Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations

Abstract

Here, we have examined the formation and dissolution of gels composed of intermediate volume-fraction nanoparticles with temperature-dependent short-range attractions using small-angle x-ray scatter- ing (SAXS), x-ray photon correlation spectroscopy (XPCS), and rheology to obtain nanoscale and macroscale sensitivity to structure and dynamics. Gel formation after temperature quenches to the vicinity of the rheologically-determined gel temperature, Tgel, was characterized via the slow-down of dynamics and changes in microstructure observed in the intensity autocorrelation functions and structure factor, respectively, as a function of quench depth (ΔT = Tquench - Tgel), wave vector, and formation time (tf). We find similar patterns in the slow-down of dynamics that maps the wave-vector-dependent dynamics at a particular ΔT and tf to that at other ΔTs and tfs via an effective scaling temperature, Ts. A single Ts applies to a broad range of ΔT and tf but does depend on the particle size. The rate of formation implied by the scaling is a far stronger function of ΔT than that of the attraction strength between colloids. Finally, we interpret this strong temperature de- pendence in terms of changes in cooperative bonding required to form stable, energetically favored, local structures.

Authors:
 [1];  [2];  [1];  [3];  [3];  [4];  [3];  [1];  [3];  [2];  [1]
+ Show Author Affiliations
  1. Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Science Division
  2. Florida State Univ., Tallahassee, FL (United States). College of Engineering, Chemical and Biomedical Engineering
  3. AGH Univ. of Science and Technology, Krakow (Poland)
  4. Johns Hopkins Univ., Baltimore, MD (United States). Dept. of Physics and Astronomy
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Science Foundation (NSF); USDOE Office of Science (SC); National Center for Research and Development, Poland
OSTI Identifier:
1425262
Alternate Identifier(s):
OSTI ID: 1404748
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Letters
Additional Journal Information:
Journal Volume: 119; Journal Issue: 17; Journal ID: ISSN 0031-9007
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING

Citation Formats

Zhang, Qingteng, Bahadur, Divya, Dufresne, Eric M., Grybos, Pawel, Kmon, Piotr, Leheny, Robert L., Maj, Piotr, Narayanan, Suresh, Szczygiel, Robert, Ramakrishnan, Subramanian, and Sandy, Alec. Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations. United States: N. p., 2017. Web. doi:10.1103/PhysRevLett.119.178006.
Copy to clipboard
Zhang, Qingteng, Bahadur, Divya, Dufresne, Eric M., Grybos, Pawel, Kmon, Piotr, Leheny, Robert L., Maj, Piotr, Narayanan, Suresh, Szczygiel, Robert, Ramakrishnan, Subramanian, & Sandy, Alec. Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations. United States. https://doi.org/10.1103/PhysRevLett.119.178006
Copy to clipboard
Zhang, Qingteng, Bahadur, Divya, Dufresne, Eric M., Grybos, Pawel, Kmon, Piotr, Leheny, Robert L., Maj, Piotr, Narayanan, Suresh, Szczygiel, Robert, Ramakrishnan, Subramanian, and Sandy, Alec. Wed . "Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations". United States. https://doi.org/10.1103/PhysRevLett.119.178006. https://www.osti.gov/servlets/purl/1425262.
Copy to clipboard
@article{osti_1425262,
title = {Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations},
author = {Zhang, Qingteng and Bahadur, Divya and Dufresne, Eric M. and Grybos, Pawel and Kmon, Piotr and Leheny, Robert L. and Maj, Piotr and Narayanan, Suresh and Szczygiel, Robert and Ramakrishnan, Subramanian and Sandy, Alec},
abstractNote = {Here, we have examined the formation and dissolution of gels composed of intermediate volume-fraction nanoparticles with temperature-dependent short-range attractions using small-angle x-ray scatter- ing (SAXS), x-ray photon correlation spectroscopy (XPCS), and rheology to obtain nanoscale and macroscale sensitivity to structure and dynamics. Gel formation after temperature quenches to the vicinity of the rheologically-determined gel temperature, Tgel, was characterized via the slow-down of dynamics and changes in microstructure observed in the intensity autocorrelation functions and structure factor, respectively, as a function of quench depth (ΔT = Tquench - Tgel), wave vector, and formation time (tf). We find similar patterns in the slow-down of dynamics that maps the wave-vector-dependent dynamics at a particular ΔT and tf to that at other ΔTs and tfs via an effective scaling temperature, Ts. A single Ts applies to a broad range of ΔT and tf but does depend on the particle size. The rate of formation implied by the scaling is a far stronger function of ΔT than that of the attraction strength between colloids. Finally, we interpret this strong temperature de- pendence in terms of changes in cooperative bonding required to form stable, energetically favored, local structures.},
doi = {10.1103/PhysRevLett.119.178006},
journal = {Physical Review Letters},
number = 17,
volume = 119,
place = {United States},
year = {Wed Oct 25 00:00:00 EDT 2017},
month = {Wed Oct 25 00:00:00 EDT 2017}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1103/PhysRevLett.119.178006
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 25 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968

  • Stöber, Werner; Fink, Arthur; Bohn, Ernst
  • Journal of Colloid and Interface Science, Vol. 26, Issue 1, p. 62-69
  • DOI: 10.1016/0021-9797(68)90272-5

A micro-mechanical study of coarsening and rheology of colloidal gels: Cage building, cage hopping, and Smoluchowski's ratchet
journal, September 2014

  • Zia, Roseanna N.; Landrum, Benjamin J.; Russel, William B.
  • Journal of Rheology, Vol. 58, Issue 5
  • DOI: 10.1122/1.4892115

Aging of a homogeneously quenched colloidal glass-forming liquid
journal, December 2010

Rheology and internal dynamics of colloidal gels from the dilute to the concentrated regime
journal, November 2014

Laponite:  What Is the Difference between a Gel and a Glass?
journal, September 1999

  • Bonn, Daniel; Kellay, Hamid; Tanaka, Hajime
  • Langmuir, Vol. 15, Issue 22
  • DOI: 10.1021/la990167+

Viscoelasticity of a colloidal gel during dynamical arrest: Evolution through the critical gel and comparison with a soft colloidal glass
journal, September 2014

  • Negi, Ajay Singh; Redmon, Carissa G.; Ramakrishnan, Subramanian
  • Journal of Rheology, Vol. 58, Issue 5
  • DOI: 10.1122/1.4883675

Colloidal gels tuned by oscillatory shear
journal, January 2017

  • Moghimi, Esmaeel; Jacob, Alan R.; Koumakis, Nick
  • Soft Matter, Vol. 13, Issue 12
  • DOI: 10.1039/C6SM02508K

Preparation and characterization of spherical monodisperse silica dispersions in nonaqueous solvents
journal, June 1981

Aging in short-ranged attractive colloids: A numerical study
journal, May 2004

  • Foffi, G.; Zaccarelli, E.; Buldyrev, S.
  • The Journal of Chemical Physics, Vol. 120, Issue 18
  • DOI: 10.1063/1.1695326

The role of quench rate in colloidal gels
journal, January 2012

Gelation as arrested phase separation in short-ranged attractive colloid–polymer mixtures
journal, November 2008

Structure and dynamics of colloidal depletion gels: Coincidence of transitions and heterogeneity
journal, October 2006

Glasslike Arrest in Spinodal Decomposition as a Route to Colloidal Gelation
journal, December 2005

Clustering and Mechanics in Dense Depletion and Thermal Gels †
journal, October 2005

  • Ramakrishnan, S.; Gopalakrishnan, V.; Zukoski, C. F.
  • Langmuir, Vol. 21, Issue 22
  • DOI: 10.1021/la050830w

The effect of attractions on the local structure of liquids and colloidal fluids
journal, December 2010

  • Taffs, Jade; Malins, Alex; Williams, Stephen R.
  • The Journal of Chemical Physics, Vol. 133, Issue 24
  • DOI: 10.1063/1.3516210

Structural origins of dynamical heterogeneity in colloidal gels
journal, May 2008

Preparation of monodisperse silica particles: Control of size and mass fraction
journal, August 1988

  • Bogush, G. H.; Tracy, M. A.; Zukoski, C. F.
  • Journal of Non-Crystalline Solids, Vol. 104, Issue 1, p. 95-106
  • DOI: 10.1016/0022-3093(88)90187-1

Phase separation dynamics in colloid–polymer mixtures: the effect of interaction range
journal, January 2013

  • Zhang, Isla; Royall, C. Patrick; Faers, Malcolm A.
  • Soft Matter, Vol. 9, Issue 6
  • DOI: 10.1039/c2sm27119b

Length scale dependence of dynamical heterogeneity in a colloidal fractal gel
journal, December 2006

Structure of colloidal gels at intermediate concentrations: the role of competing interactions
journal, January 2016

  • Capellmann, Ronja F.; Valadez-Pérez, Néstor E.; Simon, Benedikt
  • Soft Matter, Vol. 12, Issue 46
  • DOI: 10.1039/C6SM01822J

Probing Colloidal Gels at Multiple Length Scales: The Role of Hydrodynamics
journal, June 2015

Gelation of particles with short-range attraction
journal, May 2008

  • Lu, Peter J.; Zaccarelli, Emanuela; Ciulla, Fabio
  • Nature, Vol. 453, Issue 7194
  • DOI: 10.1038/nature06931

Ultralow-angle dynamic light scattering with a charge coupled device camera based multispeckle, multitau correlator
journal, August 1999

  • Cipelletti, Luca; Weitz, D. A.
  • Review of Scientific Instruments, Vol. 70, Issue 8
  • DOI: 10.1063/1.1149894

Interplay between Spinodal Decomposition and Glass Formation in Proteins Exhibiting Short-Range Attractions
journal, September 2007

Noise on photon correlation data. I. Autocorrelation functions
journal, August 1990

  • Schatzel, K.
  • Quantum Optics: Journal of the European Optical Society Part B, Vol. 2, Issue 4
  • DOI: 10.1088/0954-8998/2/4/002

Gel formation and aging in weakly attractive nanocolloid suspensions at intermediate concentrations
journal, October 2011

  • Guo, Hongyu; Ramakrishnan, S.; Harden, James L.
  • The Journal of Chemical Physics, Vol. 135, Issue 15
  • DOI: 10.1063/1.3653380

Elasticity and clustering in concentrated depletion gels
journal, October 2004

Fast multi-tau real-time software correlator for dynamic light scattering
journal, January 2001

Colloidal gelation with variable attraction energy
journal, March 2013

  • Zaccone, Alessio; Crassous, Jérôme J.; Ballauff, Matthias
  • The Journal of Chemical Physics, Vol. 138, Issue 10
  • DOI: 10.1063/1.4794695

Contrast and Stability Improvements for XPCS Measurements at Beamline 8-ID-I at the APS
conference, January 2007

  • Sandy, A. R.; Jiao, X.; Narayanan, S.
  • SYNCHROTRON RADIATION INSTRUMENTATION: Ninth International Conference on Synchrotron Radiation Instrumentation, AIP Conference Proceedings
  • DOI: 10.1063/1.2436206

Brownian dynamics simulations of aging colloidal gels
journal, June 2003

  • d’Arjuzon, Rodolphe J. M.; Frith, William; Melrose, John R.
  • Physical Review E, Vol. 67, Issue 6
  • DOI: 10.1103/PhysRevE.67.061404

Sol-Gel Transition of Concentrated Colloidal Suspensions
journal, December 2000

Linking self-assembly, rheology, and gel transition in attractive colloids
journal, September 2014

  • Zaccone, A.; Winter, H. H.; Siebenbürger, M.
  • Journal of Rheology, Vol. 58, Issue 5
  • DOI: 10.1122/1.4878838

Microstructure and Rheology of Thermoreversible Nanoparticle Gels
journal, August 2006

  • Ramakrishnan, S.; Zukoski, C. F.
  • Langmuir, Vol. 22, Issue 18
  • DOI: 10.1021/la060168j

Viscoelastic properties of colloidal gels
journal, March 1997

  • Rueb, C. J.; Zukoski, C. F.
  • Journal of Rheology, Vol. 41, Issue 2
  • DOI: 10.1122/1.550812

Quantifying the Reversible Association of Thermosensitive Nanoparticles
journal, October 2011

Arrested demixing opens route to bigels
journal, November 2012

  • Varrato, F.; Di Michele, L.; Belushkin, M.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 47
  • DOI: 10.1073/pnas.1214971109

Aging in attraction-driven colloidal glasses
journal, March 2007

32k Channel Readout IC for Single Photon Counting Pixel Detectors with Pitch, Dead Time of 85 ns, Offset Spread and 2% rms Gain Spread
journal, April 2016

Direct observation of a local structural mechanism for dynamic arrest
journal, June 2008

  • Patrick Royall, C.; Williams, Stephen R.; Ohtsuka, Takehiro
  • Nature Materials, Vol. 7, Issue 7
  • DOI: 10.1038/nmat2219

Universal Aging Features in the Restructuring of Fractal Colloidal Gels
journal, March 2000

Dynamical Arrest, Percolation, Gelation, and Glass Formation in Model Nanoparticle Dispersions with Thermoreversible Adhesive Interactions
journal, January 2012

  • Eberle, Aaron P. R.; Castañeda-Priego, Ramón; Kim, Jung M.
  • Langmuir, Vol. 28, Issue 3
  • DOI: 10.1021/la2035054

Dynamics of concentrated colloidal suspensions: diffusion, aggregation and gelation
journal, May 2001

  • Romer, S.; Urban, C.; Bissig, H.
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 359, Issue 1782
  • DOI: 10.1098/rsta.2000.0812

Colloidal gels: equilibrium and non-equilibrium routes
journal, July 2007

Colloidal Gels: Equilibrium and Non-Equilibrium Routes
text, January 2007

Gelation as arrested phase separation in short-ranged attractive colloid-polymer mixtures
text, January 2008

Aging of a Homogeneously Quenched Colloidal Glass-forming Liquid
text, January 2010

The effect of attractions on the local structure of liquids and colloidal fluids
text, January 2011

The role of quench rate in colloidal gels
text, January 2012

Colloidal gelation with variable attraction energy
text, January 2013

Probing colloidal gels at multiple lengthscales: the role of hydrodynamics
text, January 2015

Aging in short-ranged attractive colloids: A numerical study
text, January 2003

Aging in attraction-driven colloidal glasses
text, January 2006

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Anisotropic and heterogeneous dynamics in an aging colloidal gel
    journal, January 2020

    • Jain, Avni; Schulz, Florian; Lokteva, Irina
    • Soft Matter, Vol. 16, Issue 11
    • DOI: 10.1039/c9sm02230a

    Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction
    journal, January 2018

    • Harden, James L.; Guo, Hongyu; Bertrand, Martine
    • The Journal of Chemical Physics, Vol. 148, Issue 4
    • DOI: 10.1063/1.5007038

    Dynamics of soft nanoparticle suspensions at hard X-ray FEL sources below the radiation damage threshold
    text, January 2018

    • Lehmkühler, Felix; Ripado Valerio, Joana; Sheyfer, Dina
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2018-03613

    Dynamics of soft nanoparticle suspensions at hard X-ray FEL sources below the radiation-damage threshold
    journal, October 2018

    Anisotropic and heterogeneous dynamics in an aging colloidal gel
    text, January 2020

    • Jain, Avni; Schulz, Florian; Lokteva, Irina
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2020-01104
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: