Improving the Performance at Elevated Temperature of High Voltage Graphite/LiNi0.5Mn1.5O4 Cells with Added Lithium Catechol Dimethyl Borate
Abstract
Performance of LiNi0.5Mn1.5O4/graphite cells cycled to 4.8 V at 55°C with the 1.2 M LiPF6 in EC/EMC (3/7, STD electrolyte) with and without added lithium catechol dimethyl borate (LiCDMB) has been investigated. The incorporation of 0.5 wt% LiCDMB to the STD electrolyte results in an improved capacity retention and coulombic efficiency upon cycling at 55°C. Ex-situ analysis of the electrode surfaces via a combination of SEM, TEM, and XPS reveals that oxidation of LiCDMB at high potential results in the deposition of a passivation layer on the electrode surface, preventing transition metal ion dissolution from the cathode and subsequent deposition on the anode. NMR investigations of the bulk electrolyte stored at 85°C reveals that added LiCDMB prevents the thermal decomposition of LiPF6.
- Authors:
-
- Univ. of Rhode Island, Kingston, RI (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Brown Univ., Providence, RI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1425633
- Grant/Contract Number:
- SC0007074
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 2; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Electrolyte; High Voltage; Lithium Ion Battery; surface film
Citation Formats
Dong, Yingnan, Demeaux, Julien, Zhang, Yuzi, Xu, Mengqing, Zhou, Liu, MacIntosh, Alex D., and Lucht, Brett L. Improving the Performance at Elevated Temperature of High Voltage Graphite/LiNi0.5Mn1.5O4 Cells with Added Lithium Catechol Dimethyl Borate. United States: N. p., 2016.
Web. doi:10.1149/2.0331702jes.
Dong, Yingnan, Demeaux, Julien, Zhang, Yuzi, Xu, Mengqing, Zhou, Liu, MacIntosh, Alex D., & Lucht, Brett L. Improving the Performance at Elevated Temperature of High Voltage Graphite/LiNi0.5Mn1.5O4 Cells with Added Lithium Catechol Dimethyl Borate. United States. https://doi.org/10.1149/2.0331702jes
Dong, Yingnan, Demeaux, Julien, Zhang, Yuzi, Xu, Mengqing, Zhou, Liu, MacIntosh, Alex D., and Lucht, Brett L. Tue .
"Improving the Performance at Elevated Temperature of High Voltage Graphite/LiNi0.5Mn1.5O4 Cells with Added Lithium Catechol Dimethyl Borate". United States. https://doi.org/10.1149/2.0331702jes. https://www.osti.gov/servlets/purl/1425633.
@article{osti_1425633,
title = {Improving the Performance at Elevated Temperature of High Voltage Graphite/LiNi0.5Mn1.5O4 Cells with Added Lithium Catechol Dimethyl Borate},
author = {Dong, Yingnan and Demeaux, Julien and Zhang, Yuzi and Xu, Mengqing and Zhou, Liu and MacIntosh, Alex D. and Lucht, Brett L.},
abstractNote = {Performance of LiNi0.5Mn1.5O4/graphite cells cycled to 4.8 V at 55°C with the 1.2 M LiPF6 in EC/EMC (3/7, STD electrolyte) with and without added lithium catechol dimethyl borate (LiCDMB) has been investigated. The incorporation of 0.5 wt% LiCDMB to the STD electrolyte results in an improved capacity retention and coulombic efficiency upon cycling at 55°C. Ex-situ analysis of the electrode surfaces via a combination of SEM, TEM, and XPS reveals that oxidation of LiCDMB at high potential results in the deposition of a passivation layer on the electrode surface, preventing transition metal ion dissolution from the cathode and subsequent deposition on the anode. NMR investigations of the bulk electrolyte stored at 85°C reveals that added LiCDMB prevents the thermal decomposition of LiPF6.},
doi = {10.1149/2.0331702jes},
journal = {Journal of the Electrochemical Society},
number = 2,
volume = 164,
place = {United States},
year = {Tue Dec 13 00:00:00 EST 2016},
month = {Tue Dec 13 00:00:00 EST 2016}
}
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