Depth-Dependent Redox Behavior of LiNi 0.6 Mn 0.2 Co 0.2 O 2

Tian, Chixia; Nordlund, Dennis; Xin, Huolin L.; Xu, Yahong; Liu, Yijin; Sokaras, Dimosthenis; Lin, Feng; Doeff, Marca M.

doi:10.1149/2.1021803jes

Title: Depth-Dependent Redox Behavior of LiNi _0.6 Mn _0.2 Co _0.2 O ₂

Journal Article · 07 February 2018 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/2.1021803jes · OSTI ID:1425689

Tian, Chixia; Nordlund, Dennis; Xin, Huolin L.; Xu, Yahong; Liu, Yijin; Sokaras, Dimosthenis;

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Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-05CH11231; SC0012704; AC02-76SF00515

OSTI ID:: 1425689

Alternate ID(s):: OSTI ID: 1458538; OSTI ID: 1466615; OSTI ID: 1466712

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 3 Vol. 165; ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (55)

Direct observation of reversible oxygen anion redox reaction in Li-rich manganese oxide, Li ₂ MnO ₃ , studied by soft X-ray absorption spectroscopy Oishi, Masatsugu; Yamanaka, Keisuke; Watanabe, Iwao Journal of Materials Chemistry A, Vol. 4, Issue 23 https://doi.org/10.1039/C6TA00174B	journal	January 2016
Through the eyes of a chemist Francl, Michelle Nature Chemistry, Vol. 8, Issue 1 https://doi.org/10.1038/nchem.2426	journal	December 2015
Development of Microstrain in Aged Lithium Transition Metal Oxides Lee, Eung-Ju; Chen, Zonghai; Noh, Hyung-Ju Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl5022859	journal	June 2014
Possibility for an intermediate-spin ground state in the charge-transfer material SrCoO 3 Potze, R.; Sawatzky, G.; Abbate, M. Physical Review B, Vol. 51, Issue 17, p. 11501-11506 https://doi.org/10.1103/PhysRevB.51.11501	journal	May 1995
Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries Liu, Wen; Oh, Pilgun; Liu, Xien Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201409262	journal	March 2015
Self-Terminated Artificial SEI Layer for Nickel-Rich Layered Cathode Material via Mixed Gas Chemical Vapor Deposition Son, In Hyuk; Park, Jong Hwan; Kwon, Soonchul Chemistry of Materials, Vol. 27, Issue 21 https://doi.org/10.1021/acs.chemmater.5b03081	journal	October 2015
Atomic Insights into the Enhanced Surface Stability in High Voltage Cathode Materials by Ultrathin Coating Fang, Xin; Lin, Feng; Nordlund, Dennis Advanced Functional Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adfm.201602873	journal	January 2017
Oxygen 1 s x-ray-absorption edges of transition-metal oxides de Groot, F. M. F.; Grioni, M.; Fuggle, J. C. Physical Review B, Vol. 40, Issue 8 https://doi.org/10.1103/PhysRevB.40.5715	journal	September 1989
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries Lin, Feng; Nordlund, Dennis; Markus, Isaac M. Energy & Environmental Science, Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01400F	journal	January 2014
Computational and Experimental Investigation of Ti Substitution in Li ₁ (Ni _x Mn _x Co _{1–2 x – y} Ti _y )O ₂ for Lithium Ion Batteries Markus, Isaac M.; Lin, Feng; Kam, Kinson C. The Journal of Physical Chemistry Letters, Vol. 5, Issue 21 https://doi.org/10.1021/jz5017526	journal	October 2014
A comparative study on structural changes of LiCo1/3Ni1/3Mn1/3O2 and LiNi0.8Co0.15Al0.05O2 during first charge using in situ XRD Yoon, Won-Sub; Chung, Kyung Yoon; McBreen, James Electrochemistry Communications, Vol. 8, Issue 8 https://doi.org/10.1016/j.elecom.2006.06.005	journal	August 2006
High-energy cathode material for long-life and safe lithium batteries Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun Nature Materials, Vol. 8, Issue 4 https://doi.org/10.1038/nmat2418	journal	March 2009
Electronic structural changes of the electrochemically Li-ion deintercalated LiNi0.8Co0.15Al0.05O2 cathode material investigated by X-ray absorption spectroscopy Yoon, Won-Sub; Chung, Kyung Yoon; McBreen, James Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.214	journal	December 2007
A Consideration of Electrolyte Additives for LiNi _0.5 Mn _1.5 O ₄ /Li ₄ Ti ₅ O ₁₂ Li-Ion Cells Li, S. R.; Sinha, N. N.; Chen, C. H. Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.048311jes	journal	January 2013
New findings on the phase transitions in Li1−xNiO2: in situ synchrotron X-ray diffraction studies Yang, X. Q.; Sun, X.; McBreen, J. Electrochemistry Communications, Vol. 1, Issue 6 https://doi.org/10.1016/S1388-2481(99)00046-6	journal	June 1999
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li ₁ _- _x Co _1/3 Ni _1/3 Mn _1/3 O ₂ Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy Yoon, Won-Sub; Balasubramanian, Mahalingam; Chung, Kyung Yoon Journal of the American Chemical Society, Vol. 127, Issue 49 https://doi.org/10.1021/ja0530568	journal	December 2005
A review of Ni-based layered oxides for rechargeable Li-ion batteries Xu, Jing; Lin, Feng; Doeff, Marca M. Journal of Materials Chemistry A, Vol. 5, Issue 3 https://doi.org/10.1039/C6TA07991A	journal	January 2017
Influence of synthesis conditions on the surface passivation and electrochemical behavior of layered cathode materials Lin, Feng; Nordlund, Dennis; Pan, Taijun J. Mater. Chem. A, Vol. 2, Issue 46 https://doi.org/10.1039/C4TA04497E	journal	January 2014
Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries Asakura, Daisuke; Hosono, Eiji; Nanba, Yusuke AIP Advances, Vol. 6, Issue 3 https://doi.org/10.1063/1.4943673	journal	March 2016
Nanoporous spherical LiFePO4 for high performance cathodes Liu, Jun; Conry, Thomas E.; Song, Xiangyun Energy & Environmental Science, Vol. 4, Issue 3 https://doi.org/10.1039/c0ee00662a	journal	January 2011
Recent progress in cathode materials research for advanced lithium ion batteries Xu, Bo; Qian, Danna; Wang, Ziying Materials Science and Engineering: R: Reports, Vol. 73, Issue 5-6 https://doi.org/10.1016/j.mser.2012.05.003	journal	May 2012
Changes in electronic structure by Li ion deintercalation in LiNiO2 from nickel L-edge and O K-edge XANES Uchimoto, Yoshiharu; Sawada, Hiroshi; Yao, Takeshi Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00624-3	journal	July 2001
Oxygen Contribution on Li-Ion Intercalation−Deintercalation in LiCoO ₂ Investigated by O K-Edge and Co L-Edge X-ray Absorption Spectroscopy Yoon, Won-Sub; Kim, Kwang-Bum; Kim, Min-Gyu The Journal of Physical Chemistry B, Vol. 106, Issue 10 https://doi.org/10.1021/jp013735e	journal	March 2002
Changes in electronic structure of the electrochemically Li-ion deintercalated LiNiO2 system investigated by soft X-ray absorption spectroscopy Yoon, Won-Sub; Chung, Kyung Yoon; McBreen, James Journal of Power Sources, Vol. 163, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.02.013	journal	December 2006
The Impact of Electrolyte Additives and Upper Cut-off Voltage on the Formation of a Rocksalt Surface Layer in LiNi _0.8 Mn _0.1 Co _0.1 O ₂ Electrodes Li, Jing; Liu, Hanshuo; Xia, Jian Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0651704jes	journal	January 2017
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Charge Compensation Mechanism during Cycles in Fe-Containing Li 2 MnO 3 Cathode for High Energy Density and Low-Cost Lithium-Ion Batteries Yuge, Ryota; Toda, Akio; Kuroshima, Sadanori Electrochimica Acta, Vol. 189 https://doi.org/10.1016/j.electacta.2015.12.041	journal	January 2016
Estimating Hybridization of Transition Metal and Oxygen States in Perovskites from O K -edge X-ray Absorption Spectroscopy Suntivich, Jin; Hong, Wesley T.; Lee, Yueh-Lin The Journal of Physical Chemistry C, Vol. 118, Issue 4 https://doi.org/10.1021/jp410644j	journal	January 2014
2 p x-ray absorption of 3 d transition-metal compounds: An atomic multiplet description including the crystal field de Groot, F. M. F.; Fuggle, J. C.; Thole, B. T. Physical Review B, Vol. 42, Issue 9 https://doi.org/10.1103/PhysRevB.42.5459	journal	September 1990
Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches Hausbrand, R.; Cherkashinin, G.; Ehrenberg, H. Materials Science and Engineering: B, Vol. 192 https://doi.org/10.1016/j.mseb.2014.11.014	journal	February 2015
Stabilizing nickel-rich layered cathode materials by a high-charge cation doping strategy: zirconium-doped LiNi _0.6 Co _0.2 Mn _0.2 O ₂ Schipper, Florian; Dixit, Mudit; Kovacheva, Daniela Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/C6TA06740A	journal	January 2016
Local orbital occupation and energy levels of Co in Na x CoO 2 : A soft x-ray absorption study Lin, H. -J.; Chin, Y. Y.; Hu, Z. Physical Review B, Vol. 81, Issue 11 https://doi.org/10.1103/PhysRevB.81.115138	journal	March 2010
Spherical nanoporous LiCoPO4/C composites as high performance cathode materials for rechargeable lithium-ion batteries Liu, Jun; Conry, Thomas E.; Song, Xiangyun Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c1jm10793c	journal	January 2011
Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells Abraham, D. P.; Twesten, R. D.; Balasubramanian, M. Journal of The Electrochemical Society, Vol. 150, Issue 11 https://doi.org/10.1149/1.1613291	journal	January 2003
A New Type of Protective Surface Layer for High-Capacity Ni-Based Cathode Materials: Nanoscaled Surface Pillaring Layer Cho, Yonghyun; Oh, Pilgun; Cho, Jaephil Nano Letters, Vol. 13, Issue 3 https://doi.org/10.1021/nl304558t	journal	February 2013
Electrochemical and Physical Properties of Ti-Substituted Layered Nickel Manganese Cobalt Oxide (NMC) Cathode Materials Kam, Kinson C.; Mehta, Apurva; Heron, John T. Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.060208jes	journal	January 2012
Study of the Failure Mechanisms of LiNi _0.8 Mn _0.1 Co _0.1 O ₂ Cathode Material for Lithium Ion Batteries Li, Jing; Downie, Laura E.; Ma, Lin Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.1011507jes	journal	January 2015
A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries Manthiram, Arumugam; Song, Bohang; Li, Wangda Energy Storage Materials, Vol. 6 https://doi.org/10.1016/j.ensm.2016.10.007	journal	January 2017
Tailoring the surface properties of LiNi _0.4 Mn _0.4 Co _0.2 O ₂ by titanium substitution for improved high voltage cycling performance Wolff-Goodrich, Silas; Lin, Feng; Markus, Isaac M. Physical Chemistry Chemical Physics, Vol. 17, Issue 34 https://doi.org/10.1039/C5CP03228H	journal	January 2015
Soft X-Ray Absorption Spectroscopic Study of a LiNi[sub 0.5]Mn[sub 0.5]O[sub 2] Cathode during Charge Yoon, Won-Sub; Balasubramanian, Mahalingam; Yang, Xiao-Qing Journal of The Electrochemical Society, Vol. 151, Issue 2 https://doi.org/10.1149/1.1637896	journal	January 2004
Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries Lin, Feng; Nordlund, Dennis; Li, Yuyi Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.4	journal	January 2016
Diagnosis of power fade mechanisms in high-power lithium-ion cells Abraham, D. P.; Liu, J.; Chen, C. H. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00275-1	journal	June 2003
Investigation of the Local Structure of the LiNi[sub 0.5]Mn[sub 0.5]O[sub 2] Cathode Material during Electrochemical Cycling by X-Ray Absorption and NMR Spectroscopy Yoon, Won-Sub; Paik, Younkee; Yang, Xiao-Qing Electrochemical and Solid-State Letters, Vol. 5, Issue 11 https://doi.org/10.1149/1.1513001	journal	January 2002
Review—High-Capacity Li[Ni _1- _x Co _x _/2 Mn _x _/2 ]O ₂ ( x = 0.1, 0.05, 0) Cathodes for Next-Generation Li-Ion Battery Yoon, Chong S.; Choi, Moon Ho; Lim, Byung-Beom Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0101514jes	journal	January 2015
Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading Qiao, Ruimin; Wang, Yuesheng; Olalde-Velasco, Paul Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.10.013	journal	January 2015
Aliovalent titanium substitution in layered mixed Li Ni–Mn–Co oxides for lithium battery applications Kam, Kinson C.; Doeff, Marca M. Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c0jm04193a	journal	January 2011
Understanding the Degradation Mechanism of Lithium Nickel Oxide Cathodes for Li-Ion Batteries Xu, Jing; Hu, Enyuan; Nordlund, Dennis ACS Applied Materials & Interfaces, Vol. 8, Issue 46 https://doi.org/10.1021/acsami.6b11111	journal	November 2016
Electronic structure variation of the surface and bulk of a LiNi _0.5 Mn _1.5 O ₄ cathode as a function of state of charge: X-ray absorption spectroscopic study Zhou, Jigang; Hong, Da; Wang, Jian Phys. Chem. Chem. Phys., Vol. 16, Issue 27 https://doi.org/10.1039/c4cp01436g	journal	January 2014
XAS Investigation of Inhomogeneous Metal-Oxygen Bond Covalency in Bulk and Surface for Charge Compensation in Li-Ion Battery Cathode Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Material Kim, Min Gyu; Shin, Hyun Joon; Kim, Jung-Hyun Journal of The Electrochemical Society, Vol. 152, Issue 7 https://doi.org/10.1149/1.1926647	journal	January 2005
Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Synthesis, structural, magnetic and electrochemical properties of LiNi1/3Mn1/3Co1/3O2 prepared by a sol–gel method using table sugar as chelating agent Kızıltaş-Yavuz, Nilüfer; Herklotz, Markus; Hashem, Ahmed M. Electrochimica Acta, Vol. 113 https://doi.org/10.1016/j.electacta.2013.09.065	journal	December 2013
Impedance Studies on the Capacity Fading Mechanism of Li(Ni _0.5 Co _0.2 Mn _0.3 )O ₂ Cathode with High-Voltage and High-Temperature Zhao, Xing; Zhuang, Quan-Chao; Wu, Chao Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0851514jes	journal	January 2015
Surface changes on LiNi0.8Co0.2O2 particles during testing of high-power lithium-ion cells Abraham, D. P.; Twesten, R. D.; Balasubramanian, M. Electrochemistry Communications, Vol. 4, Issue 8 https://doi.org/10.1016/S1388-2481(02)00388-0	journal	August 2002
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries Noh, Hyung-Joo; Youn, Sungjune; Yoon, Chong Seung Journal of Power Sources, Vol. 233 https://doi.org/10.1016/j.jpowsour.2013.01.063	journal	July 2013

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Title: Depth-Dependent Redox Behavior of LiNi _0.6 Mn _0.2 Co _0.2 O ₂