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Title: Size dependent behavior of Fe 3O 4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation

Crystal and atomic structural changes of Fe 3O 4upon electrochemical (de)lithiation were determined.
Authors:
 [1] ;  [1] ;  [1] ;  [2] ;  [3] ;  [3] ;  [1] ;  [4] ;  [5] ; ORCiD logo [6] ;  [5] ; ORCiD logo [5]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States
  3. Columbia Univ., New York, NY (United States)
  4. American Physical Society, Ridge, NY (United States)
  5. Stony Brook Univ., Stony Brook, NY (United States)
  6. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
Publication Date:
Report Number(s):
BNL-114491-2017-JAAM
Journal ID: ISSN 1463-9076; PPCPFQ
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 19; Journal Issue: 31; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE
OSTI Identifier:
1425178

Bock, David C., Pelliccione, Christopher J., Zhang, Wei, Timoshenko, Janis, Knehr, K. W., West, Alan C., Wang, Feng, Li, Yan, Frenkel, Anatoly I., Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C.. Size dependent behavior of Fe3O4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation. United States: N. p., Web. doi:10.1039/C7CP03312E.
Bock, David C., Pelliccione, Christopher J., Zhang, Wei, Timoshenko, Janis, Knehr, K. W., West, Alan C., Wang, Feng, Li, Yan, Frenkel, Anatoly I., Takeuchi, Esther S., Takeuchi, Kenneth J., & Marschilok, Amy C.. Size dependent behavior of Fe3O4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation. United States. doi:10.1039/C7CP03312E.
Bock, David C., Pelliccione, Christopher J., Zhang, Wei, Timoshenko, Janis, Knehr, K. W., West, Alan C., Wang, Feng, Li, Yan, Frenkel, Anatoly I., Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C.. 2017. "Size dependent behavior of Fe3O4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation". United States. doi:10.1039/C7CP03312E. https://www.osti.gov/servlets/purl/1425178.
@article{osti_1425178,
title = {Size dependent behavior of Fe3O4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation},
author = {Bock, David C. and Pelliccione, Christopher J. and Zhang, Wei and Timoshenko, Janis and Knehr, K. W. and West, Alan C. and Wang, Feng and Li, Yan and Frenkel, Anatoly I. and Takeuchi, Esther S. and Takeuchi, Kenneth J. and Marschilok, Amy C.},
abstractNote = {Crystal and atomic structural changes of Fe3O4upon electrochemical (de)lithiation were determined.},
doi = {10.1039/C7CP03312E},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 31,
volume = 19,
place = {United States},
year = {2017},
month = {7}
}

Works referenced in this record:

Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in LixCoO2
journal, January 1992
  • Reimers, Jan N.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 139, Issue 8, p. 2091-2097
  • DOI: 10.1149/1.2221184

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

Phase transitions in lithiated Cu2Sb anodes for lithium batteries: an in situ X-ray diffraction study
journal, July 2001
  • Fransson, L. M. L.; Vaughey, J. T.; Benedek, R.
  • Electrochemistry Communications, Vol. 3, Issue 7, p. 317-323
  • DOI: 10.1016/S1388-2481(01)00140-0

In situ X-ray diffraction and X-ray absorption studies of high-rate lithium-ion batteries
journal, January 2001

Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites
journal, January 1997
  • Courtney, Ian A.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 2045-2052
  • DOI: 10.1149/1.1837740