Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface
Abstract
Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet–type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10-3 to 10-4 S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnet solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm·cm2 for the pristine garnet/Li and 75 ohm·cm2 for the surface-engineered garnet/Li. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metalmore »
- Authors:
-
- (Kelvin) [Univ. of Maryland, College Park, MD (United States)
- Univ. of Maryland, College Park, MD (United States)
- Publication Date:
- Research Org.:
- Univ. of Maryland, College Park, MD (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1425393
- Grant/Contract Number:
- EE0006860
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Fu, Kun, Gong, Yunhui, Liu, Boyang, Xu, Shaomao, Yao, Yonggang, Luo, Wei, Wang, Chengwei, Lacey, Steven D., Dai, Jiaqi, Chen, Yanan, Mo, Yifei, Wachsman, Eric, and Hu, Liangbing. Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface. United States: N. p., 2017.
Web. doi:10.1126/sciadv.1601659.
Fu, Kun, Gong, Yunhui, Liu, Boyang, Xu, Shaomao, Yao, Yonggang, Luo, Wei, Wang, Chengwei, Lacey, Steven D., Dai, Jiaqi, Chen, Yanan, Mo, Yifei, Wachsman, Eric, & Hu, Liangbing. Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface. United States. https://doi.org/10.1126/sciadv.1601659
Fu, Kun, Gong, Yunhui, Liu, Boyang, Xu, Shaomao, Yao, Yonggang, Luo, Wei, Wang, Chengwei, Lacey, Steven D., Dai, Jiaqi, Chen, Yanan, Mo, Yifei, Wachsman, Eric, and Hu, Liangbing. Fri .
"Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface". United States. https://doi.org/10.1126/sciadv.1601659. https://www.osti.gov/servlets/purl/1425393.
@article{osti_1425393,
title = {Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface},
author = {Fu, Kun and Gong, Yunhui and Liu, Boyang and Xu, Shaomao and Yao, Yonggang and Luo, Wei and Wang, Chengwei and Lacey, Steven D. and Dai, Jiaqi and Chen, Yanan and Mo, Yifei and Wachsman, Eric and Hu, Liangbing},
abstractNote = {Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet–type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10-3 to 10-4 S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnet solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm·cm2 for the pristine garnet/Li and 75 ohm·cm2 for the surface-engineered garnet/Li. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries.},
doi = {10.1126/sciadv.1601659},
journal = {Science Advances},
number = 4,
volume = 3,
place = {United States},
year = {2017},
month = {4}
}
Web of Science
Works referenced in this record:
A high performance lithium-ion sulfur battery based on a Li 2 S cathode using a dual-phase electrolyte
journal, January 2015
- Wang, Lina; Wang, Yonggang; Xia, Yongyao
- Energy & Environmental Science, Vol. 8, Issue 5
Improving battery safety by early detection of internal shorting with a bifunctional separator
journal, October 2014
- Wu, Hui; Zhuo, Denys; Kong, Desheng
- Nature Communications, Vol. 5, Issue 1
Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li + Conductors
journal, July 2016
- van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M.
- Advanced Energy Materials, Vol. 6, Issue 19
A review of lithium and non-lithium based solid state batteries
journal, May 2015
- Kim, Joo Gon; Son, Byungrak; Mukherjee, Santanu
- Journal of Power Sources, Vol. 282
Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes
journal, January 2015
- Cheng, Lei; Chen, Wei; Kunz, Martin
- ACS Applied Materials & Interfaces, Vol. 7, Issue 3
Solid Electrolyte: the Key for High-Voltage Lithium Batteries
journal, October 2014
- Li, Juchuan; Ma, Cheng; Chi, Miaofang
- Advanced Energy Materials, Vol. 5, Issue 4
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
journal, December 2015
- Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng
- Advanced Materials, Vol. 28, Issue 9
A Tale of Two Sites: On Defining the Carrier Concentration in Garnet-Based Ionic Conductors for Advanced Li Batteries
journal, March 2015
- Thompson, Travis; Sharafi, Asma; Johannes, Michelle D.
- Advanced Energy Materials, Vol. 5, Issue 11
Hybrid Lithium–Sulfur Batteries with a Solid Electrolyte Membrane and Lithium Polysulfide Catholyte
journal, July 2015
- Yu, Xingwen; Bi, Zhonghe; Zhao, Feng
- ACS Applied Materials & Interfaces, Vol. 7, Issue 30
Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016
- Sharafi, Asma; Meyer, Harry M.; Nanda, Jagjit
- Journal of Power Sources, Vol. 302
A dendrite-suppressing composite ion conductor from aramid nanofibres
journal, January 2015
- Tung, Siu-On; Ho, Szushen; Yang, Ming
- Nature Communications, Vol. 6, Issue 1
Interfacial Challenges in Solid-State Li Ion Batteries
journal, October 2015
- Luntz, Alan C.; Voss, Johannes; Reuter, Karsten
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
All-Solid-State Lithium-Ion Microbatteries: A Review of Various Three-Dimensional Concepts
journal, November 2010
- Oudenhoven, Jos F. M.; Baggetto, Loïc.; Notten, Peter H. L.
- Advanced Energy Materials, Vol. 1, Issue 1
High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016
- Kato, Yuki; Hori, Satoshi; Saito, Toshiya
- Nature Energy, Vol. 1, Issue 4
First-Principles Studies on Cation Dopants and Electrolyte|Cathode Interphases for Lithium Garnets
journal, May 2015
- Miara, Lincoln J.; Richards, William Davidson; Wang, Yan E.
- Chemistry of Materials, Vol. 27, Issue 11
Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries
journal, June 2016
- Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 26
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries
journal, January 2016
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- Journal of Materials Chemistry A, Vol. 4, Issue 9
A Thermally Conductive Separator for Stable Li Metal Anodes
journal, August 2015
- Luo, Wei; Zhou, Lihui; Fu, Kun
- Nano Letters, Vol. 15, Issue 9
Lithium metal anodes for rechargeable batteries
journal, January 2014
- Xu, Wu; Wang, Jiulin; Ding, Fei
- Energy Environ. Sci., Vol. 7, Issue 2
Dendritic growth mechanisms in lithium/polymer cells
journal, September 1999
- Brissot, C.; Rosso, M.; Chazalviel, J. -N.
- Journal of Power Sources, Vol. 81-82
Electrochemical Stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 Solid Electrolytes
journal, January 2016
- Han, Fudong; Zhu, Yizhou; He, Xingfeng
- Advanced Energy Materials, Vol. 6, Issue 8
Densification and ionic-conduction improvement of lithium garnet solid electrolytes by flowing oxygen sintering
journal, February 2014
- Li, Yiqiu; Wang, Zheng; Li, Chilin
- Journal of Power Sources, Vol. 248
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016
- Lin, Dingchang; Liu, Yayuan; Liang, Zheng
- Nature Nanotechnology, Vol. 11, Issue 7
Li+ and Na+ transfer through interfaces between inorganic solid electrolytes and polymer or liquid electrolytes
journal, August 2005
- Sagane, Fumihiro; Abe, Takeshi; Iriyama, Yasutoshi
- Journal of Power Sources, Vol. 146, Issue 1-2
Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12”
journal, January 2011
- Buschmann, Henrik; Dölle, Janis; Berendts, Stefan
- Physical Chemistry Chemical Physics, Vol. 13, Issue 43
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
journal, October 2007
- Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
- Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
Effect of Simultaneous Substitution of Alkali Earth Metals and Nb in Li7La3Zr2O12 on Lithium-Ion Conductivity
journal, January 2013
- Kihira, Y.; Ohta, S.; Imagawa, H.
- ECS Electrochemistry Letters, Vol. 2, Issue 7
All-solid-state lithium-oxygen battery with high safety in wide ambient temperature range
journal, August 2015
- Kitaura, Hirokazu; Zhou, Haoshen
- Scientific Reports, Vol. 5, Issue 1
A shuttle effect free lithium sulfur battery based on a hybrid electrolyte
journal, January 2014
- Wang, Qingsong; Jin, Jun; Wu, Xiangwei
- Phys. Chem. Chem. Phys., Vol. 16, Issue 39
Design principles for solid-state lithium superionic conductors
journal, August 2015
- Wang, Yan; Richards, William Davidson; Ong, Shyue Ping
- Nature Materials, Vol. 14, Issue 10
Dynamic formation of a solid-liquid electrolyte interphase and its consequences for hybrid-battery concepts
journal, March 2016
- Busche, Martin R.; Drossel, Thomas; Leichtweiss, Thomas
- Nature Chemistry, Vol. 8, Issue 5
The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014
- Cheng, Lei; Crumlin, Ethan J.; Chen, Wei
- Phys. Chem. Chem. Phys., Vol. 16, Issue 34
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002
- Aurbach, D.
- Solid State Ionics, Vol. 148, Issue 3-4
Li + -Ion Transfer through the Interface between Li + -Ion Conductive Ceramic Electrolyte and Li + -Ion-Concentrated Propylene Carbonate Solution
journal, October 2009
- Sagane, Fumihiro; Abe, Takeshi; Ogumi, Zempachi
- The Journal of Physical Chemistry C, Vol. 113, Issue 46
Excellent Cycle Life of Lithium-Metal Anodes in Lithium-Ion Batteries with Mussel-Inspired Polydopamine-Coated Separators
journal, April 2012
- Ryou, Myung-Hyun; Lee, Dong Jin; Lee, Je-Nam
- Advanced Energy Materials, Vol. 2, Issue 6
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode
journal, March 2016
- Liu, Yayuan; Lin, Dingchang; Liang, Zheng
- Nature Communications, Vol. 7, Issue 1
Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016
- Liang, Zheng; Lin, Dingchang; Zhao, Jie
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 11
Compatibility of Li[sub 7]La[sub 3]Zr[sub 2]O[sub 12] Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode
journal, January 2010
- Kotobuki, Masashi; Munakata, Hirokazu; Kanamura, Kiyoshi
- Journal of The Electrochemical Society, Vol. 157, Issue 10
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
Electrical properties of amorphous lithium electrolyte thin films
journal, July 1992
- Bates, J. B.; Dudney, N. J.; Gruzalski, G. R.
- Solid State Ionics, Vol. 53-56, Issue Part 1, p. 647-654
Li−Fe−P−O 2 Phase Diagram from First Principles Calculations
journal, February 2008
- Ong, Shyue Ping; Wang, Lei; Kang, Byoungwoo
- Chemistry of Materials, Vol. 20, Issue 5
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes
journal, August 2015
- Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng
- Nature Communications, Vol. 6, Issue 1
A Self-Assembled Breathing Interface for All-Solid-State Ceramic Lithium Batteries
journal, January 2004
- Kanno, Ryoji; Murayama, Masahiro; Inada, Taro
- Electrochemical and Solid-State Letters, Vol. 7, Issue 12
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Metallic anodes for next generation secondary batteries
journal, January 2013
- Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk
- Chemical Society Reviews, Vol. 42, Issue 23
Lithium batteries: Status, prospects and future
journal, May 2010
- Scrosati, Bruno; Garche, Jürgen
- Journal of Power Sources, Vol. 195, Issue 9
Garnet-type solid-state fast Li ion conductors for Li batteries: critical review
journal, January 2014
- Thangadurai, Venkataraman; Narayanan, Sumaletha; Pinzaru, Dana
- Chemical Society Reviews, Vol. 43, Issue 13
Interface Stability in Solid-State Batteries
journal, December 2015
- Richards, William D.; Miara, Lincoln J.; Wang, Yan
- Chemistry of Materials, Vol. 28, Issue 1
Polysulfide-Shuttle Control in Lithium-Sulfur Batteries with a Chemically/Electrochemically Compatible NaSICON-Type Solid Electrolyte
journal, August 2016
- Yu, Xingwen; Bi, Zhonghe; Zhao, Feng
- Advanced Energy Materials, Vol. 6, Issue 24
Origin of the enhanced Li + ionic conductivity in Gd +3 substituted Li 5+2x La 3 Nb 2−x Gd x O 12 lithium conducting garnets
journal, January 2015
- Ahmad, Mohamad M.; Al-Quaimi, Munirah M.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 24
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014
- Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
- Nature Materials, Vol. 13, Issue 10
High rate and stable cycling of lithium metal anode
journal, February 2015
- Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
- Nature Communications, Vol. 6, Issue 1
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12.
journal, December 2007
- Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
- ChemInform, Vol. 38, Issue 50
Works referencing / citing this record:
Progress and Perspective of Solid-State Lithium-Sulfur Batteries
journal, March 2018
- Lei, Danni; Shi, Kai; Ye, Heng
- Advanced Functional Materials, Vol. 28, Issue 38
Lithium Titanate Anode Thin Films for Li-Ion Solid State Battery Based on Garnets
journal, April 2018
- Pfenninger, Reto; Afyon, Semih; Garbayo, Iñigo
- Advanced Functional Materials, Vol. 28, Issue 21
Solid‐State Plastic Crystal Electrolytes: Effective Protection Interlayers for Sulfide‐Based All‐Solid‐State Lithium Metal Batteries
journal, March 2019
- Wang, Changhong; Adair, Keegan R.; Liang, Jianwen
- Advanced Functional Materials, Vol. 29, Issue 26
Electro–Chemo–Mechanical Issues at the Interfaces in Solid‐State Lithium Metal Batteries
journal, April 2019
- Wang, Peng; Qu, Wenjie; Song, Wei‐Li
- Advanced Functional Materials
A Li–Al–O Solid‐State Electrolyte with High Ionic Conductivity and Good Capability to Protect Li Anode
journal, December 2019
- Xie, Meilan; Lin, Xing; Huang, Zhimei
- Advanced Functional Materials, Vol. 30, Issue 7
A Metal-Organic-Framework-Based Electrolyte with Nanowetted Interfaces for High-Energy-Density Solid-State Lithium Battery
journal, November 2017
- Wang, Ziqi; Tan, Rui; Wang, Hongbin
- Advanced Materials, Vol. 30, Issue 2
Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries
journal, February 2018
- Gao, Zhonghui; Sun, Huabin; Fu, Lin
- Advanced Materials, Vol. 30, Issue 17
Elevated-Temperature 3D Printing of Hybrid Solid-State Electrolyte for Li-Ion Batteries
journal, August 2018
- Cheng, Meng; Jiang, Yizhou; Yao, Wentao
- Advanced Materials, Vol. 30, Issue 39
Lithium Silicide Surface Enrichment: A Solution to Lithium Metal Battery
journal, July 2018
- Tang, Wei; Yin, Xuesong; Kang, Sujin
- Advanced Materials, Vol. 30, Issue 34
Interface Engineering for Garnet-Based Solid-State Lithium-Metal Batteries: Materials, Structures, and Characterization
journal, October 2018
- Dai, Jiaqi; Yang, Chunpeng; Wang, Chengwei
- Advanced Materials, Vol. 30, Issue 48
Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries
journal, January 2019
- Duan, Jian; Wu, Wangyan; Nolan, Adelaide M.
- Advanced Materials, Vol. 31, Issue 10
Extended Electrochemical Window of Solid Electrolytes via Heterogeneous Multilayered Structure for High‐Voltage Lithium Metal Batteries
journal, January 2019
- Duan, Hui; Fan, Min; Chen, Wan‐Ping
- Advanced Materials, Vol. 31, Issue 12
Dual‐Phase Single‐Ion Pathway Interfaces for Robust Lithium Metal in Working Batteries
journal, March 2019
- Xu, Rui; Xiao, Ye; Zhang, Rui
- Advanced Materials, Vol. 31, Issue 19
Electrochemical and Structural Analysis in All‐Solid‐State Lithium Batteries by Analytical Electron Microscopy: Progress and Perspectives
journal, October 2019
- Zhang, Chunchen; Feng, Yuzhang; Han, Zhen
- Advanced Materials
Advances in Interfaces between Li Metal Anode and Electrolyte
journal, December 2017
- Zhang, Xue-Qiang; Cheng, Xin-Bing; Zhang, Qiang
- Advanced Materials Interfaces, Vol. 5, Issue 2
Making Sense of Complex Carbon and Metal/Carbon Systems by Secondary Electron Hyperspectral Imaging
journal, August 2019
- Abrams, Kerry J.; Dapor, Maurizio; Stehling, Nicola
- Advanced Science, Vol. 6, Issue 19
3D TiC/C Core/Shell Nanowire Skeleton for Dendrite-Free and Long-Life Lithium Metal Anode
journal, December 2017
- Liu, Sufu; Xia, Xinhui; Zhong, Yu
- Advanced Energy Materials, Vol. 8, Issue 8
Germanium Thin Film Protected Lithium Aluminum Germanium Phosphate for Solid-State Li Batteries
journal, February 2018
- Liu, Yijie; Li, Chao; Li, Bojie
- Advanced Energy Materials, Vol. 8, Issue 16
Lithiophilic CuO Nanoflowers on Ti‐Mesh Inducing Lithium Lateral Plating Enabling Stable Lithium‐Metal Anodes with Ultrahigh Rates and Ultralong Cycle Life
journal, June 2019
- Huang, Kai; Li, Zhi; Xu, Qunjie
- Advanced Energy Materials, Vol. 9, Issue 29
Stack Pressure Considerations for Room‐Temperature All‐Solid‐State Lithium Metal Batteries
journal, November 2019
- Doux, Jean‐Marie; Nguyen, Han; Tan, Darren H. S.
- Advanced Energy Materials, Vol. 10, Issue 1
Ice as Solid Electrolyte To Conduct Various Kinds of Ions
journal, July 2019
- Guo, Zeliang; Wang, Tianshuai; Wei, Hehe
- Angewandte Chemie, Vol. 131, Issue 36
High Uptake and Fast Transportation of LiPF 6 in a Porous Aromatic Framework for Solid‐State Li‐Ion Batteries
journal, December 2019
- Zou, Junyan; Trewin, Abbie; Ben, Teng
- Angewandte Chemie, Vol. 132, Issue 2
Transient Behavior of the Metal Interface in Lithium Metal-Garnet Batteries
journal, October 2017
- Fu, Kun Kelvin; Gong, Yunhui; Fu, Zhezhen
- Angewandte Chemie International Edition, Vol. 56, Issue 47
High Uptake and Fast Transportation of LiPF 6 in a Porous Aromatic Framework for Solid‐State Li‐Ion Batteries
journal, January 2020
- Zou, Junyan; Trewin, Abbie; Ben, Teng
- Angewandte Chemie International Edition, Vol. 59, Issue 2
Reducing the Interfacial Resistance in All‐Solid‐State Lithium Batteries Based on Oxide Ceramic Electrolytes
journal, April 2019
- Jiang, Zhouyang; Han, Qingyue; Wang, Suqing
- ChemElectroChem, Vol. 6, Issue 12
Interface-Engineered Li 7 La 3 Zr 2 O 12 -Based Garnet Solid Electrolytes with Suppressed Li-Dendrite Formation and Enhanced Electrochemical Performance
journal, October 2018
- Zhang, Zhaoshuai; Zhang, Long; Liu, Yanyan
- ChemSusChem, Vol. 11, Issue 21
Synthesis and Properties of NaSICON‐type LATP and LAGP Solid Electrolytes
journal, July 2019
- DeWees, Rachel; Wang, Hui
- ChemSusChem, Vol. 12, Issue 16
Design Principles of the Anode–Electrolyte Interface for All Solid‐State Lithium Metal Batteries
journal, October 2019
- Shen, Zeyu; Zhang, Weidong; Zhu, Guannan
- Small Methods, Vol. 4, Issue 1
Using in operando diffraction to relate lattice strain with degradation mechanism in a NMC battery
journal, October 2018
- Jha, Shikhar Krishn; Charalambous, Harry; Okasinski, John S.
- Journal of Materials Science, Vol. 54, Issue 3
Mechanistic understanding and strategies to design interfaces of solid electrolytes: insights gained from transmission electron microscopy
journal, May 2019
- Hood, Zachary D.; Chi, Miaofang
- Journal of Materials Science, Vol. 54, Issue 15
Infiltrating lithium into carbon cloth decorated with zinc oxide arrays for dendrite-free lithium metal anode
journal, November 2018
- Wang, Xianshu; Pan, Zhenghui; Wu, Yang
- Nano Research, Vol. 12, Issue 3
Rechargeable solid-state Li-air batteries: a status report
journal, April 2018
- Yang, Chu-Shu; Gao, Kang-Ning; Zhang, Xiao-Ping
- Rare Metals, Vol. 37, Issue 6
Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives
journal, August 2019
- Zhao, Wenjia; Yi, Jin; He, Ping
- Electrochemical Energy Reviews, Vol. 2, Issue 4
Diatomite derived hierarchical hybrid anode for high performance all-solid-state lithium metal batteries
journal, June 2019
- Zhou, Fei; Li, Zheng; Lu, Yu-Yang
- Nature Communications, Vol. 10, Issue 1
Tuning wettability of molten lithium via a chemical strategy for lithium metal anodes
journal, October 2019
- Wang, Shu-Hua; Yue, Junpei; Dong, Wei
- Nature Communications, Vol. 10, Issue 1
A low ride on processing temperature for fast lithium conduction in garnet solid-state battery films
journal, May 2019
- Pfenninger, Reto; Struzik, Michal; Garbayo, Iñigo
- Nature Energy, Vol. 4, Issue 6
Sur-/interfacial regulation in all-solid-state rechargeable Li-ion batteries based on inorganic solid-state electrolytes: advances and perspectives
journal, January 2019
- Liang, Longwei; Sun, Xuan; Zhang, Jinyang
- Materials Horizons, Vol. 6, Issue 5
An artificial solid interphase with polymers of intrinsic microporosity for highly stable Li metal anodes
journal, January 2019
- Moon, Gi Hyeon; Kim, Hyun Jong; Chae, Il Seok
- Chemical Communications, Vol. 55, Issue 44
Single-ion conducting artificial solid electrolyte interphase layers for dendrite-free and highly stable lithium metal anodes
journal, January 2019
- Deng, Kuirong; Han, Dongmei; Ren, Shan
- Journal of Materials Chemistry A, Vol. 7, Issue 21
Oriented porous LLZO 3D structures obtained by freeze casting for battery applications
journal, January 2019
- Shen, Hao; Yi, Eongyu; Amores, Marco
- Journal of Materials Chemistry A, Vol. 7, Issue 36
Continuous plating/stripping behavior of solid-state lithium metal anode in a 3D ion-conductive framework
journal, March 2018
- Yang, Chunpeng; Zhang, Lei; Liu, Boyang
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 15
Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode
journal, November 2017
- Xie, Jin; Liao, Lei; Gong, Yongji
- Science Advances, Vol. 3, Issue 11
Upgrading traditional liquid electrolyte via in situ gelation for future lithium metal batteries
journal, October 2018
- Liu, Feng-Quan; Wang, Wen-Peng; Yin, Ya-Xia
- Science Advances, Vol. 4, Issue 10
Review—Li Metal Anode in Working Lithium-Sulfur Batteries
journal, June 2017
- Cheng, Xin-Bing; Huang, Jia-Qi; Zhang, Qiang
- Journal of The Electrochemical Society, Vol. 165, Issue 1
Defect Detection in Solid-State Battery Electrolytes Using Lock-In Thermal Imaging
journal, January 2018
- Sulas, Dana B.; Johnston, Steve; Seitzman, Natalie
- Journal of The Electrochemical Society, Vol. 165, Issue 13
Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN) 2 Based Li/I 2 Battery
journal, January 2018
- Abraham, Alyson; Huang, Jianping; Smith, Paul F.
- Journal of The Electrochemical Society, Vol. 165, Issue 10
Combinatorial Methods for Improving Lithium Metal Cycling Efficiency
journal, January 2018
- Genovese, Matthew; Louli, A. J.; Weber, Rochelle
- Journal of The Electrochemical Society, Vol. 165, Issue 13
Towards Mixed Ionic and Electronic Conducting Li-Stuffed Garnets
journal, January 2018
- Samson, Alfred Junio; Hofstetter, Kyle; Wachsman, Eric
- Journal of The Electrochemical Society, Vol. 165, Issue 10
Research Progress of the Solid State Lithium-Sulfur Batteries
journal, October 2019
- Wang, HangChao; Cao, Xin; Liu, Wen
- Frontiers in Energy Research, Vol. 7
Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection
journal, January 2018
- Yan, Jianhua; Yu, Jianyong; Ding, Bin
- Advanced Materials, Vol. 30, Issue 7
Borohydride-Scaffolded Li/Na/Mg Fast Ionic Conductors for Promising Solid-State Electrolytes
journal, October 2018
- Cuan, Jing; Zhou, You; Zhou, Tengfei
- Advanced Materials, Vol. 31, Issue 1
Interphases, Interfaces, and Surfaces of Active Materials in Rechargeable Batteries and Perovskite Solar Cells
journal, January 2020
- Liu, Chaofeng; Yuan, Jifeng; Masse, Robert
- Advanced Materials
A Material Perspective of Rechargeable Metallic Lithium Anodes
journal, February 2018
- Li, Bin; Wang, Ying; Yang, Shubin
- Advanced Energy Materials, Vol. 8, Issue 13
Perovskite Membranes with Vertically Aligned Microchannels for All-Solid-State Lithium Batteries
journal, August 2018
- Jiang, Zhouyang; Xie, Huiqi; Wang, Suqing
- Advanced Energy Materials, Vol. 8, Issue 27
Constructing Multifunctional Interphase between Li 1.4 Al 0.4 Ti 1.6 (PO 4 ) 3 and Li Metal by Magnetron Sputtering for Highly Stable Solid‐State Lithium Metal Batteries
journal, July 2019
- Hao, Xiaoge; Zhao, Qiang; Su, Shiming
- Advanced Energy Materials, Vol. 9, Issue 34
Interfacial Incompatibility and Internal Stresses in All‐Solid‐State Lithium Ion Batteries
journal, August 2019
- He, Yanming; Lu, Chuanyang; Liu, Shan
- Advanced Energy Materials, Vol. 9, Issue 36
Diffusion Limitation of Lithium Metal and Li–Mg Alloy Anodes on LLZO Type Solid Electrolytes as a Function of Temperature and Pressure
journal, October 2019
- Krauskopf, Thorben; Mogwitz, Boris; Rosenbach, Carolin
- Advanced Energy Materials, Vol. 9, Issue 44
Solid‐State Lithium Batteries: Bipolar Design, Fabrication, and Electrochemistry
journal, May 2019
- Jung, Kyu‐Nam; Shin, Hyun‐Seop; Park, Min‐Sik
- ChemElectroChem, Vol. 6, Issue 15
A review of solid electrolytes for safe lithium-sulfur batteries
journal, November 2017
- Sun, Ying-Zhi; Huang, Jia-Qi; Zhao, Chen-Zi
- Science China Chemistry, Vol. 60, Issue 12
Stabilizing a high-voltage LiNi 0.5 Mn 1.5 O 4 cathode towards all solid state batteries: a Li–Al–Ti–P–O solid electrolyte nano-shell with a host material
journal, January 2019
- Li, Li; Zhao, Rui; Xu, Tinghua
- Nanoscale, Vol. 11, Issue 18
Ultra-thin atom layer deposited alumina film enables the precise lifetime control of fully biodegradable electronic devices
journal, January 2019
- Huang, Shuyi; Xuan, Weipeng; Liu, Shuting
- Nanoscale, Vol. 11, Issue 46
A borate decorated anion-immobilized solid polymer electrolyte for dendrite-free, long-life Li metal batteries
journal, January 2019
- Ma, Cheng; Feng, Yiming; Xing, Fangzhou
- Journal of Materials Chemistry A, Vol. 7, Issue 34
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes
journal, October 2017
- Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 42
Transient Behavior of the Metal Interface in Lithium Metal-Garnet Batteries
journal, October 2017
- Fu, Kun Kelvin; Gong, Yunhui; Fu, Zhezhen
- Angewandte Chemie, Vol. 129, Issue 47
A Perovskite Electrolyte That Is Stable in Moist Air for Lithium-Ion Batteries
journal, June 2018
- Li, Yutao; Xu, Henghui; Chien, Po-Hsiu
- Angewandte Chemie International Edition, Vol. 57, Issue 28
Graphitic Carbon Nitride (g‐C 3 N 4 ): An Interface Enabler for Solid‐State Lithium Metal Batteries
journal, January 2020
- Huang, Ying; Chen, Bo; Duan, Jian
- Angewandte Chemie International Edition, Vol. 59, Issue 9
Nanostructured Metal–Organic Framework (MOF)‐Derived Solid Electrolytes Realizing Fast Lithium Ion Transportation Kinetics in Solid‐State Batteries
journal, April 2019
- Wu, Jian‐Fang; Guo, Xin
- Small, Vol. 15, Issue 27
In situ X-ray photoelectron spectroscopy investigation of the solid electrolyte interphase in a Li/Li6.4Ga0.2La3Zr2O12/LiFePO4 all-solid-state battery
journal, June 2019
- Liu, Zhen; Li, Guozhu; Borodin, Andriy
- Journal of Solid State Electrochemistry, Vol. 23, Issue 7
Recent Progress in All-Solid-State Lithium−Sulfur Batteries Using High Li-Ion Conductive Solid Electrolytes
journal, February 2019
- Umeshbabu, Ediga; Zheng, Bizhu; Yang, Yong
- Electrochemical Energy Reviews, Vol. 2, Issue 2
High Li + transference gel interface between solid-oxide electrolyte and cathode for quasi-solid lithium-ion batteries
journal, January 2019
- Subramani, Ramesh; Tseng, Yu-Hsien; Lee, Yuh-Lang
- Journal of Materials Chemistry A, Vol. 7, Issue 19
Communication—Li/Li 7 La 3 Zr 2 O 12 Interfacial Modification by Constructing a Layer of Cu-Li Alloy
journal, January 2019
- Xiang, Xing; Cao, Shiyu; Chen, Fei
- Journal of The Electrochemical Society, Vol. 166, Issue 13
Sol Gel vs Solid State Synthesis of the Fast Lithium-Ion Conducting Solid State Electrolyte Li7La3Zr2O12 Substituted with Iron
text, January 2019
- Paulus, Anja; Kammler, Simon; Heuer, Sabrina
- RWTH Aachen University
Graphitic Carbon Nitride (g‐C 3 N 4 ): An Interface Enabler for Solid‐State Lithium Metal Batteries
journal, January 2020
- Huang, Ying; Chen, Bo; Duan, Jian
- Angewandte Chemie, Vol. 132, Issue 9
Nanostructured Metal–Organic Framework (MOF)‐Derived Solid Electrolytes Realizing Fast Lithium Ion Transportation Kinetics in Solid‐State Batteries
journal, January 2019
- Wu, Jian‐Fang; Guo, Xin
- Small, Vol. 15, Issue 5
Engineering stable interfaces for three-dimensional lithium metal anodes
journal, July 2018
- Xie, Jin; Wang, Jiangyan; Lee, Hye Ryoung
- Science Advances, Vol. 4, Issue 7
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries
journal, January 2017
- Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian
- Journal of The Electrochemical Society, Vol. 164, Issue 7
A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries
journal, June 2018
- Li, Yutao; Xu, Henghui; Chien, Po‐Hsiu
- Angewandte Chemie, Vol. 130, Issue 28
A 3D Lithium/Carbon Fiber Anode with Sustained Electrolyte Contact for Solid‐State Batteries
journal, December 2019
- Zhang, Ying; Shi, Yang; Hu, Xin‐Cheng
- Advanced Energy Materials, Vol. 10, Issue 3
Sol Gel vs Solid State Synthesis of the Fast Lithium-Ion Conducting Solid State Electrolyte Li 7 La 3 Zr 2 O 12 Substituted with Iron
journal, January 2019
- Paulus, Anja; Kammler, Simon; Heuer, Sabrina
- Journal of The Electrochemical Society, Vol. 166, Issue 3