Deconvolution of Composition and Crystallite Size of Silver Hollandite Nanorods: Influence on Electrochemistry

Durham, Jessica L.; Huang, Jianping; Zhang, Bingjie; Wu, Lijun; Tong, Xiao; Pelliccione, Christopher J.; Zhu, Yimei; Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J.

doi:10.1149/2.1371714jes

Title: Deconvolution of Composition and Crystallite Size of Silver Hollandite Nanorods: Influence on Electrochemistry

Journal Article · 16 December 2017 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/2.1371714jes · OSTI ID:1425104

Durham, Jessica L. ^[1];

^[1]; Zhang, Bingjie ^[1]; Wu, Lijun ^[2]; Tong, Xiao ^[2]; Pelliccione, Christopher J. ^[2]; Zhu, Yimei ^[2]; Takeuchi, Esther S. ^[3]; Marschilok, Amy C. ^[4]; Takeuchi, Kenneth J. ^[4]

Stony Brook Univ., NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
Stony Brook Univ., NY (United States). Dept. of Chemistry. Dept. of Materials Science and Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
Stony Brook Univ., NY (United States). Dept. of Chemistry. Dept. of Materials Science and Chemical Engineering

In this paper, silver hollandite (Ag_1.4Mn₈O₁₆) has been synthesized by an aqueous, low-temperature co-precipitation technique to afford silver hollandite with distinct crystallite sizes (10 and 15 nm, identified as S-Ag_1.4Mn₈O₁₆ and L-Ag_1.4Mn₈O₁₆, respectively) and equivalent silver content (x), allowing for the deconvolution of electrochemical effects related to crystallite size and silver content. The as-prepared silver hollandite materials were confirmed to be structurally analogous. Notably, TEM imaging reveals a high degree of bundling of S-Ag_1.4Mn₈O₁₆ nanorods compared to L-Ag_1.4Mn₈O₁₆ which facilitates more intimate connection of the S-Ag_1.4Mn₈O₁₆ material with enhanced interparticle contact. The electrochemical behavior and lithium diffusion properties were investigated by galvanostatic cycling, CV, electrochemical impedance, pulsed-discharge experiments, and ex-situ XAS analysis of cycled cathodes. Lithium based electrochemical cells containing S-Ag_1.4Mn₈O₁₆ delivered a capacity 15X higher than L-Ag_1.4Mn₈O₁₆ on cycle 1. Ex-situ XAS demonstrated structural change for S-Ag_1.4Mn₈O₁₆ and formation of Ag⁰ on insertion of 3.8 Li⁺ intercalation. However, the samples of L-Ag_1.4Mn₈O₁₆ were lithiated by a more limited 0.25 molar equivalents, where no significant structural changes were observed. Finally, the findings affirm crystallite size significantly impacts electrochemistry independent of cation occupancy of the α-MnO₂ type structure.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0012673; AC02-06CH11357

OSTI ID:: 1425104

Report Number(s):: BNL-203324-2018-JAAM

Journal Information:: Journal of the Electrochemical Society, Vol. 164, Issue 14; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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