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Title: Interaction between the exchanged Mn 2+ and Yb 3+ ions confined in zeolite-Y and their luminescence behaviours

Abstract

Luminescent zeolites exchanged with two distinct and interacted emissive ions are vital but less-studied for the potential applications in white light emitting diodes, solar cells, optical codes, biomedicine and so on. Typical transition metal ion Mn 2+ and lanthanide ion Yb 3+ are adopted as a case study via their characteristic transitions and the interaction between them. The option is considered with that the former with d-d transition has a large gap between the first excited state 4T 1 and the ground state 6A 1 (normally >17,000 cm -1) while the latter with f-f transition has no metastable excited state above 10,000 cm -1, which requires the vicinity of these two ions for energy transfer. The results of various characterizations, including BET measurement, photoluminescence spectroscopy, solid-state NMR, and X-ray absorption spectroscopy, etc., show that Yb 3+ would preferably enter into the zeolite-Y pores and introduction of Mn 2+ would cause aggregation of each other. Herein, cation-cation repulsion may play a significant role for the high valence of Mn 2+ and Yb 3+ when exchanging the original cations with +1 valence. Energy transfer phenomena between Mn2+ and Yb 3+ occur only at elevated contents in the confined pores of zeolite. Themore » research would benefit the design of zeolite composite opto-functional materials.« less

Authors:
 [1];  [1];  [1];  [2];  [1]
  1. South China Univ. of Technology (SCUT), Guangzhou (China)
  2. Carnegie Inst. of Washington, Argonne, IL (United States). Geophysical Lab.
Publication Date:
Research Org.:
Carnegie Inst. of Science, Washington, DC (United States). Geophysical Lab.; Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); DOE - BASIC ENERGY SCIENCESNSFDOE-NNSAFOREIGN
OSTI Identifier:
1425873
Alternate Identifier(s):
OSTI ID: 1357630
Grant/Contract Number:  
NA0001974; FG02-99ER45775; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Ye, Shi, Sun, Jiayi, Yi, Xiong, Wang, Yonggang, and Zhang, Qinyuan. Interaction between the exchanged Mn2+ and Yb3+ ions confined in zeolite-Y and their luminescence behaviours. United States: N. p., 2017. Web. doi:10.1038/srep46219.
Ye, Shi, Sun, Jiayi, Yi, Xiong, Wang, Yonggang, & Zhang, Qinyuan. Interaction between the exchanged Mn2+ and Yb3+ ions confined in zeolite-Y and their luminescence behaviours. United States. doi:10.1038/srep46219.
Ye, Shi, Sun, Jiayi, Yi, Xiong, Wang, Yonggang, and Zhang, Qinyuan. Mon . "Interaction between the exchanged Mn2+ and Yb3+ ions confined in zeolite-Y and their luminescence behaviours". United States. doi:10.1038/srep46219. https://www.osti.gov/servlets/purl/1425873.
@article{osti_1425873,
title = {Interaction between the exchanged Mn2+ and Yb3+ ions confined in zeolite-Y and their luminescence behaviours},
author = {Ye, Shi and Sun, Jiayi and Yi, Xiong and Wang, Yonggang and Zhang, Qinyuan},
abstractNote = {Luminescent zeolites exchanged with two distinct and interacted emissive ions are vital but less-studied for the potential applications in white light emitting diodes, solar cells, optical codes, biomedicine and so on. Typical transition metal ion Mn2+ and lanthanide ion Yb3+ are adopted as a case study via their characteristic transitions and the interaction between them. The option is considered with that the former with d-d transition has a large gap between the first excited state 4T1 and the ground state 6A1 (normally >17,000 cm-1) while the latter with f-f transition has no metastable excited state above 10,000 cm-1, which requires the vicinity of these two ions for energy transfer. The results of various characterizations, including BET measurement, photoluminescence spectroscopy, solid-state NMR, and X-ray absorption spectroscopy, etc., show that Yb3+ would preferably enter into the zeolite-Y pores and introduction of Mn2+ would cause aggregation of each other. Herein, cation-cation repulsion may play a significant role for the high valence of Mn2+ and Yb3+ when exchanging the original cations with +1 valence. Energy transfer phenomena between Mn2+ and Yb3+ occur only at elevated contents in the confined pores of zeolite. The research would benefit the design of zeolite composite opto-functional materials.},
doi = {10.1038/srep46219},
journal = {Scientific Reports},
number = ,
volume = 7,
place = {United States},
year = {2017},
month = {4}
}

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Works referenced in this record:

Strong white photoluminescence from annealed zeolites
journal, January 2014


Impact of Aqueous Medium on Zeolite Framework Integrity
journal, April 2015


ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005


Characterization of Fluorescence in Heat-Treated Silver-Exchanged Zeolites
journal, March 2009

  • De Cremer, Gert; Coutiño-Gonzalez, Eduardo; Roeffaers, Maarten B. J.
  • Journal of the American Chemical Society, Vol. 131, Issue 8
  • DOI: 10.1021/ja810071s

Antibacterial activity of heavy metal-loaded natural zeolite
journal, January 2012


Spontaneous nucleation and growth of pure silica zeolite-? free of connectivity defects
journal, January 1996

  • Camblor, Miguel A.; Corma, Avelino; Valencia, Susana
  • Chemical Communications, Issue 20
  • DOI: 10.1039/cc9960002365

Enhanced near infrared emission from the partially vitrified Nd 3+ and silver co-doped zeolite Y
journal, January 2014

  • Lin, Hui; Chu Rong Gui, Sa; Imakita, Kenji
  • Journal of Applied Physics, Vol. 115, Issue 3
  • DOI: 10.1063/1.4862232

Room-temperature upconverted white light from GdMgB5O10 : Yb3+, Mn2+
journal, January 2011

  • Ye, Shi; Li, Ya-jie; Yu, De-chao
  • Journal of Materials Chemistry, Vol. 21, Issue 11
  • DOI: 10.1039/c0jm03307c

Direct Observation of Luminescent Silver Clusters Confined in Faujasite Zeolites
journal, July 2016

  • Altantzis, Thomas; Coutino-Gonzalez, Eduardo; Baekelant, Wouter
  • ACS Nano, Vol. 10, Issue 8
  • DOI: 10.1021/acsnano.6b02834

Luminescence enhancement of ZnS:Mn nanoclusters in zeolite
journal, November 2000

  • Chen, Wei; Sammynaiken, Ramaswami; Huang, Yining
  • Journal of Applied Physics, Vol. 88, Issue 9
  • DOI: 10.1063/1.1314903

Room‐Temperature Wavelength‐Tunable Single‐Band Upconversion Luminescence from Yb 3+ /Mn 2+ Codoped Fluoride Perovskites ABF 3
journal, February 2016


A new yellowish-green-emitting phosphor: Eu2+-doped K4CaSi3O9
journal, January 2012


Up-conversion luminescence of Mn 2 + in Z n S : M n 2 + nanoparticles
journal, July 2001


Anomalous NIR Luminescence in Mn 2+ -Doped Fluoride Perovskite Nanocrystals
journal, March 2014


Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Photophysical Properties of Metal Ion Functionalized NaY Zeolite
journal, January 2014

  • Duan, Tian-Wei; Yan, Bing
  • Photochemistry and Photobiology, Vol. 90, Issue 3
  • DOI: 10.1111/php.12235

Tunable Red Luminescence of Mn[sup 2+]-Doped NaCaPO[sub 4] Phosphors
journal, January 2010

  • Zhang, Suyin; Huang, Yanlin; Kai, Weifang
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 2
  • DOI: 10.1149/1.3266872

Thermoluminescence of CdS clusters in zeolite-Y
journal, March 1997


Correlations between lattice structures of zeolites and their 29Si MAS n.m.r. spectra: zeolites KZ-2, ZSM-12, and Beta
journal, March 1988


Highly luminescent Eu3+-exchanged zeolite L crystals resulting from modification with silylated β-diketone
journal, January 2012

  • Li, Huanrong; Zhang, Haohui; Wang, Lingyun
  • Journal of Materials Chemistry, Vol. 22, Issue 18
  • DOI: 10.1039/c2jm16177j

EPR Determination of the Nearest‐Neighbor Exchange Constant for Mn 2+ Pairs in KZnF 3
journal, March 1969


Photostimulated luminescence of AgI clusters in zeolite-Y
journal, April 1998

  • Chen, Wei; Wang, Zhanguo; Lin, Zhaojun
  • Journal of Applied Physics, Vol. 83, Issue 7
  • DOI: 10.1063/1.366611

Phase formations and tunable red luminescence of Na2CaMg1−xMnx(PO4)2 (x = 0.05–1.0)
journal, January 2011

  • Lü, Juan; Du, Fuping; Zhu, Rui
  • Journal of Materials Chemistry, Vol. 21, Issue 41
  • DOI: 10.1039/c1jm12854j

The effect of positioning cations on acidity and stability of the framework structure of Y zeolite
journal, March 2016

  • Deng, Changshun; Zhang, Junji; Dong, Lihui
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep23382

Cu−Ce Bimetal Ion-Exchanged Y Zeolites for Selective Adsorption of Thiophenic Sulfur
journal, November 2008

  • Shan, Jia-Hui; Liu, Xiao-Qin; Sun, Lin-Bing
  • Energy & Fuels, Vol. 22, Issue 6
  • DOI: 10.1021/ef800296n

Determination and Optimization of the Luminescence External Quantum Efficiency of Silver-Clusters Zeolite Composites
journal, March 2013

  • Coutino-Gonzalez, Eduardo; Roeffaers, Maarten B. J.; Dieu, Bjorn
  • The Journal of Physical Chemistry C, Vol. 117, Issue 14
  • DOI: 10.1021/jp400511z

Photovoltaic Effects of CdS and PbS Quantum Dots Encapsulated in Zeolite Y
journal, December 2011

  • Kim, Hyun Sung; Jeong, Nak Cheon; Yoon, Kyung Byung
  • Langmuir, Vol. 27, Issue 23
  • DOI: 10.1021/la2025395

Mn2+-sensitized near-IR emission from Nd3+-activated Sr,Mn-metaphosphate glasses
journal, November 2013


Tuning the energetics and tailoring the optical properties of silver clusters confined in zeolites
journal, June 2016

  • Fenwick, Oliver; Coutiño-Gonzalez, Eduardo; Grandjean, Didier
  • Nature Materials, Vol. 15, Issue 9
  • DOI: 10.1038/nmat4652

Photoluminescence and photostimulated luminescence of Tb3+ and Eu3+ in zeolite-Y
journal, August 2000

  • Chen, Wei; Sammynaiken, Ramaswami; Huang, Yining
  • Journal of Applied Physics, Vol. 88, Issue 3
  • DOI: 10.1063/1.373834

Near infrared emission from molecule-like silver clusters confined in zeolite A assisted by thermal activation
journal, July 2014

  • Lin, Hui; Imakita, Kenji; Rong Gui, Sa Chu
  • Journal of Applied Physics, Vol. 116, Issue 1
  • DOI: 10.1063/1.4886697

Nanochemistry: Synthesis in diminishing dimensions
journal, October 1992


Novel materials doped with trivalent lanthanides and transition metal ions showing near-infrared to visible photon upconversion
journal, March 2005


Optical Encoding of Silver Zeolite Microcarriers
journal, December 2009

  • De Cremer, Gert; Sels, Bert F.; Hotta, Jun-ichi
  • Advanced Materials, Vol. 22, Issue 9
  • DOI: 10.1002/adma.200902937

K 3 Fe(CN) 6 under External Pressure: Dimerization of CN Coupled with Electron Transfer to Fe(III)
journal, September 2015

  • Li, Kuo; Zheng, Haiyan; Wang, Lijuan
  • The Journal of Physical Chemistry C, Vol. 119, Issue 39
  • DOI: 10.1021/acs.jpcc.5b06793

Green to red tunable upconversion fluorescence from Bi–Er–Yb codoped zeolites
journal, June 2013


Luminescence enhancement of EuS nanoclusters in zeolite
journal, April 2000

  • Chen, Wei; Zhang, Xinhui; Huang, Yining
  • Applied Physics Letters, Vol. 76, Issue 17
  • DOI: 10.1063/1.126335