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Title: IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts

Abstract

Here in this paper we report an IR-IR double resonance study of the structural landscape present in the Na+(glucose) complex. Our experimental approach involves minimal modifications to a typical IR predissociation setup, and can be carried out via ion-dip or isomer-burning methods, providing additional flexibility to suit different experimental needs. In the current study, the single-laser IR predissociation spectrum of Na+(glucose), which clearly indicates contributions from multiple structures, was experimentally disentangled to reveal the presence of three α-conformers and five β-conformers. Comparisons with calculations show that these eight conformations correspond to the lowest energy gas-phase structures with distinctive Na+ coordination.

Authors:
 [1];  [1];  [1]; ORCiD logo [1]
  1. Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of Wisconsin, Madison, WI (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1425956
Grant/Contract Number:  
SC0010326; CHE-0840494
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Society for Mass Spectrometry
Additional Journal Information:
Journal Volume: 29; Journal Issue: 1; Journal ID: ISSN 1044-0305
Publisher:
American Society for Mass Spectrometry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Glucose; Spectroscopy; Conformers; Metal ion

Citation Formats

Voss, Jonathan M., Kregel, Steven J., Fischer, Kaitlyn C., and Garand, Etienne. IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts. United States: N. p., 2017. Web. doi:10.1007/s13361-017-1813-x.
Voss, Jonathan M., Kregel, Steven J., Fischer, Kaitlyn C., & Garand, Etienne. IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts. United States. doi:10.1007/s13361-017-1813-x.
Voss, Jonathan M., Kregel, Steven J., Fischer, Kaitlyn C., and Garand, Etienne. Wed . "IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts". United States. doi:10.1007/s13361-017-1813-x. https://www.osti.gov/servlets/purl/1425956.
@article{osti_1425956,
title = {IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts},
author = {Voss, Jonathan M. and Kregel, Steven J. and Fischer, Kaitlyn C. and Garand, Etienne},
abstractNote = {Here in this paper we report an IR-IR double resonance study of the structural landscape present in the Na+(glucose) complex. Our experimental approach involves minimal modifications to a typical IR predissociation setup, and can be carried out via ion-dip or isomer-burning methods, providing additional flexibility to suit different experimental needs. In the current study, the single-laser IR predissociation spectrum of Na+(glucose), which clearly indicates contributions from multiple structures, was experimentally disentangled to reveal the presence of three α-conformers and five β-conformers. Comparisons with calculations show that these eight conformations correspond to the lowest energy gas-phase structures with distinctive Na+ coordination.},
doi = {10.1007/s13361-017-1813-x},
journal = {Journal of the American Society for Mass Spectrometry},
number = 1,
volume = 29,
place = {United States},
year = {2017},
month = {9}
}

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