolate Frameworks
journal, April 2017
- Yang, Jingjing; Zhang, Yue-Biao; Liu, Qi
- Journal of the American Chemical Society, Vol. 139, Issue 18
Lewis Acid–Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries
journal, April 2014
- Zheng, Jianming; Tian, Jian; Wu, Dangxin
- Nano Letters, Vol. 14, Issue 5
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015
- McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
- Nature, Vol. 519, Issue 7543
A pressure-amplifying framework material with negative gas adsorption transitions
journal, April 2016
- Krause, Simon; Bon, Volodymyr; Senkovska, Irena
- Nature, Vol. 532, Issue 7599
Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011
- Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
- Nature Chemistry, Vol. 4, Issue 2, p. 83-89
Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation
journal, February 2012
- Lu, Guang; Li, Shaozhou; Guo, Zhen
- Nature Chemistry, Vol. 4, Issue 4, p. 310-316
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
journal, March 2016
- Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis
- Nature Communications, Vol. 7, Issue 1
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009
- Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009
- Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
An amine-functionalized metal organic framework for preferential CO2 adsorption at low pressures
journal, January 2009
- Vaidhyanathan, Ramanathan; Iremonger, Simon S.; Dawson, Karl W.
- Chemical Communications, Issue 35
Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010
- Garibay, Sergio J.; Cohen, Seth M.
- Chemical Communications, Vol. 46, Issue 41, p. 7700-7702
Postsynthetic tuning of hydrophilicity in pyrazolate MOFs to modulate water adsorption properties
journal, January 2013
- Wade, Casey R.; Corrales-Sanchez, Tachmajal; Narayan, Tarun C.
- Energy & Environmental Science, Vol. 6, Issue 7
Defect engineering of UiO-66 for CO 2 and H 2 O uptake – a combined experimental and simulation study
journal, January 2016
- Liang, Weibin; Coghlan, Campbell J.; Ragon, Florence
- Dalton Transactions, Vol. 45, Issue 11
Energy level alignment at metal/organic semiconductor interfaces: “Pillow” effect, induced density of interface states, and charge neutrality level
journal, April 2007
- Vázquez, H.; Dappe, Y. J.; Ortega, J.
- The Journal of Chemical Physics, Vol. 126, Issue 14
Band alignment at metal/organic and metal/oxide/organic interfaces
journal, November 2008
- Helander, M. G.; Wang, Z. B.; Qiu, J.
- Applied Physics Letters, Vol. 93, Issue 19
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010
- Deng, H.; Doonan, C. J.; Furukawa, H.
- Science, Vol. 327, Issue 5967, p. 846-850
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013
- Herm, Z. R.; Wiers, B. M.; Mason, J. A.
- Science, Vol. 340, Issue 6135, p. 960-964
Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013
- Kong, X.; Deng, H.; Yan, F.
- Science, Vol. 341, Issue 6148, p. 882-885
Structural models for the metal centers in the nitrogenase molybdenum-iron protein
journal, September 1992
- Kim, J.; Rees, D.
- Science, Vol. 257, Issue 5077
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
journal, May 2016
- Cui, X.; Chen, K.; Xing, H.
- Science, Vol. 353, Issue 6295
Chemical principles for electroactive metal–organic frameworks
journal, November 2016
- Walsh, Aron; Butler, Keith T.; Hendon, Christopher H.
- MRS Bulletin, Vol. 41, Issue 11
Works referencing / citing this record:
Energy-Structure-Function Maps: Cartography for Materials Discovery
journal, December 2017
- Day, Graeme M.; Cooper, Andrew I.
- Advanced Materials, Vol. 30, Issue 37
On the potential for nanoscale metal–organic frameworks for energy applications
journal, January 2019
- Kuyuldar, Seher; Genna, Douglas T.; Burda, Clemens
- Journal of Materials Chemistry A, Vol. 7, Issue 38
Interpenetration Isomerism in Triptycene‐Based Hydrogen‐Bonded Organic Frameworks
journal, January 2019
- Li, Penghao; Li, Peng; Ryder, Matthew R.
- Angewandte Chemie, Vol. 131, Issue 6
Tunable titanium metal–organic frameworks with infinite 1D Ti–O rods for efficient visible-light-driven photocatalytic H 2 evolution
journal, January 2019
- Li, Changqing; Xu, Hui; Gao, Junkuo
- Journal of Materials Chemistry A, Vol. 7, Issue 19
Recent Advances of MOFs and MOF-Derived Materials in Thermally Driven Organic Transformations
journal, November 2018
- Yang, Shuliang; Peng, Li; Bulut, Safak
- Chemistry - A European Journal, Vol. 25, Issue 9
Supramolecular Organization in Confined Nanospaces
journal, April 2018
- Tabacchi, Gloria
- ChemPhysChem, Vol. 19, Issue 11
2D coordination polymers: Design guidelines and materials perspective
journal, December 2019
- Tran, Michael; Kline, Katelyn; Qin, Ying
- Applied Physics Reviews, Vol. 6, Issue 4
A robust etb -type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture
journal, January 2019
- Hu, Han; Zhu, Jiaxing; Yang, Feilong
- Chemical Communications, Vol. 55, Issue 46
Stack the Bowls: Tailoring the Electronic Structure of Corannulene-Integrated Crystalline Materials
journal, July 2018
- Rice, Allison M.; Dolgopolova, Ekaterina A.; Yarbrough, Brandon J.
- Angewandte Chemie International Edition, Vol. 57, Issue 35
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
journal, September 2019
- Rieth, Adam J.; Wright, Ashley M.; Dincă, Mircea
- Nature Reviews Materials, Vol. 4, Issue 11
Syntheses, Structures, and Properties of Two Cd(II)/Zn(II) Complexes with 1,2,4-triazole Derivatives
journal, August 2019
- Ju, F. Y.; Li, G. L.; Li, X. L.
- Russian Journal of Coordination Chemistry, Vol. 45, Issue 8
An In Situ Procedure for the Preparation of Zeolitic Imidazolate Framework‐8 Polyacrylamide Hydrogel for Adsorption of Aqueous Pollutants
journal, February 2019
- Maan, Omar; Song, Ping; Chen, Ningxin
- Advanced Materials Interfaces, Vol. 6, Issue 10
Integration of a (–Cu–S–)n plane in a metal–organic framework affords high electrical conductivity
journal, April 2019
- Pathak, Abhishek; Shen, Jing-Wen; Usman, Muhammad
- Nature Communications, Vol. 10, Issue 1
Mixed-matrix membranes for CO 2 separation: role of the third component
journal, January 2019
- Guo, Xiangyu; Qiao, Zhihua; Liu, Dahuan
- Journal of Materials Chemistry A, Vol. 7, Issue 43
2D networks of metallo-capsules and other coordination polymers from a hexapodal ligand
journal, January 2018
- Thorp-Greenwood, Flora L.; Berry, Gilberte Therese; Boyadjieva, Sophia S.
- CrystEngComm, Vol. 20, Issue 28
Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine
journal, January 2018
- Nagatomi, Hisanori; Yanai, Nobuhiro; Yamada, Teppei
- Chemistry - A European Journal, Vol. 24, Issue 8
Crystalline Kitaev spin liquids
journal, October 2017
- Yamada, Masahiko G.; Dwivedi, Vatsal; Hermanns, Maria
- Physical Review B, Vol. 96, Issue 15
Recent advances in two-dimensional-material-based sensing technology toward health and environmental monitoring applications
journal, January 2020
- Tyagi, Deepika; Wang, Huide; Huang, Weichun
- Nanoscale, Vol. 12, Issue 6
In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts
journal, December 2018
- Gao, Wen‐Yang; Cardenal, Ashley D.; Wang, Chen‐Hao
- Chemistry – A European Journal, Vol. 25, Issue 14
Layer-by-layer integration of conducting polymers and metal organic frameworks onto electrode surfaces: enhancement of the oxygen reduction reaction through electrocatalytic nanoarchitectonics
journal, January 2019
- Mártire, Ana Paula; Segovia, Gustavo M.; Azzaroni, Omar
- Molecular Systems Design & Engineering, Vol. 4, Issue 4
Catalytic Transfer Hydrogenation of Biomass-Derived Carbonyls over Hafnium-Based Metal-Organic Frameworks
journal, December 2017
- Rojas-Buzo, Sergio; García-García, Pilar; Corma, Avelino
- ChemSusChem, Vol. 11, Issue 2
Low‐Dimensional Metal‐Organic Frameworks and their Diverse Functional Roles in Catalysis
journal, May 2019
- Tan, Ying Chuan; Zeng, Hua Chun
- ChemCatChem, Vol. 11, Issue 14
Models Facilitating the Design of a New Metal‐Organic Framework Catalyst for the Selective Decomposition of Formic Acid into Hydrogen and Carbon Dioxide
journal, April 2019
- O'Hair, Richard A. J.; Mravak, Antonija; Krstić, Marjan
- ChemCatChem, Vol. 11, Issue 10
Robust Ultramicroporous Metal-Organic Frameworks with Benchmark Affinity for Acetylene
journal, July 2018
- Peng, Yun-Lei; Pham, Tony; Li, Pengfei
- Angewandte Chemie International Edition, Vol. 57, Issue 34
Proton Conductivity of Composite Polyelectrolyte Membranes with Metal‐Organic Frameworks for Fuel Cell Applications
journal, December 2018
- Escorihuela, Jorge; Narducci, Riccardo; Compañ, Vicente
- Advanced Materials Interfaces
Electrically Conducting Nanocomposites of Carbon Nanotubes and Metal‐Organic Frameworks with Strong Interactions between the two Components
journal, July 2019
- Schulze, Hendrik A.; Hoppe, Bastian; Schäfer, Malte
- ChemNanoMat, Vol. 5, Issue 9
Ultrafast Synthesis of Ni-MOF in One Minute by Ball Milling
journal, December 2018
- Zhang, Ren; Tao, Cheng-An; Chen, Rui
- Nanomaterials, Vol. 8, Issue 12
Metal-Organic Frameworks for the Development of Biosensors: A Current Overview
journal, October 2018
- Carrasco, Sergio
- Biosensors, Vol. 8, Issue 4
Crisscrossing coordination networks: ligand doping to control the chemomechanical properties of stimuli-responsive metallogels
journal, January 2019
- Kim, Junghwan; Lee, Dongwhan
- Chemical Science, Vol. 10, Issue 13
Insights into Selective Gas Sorbent Functionality Gained by Using Time-Resolved Neutron Diffraction
journal, May 2018
- Auckett, Josie E.; Duyker, Samuel G.; Turner, David R.
- ChemPlusChem, Vol. 83, Issue 7
Regulation of the Degree of Interpenetration in Metal–Organic Frameworks
journal, December 2019
- Verma, Gaurav; Butikofer, Sydney; Kumar, Sanjay
- Topics in Current Chemistry, Vol. 378, Issue 1
Metal-Organic-Framework-Derived Co 3 S 4 Hollow Nanoboxes for the Selective Reduction of Nitroarenes
journal, August 2018
- Yang, Shuliang; Peng, Li; Sun, Daniel T.
- ChemSusChem, Vol. 11, Issue 18
Anisotropic Thermal and Guest-Induced Responses of an Ultramicroporous Framework with Rigid Linkers
journal, March 2018
- Auckett, Josie E.; Duyker, Samuel G.; Izgorodina, Ekaterina I.
- Chemistry - A European Journal, Vol. 24, Issue 19
Two-Dimensional Co@N-Carbon Nanocomposites Facilely Derived from Metal-Organic Framework Nanosheets for Efficient Bifunctional Electrocatalysis
journal, May 2018
- Cong, Jingkun; Xu, Hui; Lu, Mengting
- Chemistry - An Asian Journal, Vol. 13, Issue 11
Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal-Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica
journal, June 2018
- Luz, Ignacio; Soukri, Mustapha; Lail, Marty
- Chemistry - A European Journal, Vol. 24, Issue 42
Self-adjusting binding pockets enhance H 2 and CH 4 adsorption in a uranium-based metal–organic framework
journal, January 2020
- Halter, Dominik P.; Klein, Ryan A.; Boreen, Michael A.
- Chemical Science
The Chemistry of Reticular Framework Nanoparticles: MOF, ZIF, and COF Materials
journal, February 2020
- Ploetz, Evelyn; Engelke, Hanna; Lächelt, Ulrich
- Advanced Functional Materials, Vol. 30, Issue 41
Crystal structure of catena-poly[diaqua-(μ2-1,2-bis(4-pyridinyl)ethyane-κ2N:N′)-(μ2–pyridazine-4,5-dicarboxylato-κ2O:O′)]dizinc(II) dihydrate, C12H12ZnN3O6
journal, March 2019
- Feng-Yang, Ju; Ke-Xin, Ding; Fang, Liu
- Zeitschrift für Kristallographie - New Crystal Structures, Vol. 234, Issue 3
Aspects of semiconductivity in soft, porous metal-organic framework crystals
journal, July 2019
- Muschielok, Christoph; Oberhofer, Harald
- The Journal of Chemical Physics, Vol. 151, Issue 1
MOFs for Electrocatalysis: From Serendipity to Design Strategies
journal, December 2018
- Aiyappa, Harshitha Barike; Masa, Justus; Andronescu, Corina
- Small Methods, Vol. 3, Issue 8
A luminescent inorganic–organic hybrid, [Cd(C 16 H 10 N 2 O 8 S)(H 2 O)], for the selective and recyclable detection of chromates and dichromates in aqueous solution
journal, January 2019
- Kundu, Tanaya; Manna, Krishna; Jana, Ajay K.
- New Journal of Chemistry, Vol. 43, Issue 33
Schalten in Metall‐organischen Gerüsten
journal, December 2019
- Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali
- Angewandte Chemie
Interpenetration Isomerism in Triptycene-Based Hydrogen-Bonded Organic Frameworks
journal, January 2019
- Li, Penghao; Li, Peng; Ryder, Matthew R.
- Angewandte Chemie International Edition, Vol. 58, Issue 6
The role of reticular chemistry in the design of CO2 reduction catalysts
journal, February 2018
- Diercks, Christian S.; Liu, Yuzhong; Cordova, Kyle E.
- Nature Materials, Vol. 17, Issue 4
Structural Basis of CO2 Adsorption in a Flexible Metal-Organic Framework Material
journal, March 2019
- Allen, Andrew; Wong-Ng, Winnie; Cockayne, Eric
- Nanomaterials, Vol. 9, Issue 3
Metal–Organic Frameworks for Electrocatalysis
book, January 2020
- Usman, Muhammad; Zhu, Qi-Long
- Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 29-66
Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
journal, October 2018
- Tan, Ying Chuan; Zeng, Hua Chun
- Nature Communications, Vol. 9, Issue 1
Enhancing the photoluminescence of surface anchored metal–organic frameworks: mixed linkers and efficient acceptors
journal, January 2018
- Oldenburg, M.; Turshatov, A.; Busko, D.
- Physical Chemistry Chemical Physics, Vol. 20, Issue 17
A Metal-Organic Framework with Exceptional Activity for C−H Bond Amination
journal, December 2017
- Wang, Le; Agnew, Douglas W.; Yu, Xiao
- Angewandte Chemie, Vol. 130, Issue 2
Defect Creation in HKUST-1 via Molecular Imprinting: Attaining Anionic Framework Property and Mesoporosity for Cation Exchange Applications
journal, September 2017
- Tan, Ying Chuan; Zeng, Hua Chun
- Advanced Functional Materials, Vol. 27, Issue 42
Coordination driven architectures based on metalloligands offering appended carboxylic acid groups
journal, July 2018
- Kumar, Gulshan; Gupta, Rajeev
- Journal of Chemical Sciences, Vol. 130, Issue 7
Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis
journal, January 2020
- Zhao, Kuangmin; Zhu, Weiwei; Liu, Suqin
- Nanoscale Advances, Vol. 2, Issue 2
Switching in Metal–Organic Frameworks
journal, December 2019
- Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali
- Angewandte Chemie International Edition, Vol. 59, Issue 12
A Metal-Organic Framework with Exceptional Activity for C−H Bond Amination
journal, December 2017
- Wang, Le; Agnew, Douglas W.; Yu, Xiao
- Angewandte Chemie International Edition, Vol. 57, Issue 2
Robust Ultramicroporous Metal-Organic Frameworks with Benchmark Affinity for Acetylene
journal, July 2018
- Peng, Yun-Lei; Pham, Tony; Li, Pengfei
- Angewandte Chemie, Vol. 130, Issue 34
Models Facilitating the Design of a New Metal‐Organic Framework Catalyst for the Selective Decomposition of Formic Acid into Hydrogen and Carbon Dioxide
journal, April 2019
- O'Hair, Richard A. J.; Mravak, Antonija; Krstić, Marjan
- ChemCatChem, Vol. 11, Issue 10
Stack the Bowls: Tailoring the Electronic Structure of Corannulene-Integrated Crystalline Materials
journal, July 2018
- Rice, Allison M.; Dolgopolova, Ekaterina A.; Yarbrough, Brandon J.
- Angewandte Chemie, Vol. 130, Issue 35
Two-Dimensional Band Structure in Honeycomb Metal–Organic Frameworks
journal, August 2018
- Kumar, Avijit; Banerjee, Kaustuv; Foster, Adam S.
- Nano Letters, Vol. 18, Issue 9
Host–Guest Chemistry Meets Electrocatalysis: Cucurbit[6]uril on a Au Surface as a Hybrid System in CO2 Reduction
journal, November 2019
- Wagner, Andreas; Ly, Khoa H.; Heidary, Nina
- ACS Catalysis, Vol. 10, Issue 1
The Future of Molecular Machines
journal, March 2020
- Aprahamian, Ivan
- ACS Central Science, Vol. 6, Issue 3
Reticular Chemistry in All Dimensions
journal, July 2019
- Yaghi, Omar M.
- ACS Central Science, Vol. 5, Issue 8
Metal Substitution as the Method of Modifying Electronic Structure of Metal–Organic Frameworks
journal, March 2019
- Syzgantseva, Maria A.; Ireland, Christopher Patrick; Ebrahim, Fatmah Mish
- Journal of the American Chemical Society, Vol. 141, Issue 15
Metal-Organic Frameworks for the Development of Biosensors: A Current Overview
journal, October 2018
- Carrasco, Sergio
- Biosensors, Vol. 8, Issue 4
The Tuning of Optical Properties of Nanoscale MOFs-Based Thin Film through Post-Modification
journal, August 2017
- Yin, Wenchang; Tao, Cheng-an; Zou, Xiaorong
- Nanomaterials, Vol. 7, Issue 9
Tunable Metal–Organic Frameworks for Heat Transformation Applications
journal, August 2018
- Chaemchuen, Somboon; Xiao, Xuan; Klomkliang, Nikom
- Nanomaterials, Vol. 8, Issue 9
Ultrafast Synthesis of Ni-MOF in One Minute by Ball Milling
journal, December 2018
- Zhang, Ren; Tao, Cheng-An; Chen, Rui
- Nanomaterials, Vol. 8, Issue 12