Title: Optimizing photovoltaic performance in CuInS ₂ and CdS quantum dot-sensitized solar cells by using an agar-based gel polymer electrolyte

Abstract

Quantum dot-sensitized solar cells (QDSSCs) offer new opportunities to address the clean energy challenge, being one of the top candidates for third generation photovoltaics. Like dye-sensitized solar cells (DSSCs), QDSSCs normally use liquid electrolytes that suffer from issues such as evaporation or leakage. In this study a gel polysulfide electrolyte was prepared containing a natural polymer, agar, and was used as a quasi-solid-state electrolyte in solar cells to replace the conventional liquid electrolytes. This gel electrolyte shows almost the same conductivity as the liquid one. The solar cells were fabricated using CuInS₂ quantum dots (QDs), previously synthesized, deposited on TiO₂ photoanodes by electrophoretic deposition (EPD). CdS was deposited on TiO₂ by successive ionic layer adsorption and reaction (SILAR). Reduced graphene oxide (RGO)–Cu₂S, brass, and thin film CuxS were used as counter electrodes. Compared to a liquid polysulfide water based electrolyte, solar cells based on CuInS₂ and CdS using gel polymer electrolyte (GPE) exhibit greater incident photon to current conversion efficiency (IPCE = 51.7% at 520 nm and 72.7% at 440 nm), photocurrent density (J_sc = 10.75 and 13.51 mA cm^-2), and power conversion efficiency (η = 2.97 and 2.98%) while exhibiting significantly enhanced stability. The solar cells employing the agar-basedmore » gel polymeric electrolyte are about a factor of 0.20 more stable than using a liquid electrolyte. The higher photovoltaic performance is due to the good conductivity and high wettability as well as the superior permeation capability of the gel electrolyte into the mesoporous matrix of a TiO² film« less

Authors:

Raphael, E.  ^[1];

• Search DOE PAGES for author "Raphael, E."
• Search DOE PAGES for ORCID "0000-0002-5617-8428"
• Search orcid.org for ORCID "0000-0002-5617-8428"

Jara, D. H. ^[2]; Schiavon, M. A.  ^[3]

• Search DOE PAGES for author "Schiavon, M. A."
• Search DOE PAGES for ORCID "0000-0002-1553-5388"
• Search orcid.org for ORCID "0000-0002-1553-5388"

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+ Show Author Affiliations

1. Univ. of Notre Dame, IN (United States); Univ. of Sao Joao del-Rei (Brazil)
2. Univ. of Notre Dame, IN (United States)
3. Univ. of Sao Joao del-Rei (Brazil)

Publication Date:

2017-01-19

Research Org.:

Univ. of Notre Dame, IN (United States)

Sponsoring Org.:

USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

OSTI Identifier:

1425981

Grant/Contract Number:  

FC02-02ER63421

Resource Type:

Accepted Manuscript

Journal Name:

RSC Advances

Additional Journal Information:

Journal Volume: 7; Journal Issue: 11; Journal ID: ISSN 2046-2069

Publisher:

Royal Society of Chemistry

Country of Publication:

United States

Language:

English

Subject:

14 SOLAR ENERGY