Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts

Li, Luyao; Wong, Stanislaus S.

doi:10.1021/acsomega.8b00169

Title: Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts

Abstract

Fuel cells (FCs) convert chemical energy into electricity through electrochemical reactions. They maintain desirable functional advantages that render them as attractive candidates for renewable energy alternatives. However, the high cost and general scarcity of conventional FC catalysts largely limit the ubiquitous application of this device configuration. For example, under current consumption requirements, there is an insufficient global reserve of Pt to provide for the needs of an effective FC for every car produced. Therefore, it is absolutely necessary in the future to replace Pt either completely or in part with far more plentiful, abundant, cheaper, and potentially less toxic first row transition metals, because the high cost-to-benefit ratio of conventional catalysts is and will continue to be a major limiting factor preventing mass commercialization. We and other groups have explored a number of nanowire-based catalytic architectures, which are either Pt-free or with reduced Pt content, as an energy efficient solution with improved performance metrics versus conventional, currently commercially available Pt nanoparticles that are already well established in the community. Specifically, in this Perspective, we highlight strategies aimed at the rational modification of not only the physical structure but also the chemical composition as a means of developing superior electrocatalysts formore »« less

Authors:

Li, Luyao ^[1];

^[1]

Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, United States

Publication Date:: Mon Mar 19 00:00:00 EDT 2018

Research Org.:: Stony Brook Univ., NY (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1426831

Alternate Identifier(s):: OSTI ID: 1425102

Report Number(s):: BNL-203322-2018-JAAM
Journal ID: ISSN 2470-1343

Grant/Contract Number:: SC0012704

Resource Type:: Published Article

Journal Name:: ACS Omega

Additional Journal Information:: Journal Name: ACS Omega Journal Volume: 3 Journal Issue: 3; Journal ID: ISSN 2470-1343

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 30 DIRECT ENERGY CONVERSION; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysts; fuel cells; nanowires

Citation Formats


                    Li, Luyao, and Wong, Stanislaus S. Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts.  United States: N. p., 2018. 
Web.  doi:10.1021/acsomega.8b00169.

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                    Li, Luyao, & Wong, Stanislaus S. Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts.  United States.  https://doi.org/10.1021/acsomega.8b00169

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                    Li, Luyao, and Wong, Stanislaus S. Mon .  
"Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts".  United States.  https://doi.org/10.1021/acsomega.8b00169.

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@article{osti_1426831,

  title        = {Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts},

  author       = {Li, Luyao and Wong, Stanislaus S.},

  abstractNote = {Fuel cells (FCs) convert chemical energy into electricity through electrochemical reactions. They maintain desirable functional advantages that render them as attractive candidates for renewable energy alternatives. However, the high cost and general scarcity of conventional FC catalysts largely limit the ubiquitous application of this device configuration. For example, under current consumption requirements, there is an insufficient global reserve of Pt to provide for the needs of an effective FC for every car produced. Therefore, it is absolutely necessary in the future to replace Pt either completely or in part with far more plentiful, abundant, cheaper, and potentially less toxic first row transition metals, because the high cost-to-benefit ratio of conventional catalysts is and will continue to be a major limiting factor preventing mass commercialization. We and other groups have explored a number of nanowire-based catalytic architectures, which are either Pt-free or with reduced Pt content, as an energy efficient solution with improved performance metrics versus conventional, currently commercially available Pt nanoparticles that are already well established in the community. Specifically, in this Perspective, we highlight strategies aimed at the rational modification of not only the physical structure but also the chemical composition as a means of developing superior electrocatalysts for a number of small-molecule-based anodic oxidation and cathodic reduction reactions, which underlie the overall FC behavior. In particular, we focus on efforts to precisely, synergistically, and simultaneously tune not only the size, morphology, architectural motif, surface chemistry, and chemical composition of the as-generated catalysts but also the nature of the underlying support so as to controllably improve performance metrics of the hydrogen oxidation reaction, the methanol oxidation reaction, the ethanol oxidation reaction, and the formic acid oxidation reaction, in addition to the oxygen reduction reaction.},

  doi          = {10.1021/acsomega.8b00169},

  journal      = {ACS Omega},

  number       = 3,

  volume       = 3,

  place        = {United States},

  year         = {Mon Mar 19 00:00:00 EDT 2018},

  month        = {Mon Mar 19 00:00:00 EDT 2018}

}

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Abstract

Citation Formats

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A review of unitized regenerative fuel cell stack: Material, design and research achievements journal, October 2014

Designing Enhanced One-Dimensional Electrocatalysts for the Oxygen Reduction Reaction: Probing Size- and Composition-Dependent Electrocatalytic Behavior in Noble Metal Nanowires journal, October 2012

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The role of electronic properties of Pt and Pt alloys for enhanced reformate electro-oxidation in polymer electrolyte membrane fuel cells journal, September 2013

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Controlling the Catalytic Activity of Platinum-Monolayer Electrocatalysts for Oxygen Reduction with Different Substrates journal, March 2005

Anode Materials for Low-Temperature Fuel Cells: A Density Functional Theory Study journal, April 2001

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High Throughput Experimental and Theoretical Predictive Screening of Materials − A Comparative Study of Search Strategies for New Fuel Cell Anode Catalysts journal, October 2003

Palladium and palladium–tin supported on multi wall carbon nanotubes or carbon for alkaline direct ethanol fuel cell journal, February 2015

Ethanol, Acetaldehyde and Acetic Acid Adsorption/Electrooxidation on a Pt Thin Film Electrode under Continuous Electrolyte Flow: An in Situ ATR-FTIRS Flow Cell Study journal, May 2010

Evolution of Nanoporous Pt-Fe Alloy Nanowires by Dealloying and their Catalytic Property for Oxygen Reduction Reaction journal, July 2011

Effect of Strain on the Reactivity of Metal Surfaces journal, September 1998

Heteroatom Doped Carbon Nanofibers Synthesized by Chemical Vapor Deposition as Platinum Electrocatalyst Supports for Polymer Electrolyte Membrane Fuel Cells journal, November 2015

Synthesis and Oxygen Reduction Reaction Activity of Atomic and Nanoparticle Gold on Thiol-Functionalized Multiwall Carbon Nanotubes journal, January 2011

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Platinum-Coated Copper Nanowires with High Activity for Hydrogen Oxidation Reaction in Base journal, August 2013

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journal, January 2003

A review of unitized regenerative fuel cell stack: Material, design and research achievements
journal, October 2014

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The role of electronic properties of Pt and Pt alloys for enhanced reformate electro-oxidation in polymer electrolyte membrane fuel cells
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Understanding and approaches for the durability issues of Pt-based catalysts for PEM fuel cell
journal, September 2007

Controlling the Catalytic Activity of Platinum-Monolayer Electrocatalysts for Oxygen Reduction with Different Substrates
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Anode Materials for Low-Temperature Fuel Cells: A Density Functional Theory Study
journal, April 2001

Supercritical Carbon-Dioxide-Assisted Deposition of Pt Nanoparticles on Graphene Sheets and Their Application as an Electrocatalyst for Direct Methanol Fuel Cells
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High Throughput Experimental and Theoretical Predictive Screening of Materials − A Comparative Study of Search Strategies for New Fuel Cell Anode Catalysts
journal, October 2003

Palladium and palladium–tin supported on multi wall carbon nanotubes or carbon for alkaline direct ethanol fuel cell
journal, February 2015

Ethanol, Acetaldehyde and Acetic Acid Adsorption/Electrooxidation on a Pt Thin Film Electrode under Continuous Electrolyte Flow: An in Situ ATR-FTIRS Flow Cell Study
journal, May 2010

Evolution of Nanoporous Pt-Fe Alloy Nanowires by Dealloying and their Catalytic Property for Oxygen Reduction Reaction
journal, July 2011

Effect of Strain on the Reactivity of Metal Surfaces
journal, September 1998

Heteroatom Doped Carbon Nanofibers Synthesized by Chemical Vapor Deposition as Platinum Electrocatalyst Supports for Polymer Electrolyte Membrane Fuel Cells
journal, November 2015

Synthesis and Oxygen Reduction Reaction Activity of Atomic and Nanoparticle Gold on Thiol-Functionalized Multiwall Carbon Nanotubes
journal, January 2011

Ultra-low platinum content fuel cell anode electrocatalyst with a long-term performance stability
journal, September 2004

A Strategy for Fabricating Porous PdNi@Pt Core-shell Nanostructures and Their Enhanced Activity and Durability for the Methanol Electrooxidation
journal, January 2015

Synthesis of PtRu Nanowires and Their Catalytic Activity in the Anode of Direct Methanol Fuel Cells
journal, October 2006

Platinum-Coated Copper Nanowires with High Activity for Hydrogen Oxidation Reaction in Base
journal, August 2013

Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co
journal, January 1999

Scalable Bromide-Triggered Synthesis of Pd@Pt Core–Shell Ultrathin Nanowires with Enhanced Electrocatalytic Performance toward Oxygen Reduction Reaction
journal, June 2015

Palladium–iridium nanowires for enhancement of electro-catalytic activity towards oxygen reduction reaction
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Facile synthesis of Pd-decorated Pt/Ru networks with highly improved activity for methanol electrooxidation in alkaline media
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Electrospun bimetallic nanowires of PtRh and PtRu with compositional variation for methanol electrooxidation
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Platinum Monolayer Electrocatalysts for Anodic Oxidation of Alcohols
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Synthesis and Comparative Study of Nanoporous Palladium-Based Bimetallic Catalysts for Formic Acid Oxidation
journal, December 2014

Water-in-Oil Microemulsion Synthesis of Platinum−Ruthenium Nanoparticles, Their Characterization and Electrocatalytic Properties
journal, January 2003

Three Dimensional PtRh Alloy Porous Nanostructures: Tuning the Atomic Composition and Controlling the Morphology for the Application of Direct Methanol Fuel Cells
journal, May 2012

The Oxidation of Methanol on PtRu(111): A Periodic Density Functional Theory Investigation
journal, August 2015

Design Principles for Heteroatom-Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal-Air Batteries
journal, September 2015

The methanol oxidation reaction on platinum alloys with the first row transition metals
journal, March 2006

Kinetics of the Anode Processes in PEM Fuel Cells - The Promoting Effect of Ru in PtRu Anodes
journal, December 2001

Role of Chemical Composition in the Enhanced Catalytic Activity of Pt-Based Alloyed Ultrathin Nanowires for the Hydrogen Oxidation Reaction under Alkaline Conditions
journal, May 2016

Tailoring Chemical Composition To Achieve Enhanced Methanol Oxidation Reaction and Methanol-Tolerant Oxygen Reduction Reaction Performance in Palladium-Based Nanowire Systems
journal, August 2013

Bromide ion mediated synthesis of carbon supported ultrathin palladium nanowires with enhanced catalytic activity toward formic acid/ethanol electrooxidation
journal, February 2014

Platinum-Based Nanowire Networks with Enhanced Oxygen-Reduction Activity
journal, November 2014

Pt-Covered Multiwall Carbon Nanotubes for Oxygen Reduction in Fuel Cell Applications
journal, May 2011

Experimental and DFT study of thiol-stabilized Pt/CNTs catalysts
journal, January 2012

Methanol electrooxidation on well-characterized platinum-ruthenium bulk alloys
journal, November 1993

Novel Pt–Ru–Ni/C Catalysts for Methanol Electro-oxidation in Acid Medium
journal, January 2006

A review of power battery thermal energy management
journal, December 2011

Catalysis at the Rim: A Mechanism for Low Temperature CO Oxidation over Pt ₃ Sn
journal, September 2017

Shape- and Composition-Sensitive Activity of Pt and PtAu Catalysts for Formic Acid Electrooxidation
journal, August 2012

Hydrothermal synthesis of spindle-like Zn2SiO4 nanoparticles and its application in lithium-ion battery
journal, October 2015

Synthesis of Ultrathin Palladium and Platinum Nanowires and a Study of Their Magnetic Properties
journal, February 2008

In Situ Probing of the Active Site Geometry of Ultrathin Nanowires for the Oxygen Reduction Reaction
journal, September 2015

Synthesis of Platinum Nanowire Networks Using a Soft Template
journal, December 2007

Highly branched Pt–Ni nanocrystals enclosed by stepped surface for methanol oxidation
journal, January 2012

Synthesis of Ultrathin FePtPd Nanowires and Their Use as Catalysts for Methanol Oxidation Reaction
journal, October 2011

Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction
journal, May 2009

Ultrathin Pt-Based Alloy Nanowire Networks: Synthesized by CTAB Assistant Two-Phase Water−Chloroform Micelles
journal, November 2009

Quantitating the Lattice Strain Dependence of Monolayer Pt Shell Activity toward Oxygen Reduction
journal, April 2013

Doping effect of carboxylic acid group functionalized multi-walled carbon nanotube on polyaniline
journal, September 2011

A general scheme for the estimation of oxygen binding energies on binary transition metal surface alloys
journal, November 2005

Synchrotron-Based In Situ Characterization of Carbon-Supported Platinum and Platinum Monolayer Electrocatalysts
journal, December 2015

Enhanced stability and activity of PtRu nanotubes for methanol electrooxidation
journal, July 2009

Multifunctional Ultrathin Pd _x Cu _{1– x} and Pt∼Pd _x Cu _{1– x} One-Dimensional Nanowire Motifs for Various Small Molecule Oxidation Reactions
journal, November 2015

Rapid fabrication of Cu/Pd nano/micro-particles porous-structured catalyst using hydrogen bubbles dynamic template and their enhanced catalytic performance for formic acid electrooxidation
journal, May 2014

One-Pot, High-Yield Synthesis of 5-Fold Twinned Pd Nanowires and Nanorods
journal, April 2009

Composition–Structure–Activity Relationships for Palladium-Alloyed Nanocatalysts in Oxygen Reduction Reaction: An Ex-Situ/In-Situ High Energy X-ray Diffraction Study
journal, August 2015

Direct methanol fuel cells for vehicular applications
journal, March 1998

Pt–Ru/multi-walled carbon nanotubes as electrocatalysts for direct methanol fuel cell
journal, January 2008

Fe–N–C Catalyst Graphitic Layer Structure and Fuel Cell Performance
journal, June 2017

Overview of the development of CO-tolerant anode electrocatalysts for proton-exchange membrane fuel cells
journal, June 2006

Proton Exchange Membrane Fuel Cell Reversal: A Review
journal, December 2016

PtRu Nanoparticle Electrocatalyst with Bulk Alloy Properties Prepared through a Sonochemical Method
journal, September 2006

Segmented Pt/Ru, Pt/Ni, and Pt/RuNi Nanorods as Model Bifunctional Catalysts for Methanol Oxidation
journal, January 2006

Shell thickness effects on reconfiguration of NiO _core –Pt _shell anodic catalysts in a high current density direct methanol fuel cell
journal, January 2016

Fullerene applications in fuel cells: A review
journal, October 2016

Controlling the growth direction of one-dimensional ZnO nanostructures by changing the oxygen content in the reaction atmosphere
journal, September 2005

Palladium-based electrocatalysts for hydrogen oxidation and oxygen reduction reactions
journal, March 2011

A review of anode catalysis in the direct methanol fuel cell
journal, April 2006

A volcano curve: optimizing methanol electro-oxidation on Pt-decorated Ru nanoparticles
journal, January 2009

Tuning Nanowires and Nanotubes for Efficient Fuel-Cell Electrocatalysis
journal, September 2016

The influence of methanol on the chemical state of PtRu anodes in a high-temperature direct methanol fuel cell studied in situ by synchrotron-based near-ambient pressure x-ray photoelectron spectroscopy
journal, November 2016