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Title: Solvent effect in sonochemical synthesis of metal-alloy nanoparticles for use as electrocatalysts

Abstract

Nanomaterials are now widely used in the fabrication of electrodes and electrocatalysts. In this paper, we report a sonochemical study of the synthesis of molybdenum and palladium alloy nanomaterials supported on functionalized carbon material in various solvents: hexadecane, ethanol, ethylene glycol, polyethylene glycol (PEG 400) and Ionic liquids (ILs). The objective was to identify simple and more environmentally friendly design and fabrication methods for nanomaterial synthesis that are suitable as electrocatalysts in electrochemical applications. The particles size and distribution of nanomaterials were compared on two different carbons as supports: activated carbon and multiwall carbon nanotubes (MWCNTs). The results show that carbon materials functionalized with ILs in ethanol/deionized water mixture solvent produced smaller particles sizes (3.00 ± 0.05 nm) with uniform distribution while in PEG 400, functionalized materials produced 4.00 ± 1 nm sized particles with uneven distribution (range). In hexadecane solvents with Polyvinylpyrrolidone (PVP) as capping ligands, large particle sizes (14.00 ± 1 nm) were produced with wide particle size distribution. Finally, the metal alloy nanoparticles produced in ILs without any external reducing agent have potential to exhibit a higher catalytic activity due to smaller particle size and uniform distribution.

Authors:
 [1];  [2];  [3];  [3];  [4];  [2];  [1]
  1. Stony Brook Univ., NY (United States). Advanced Energy Research & Technology Center. Materials Science & Chemical Engineering Dept.
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
  3. Stony Brook Univ., NY (United States). Materials Science & Chemical Engineering Dept.
  4. Farmingdale State College, Farmingdale, NY (United States). Inst. for Research and Technology Transfer
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States); Farmingdale State College, Farmingdale, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1425100
Report Number(s):
BNL-203318-2018-JAAM
Journal ID: ISSN 1350-4177
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Ultrasonics Sonochemistry
Additional Journal Information:
Journal Volume: 41; Journal ID: ISSN 1350-4177
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Okoli, Celest U., Kuttiyiel, Kurian A., Cole, Jesse, McCutchen, J., Tawfik, Hazem, Adzic, Radoslav R., and Mahajan, Devinder. Solvent effect in sonochemical synthesis of metal-alloy nanoparticles for use as electrocatalysts. United States: N. p., 2017. Web. https://doi.org/10.1016/j.ultsonch.2017.09.049.
Okoli, Celest U., Kuttiyiel, Kurian A., Cole, Jesse, McCutchen, J., Tawfik, Hazem, Adzic, Radoslav R., & Mahajan, Devinder. Solvent effect in sonochemical synthesis of metal-alloy nanoparticles for use as electrocatalysts. United States. https://doi.org/10.1016/j.ultsonch.2017.09.049
Okoli, Celest U., Kuttiyiel, Kurian A., Cole, Jesse, McCutchen, J., Tawfik, Hazem, Adzic, Radoslav R., and Mahajan, Devinder. Tue . "Solvent effect in sonochemical synthesis of metal-alloy nanoparticles for use as electrocatalysts". United States. https://doi.org/10.1016/j.ultsonch.2017.09.049. https://www.osti.gov/servlets/purl/1425100.
@article{osti_1425100,
title = {Solvent effect in sonochemical synthesis of metal-alloy nanoparticles for use as electrocatalysts},
author = {Okoli, Celest U. and Kuttiyiel, Kurian A. and Cole, Jesse and McCutchen, J. and Tawfik, Hazem and Adzic, Radoslav R. and Mahajan, Devinder},
abstractNote = {Nanomaterials are now widely used in the fabrication of electrodes and electrocatalysts. In this paper, we report a sonochemical study of the synthesis of molybdenum and palladium alloy nanomaterials supported on functionalized carbon material in various solvents: hexadecane, ethanol, ethylene glycol, polyethylene glycol (PEG 400) and Ionic liquids (ILs). The objective was to identify simple and more environmentally friendly design and fabrication methods for nanomaterial synthesis that are suitable as electrocatalysts in electrochemical applications. The particles size and distribution of nanomaterials were compared on two different carbons as supports: activated carbon and multiwall carbon nanotubes (MWCNTs). The results show that carbon materials functionalized with ILs in ethanol/deionized water mixture solvent produced smaller particles sizes (3.00 ± 0.05 nm) with uniform distribution while in PEG 400, functionalized materials produced 4.00 ± 1 nm sized particles with uneven distribution (range). In hexadecane solvents with Polyvinylpyrrolidone (PVP) as capping ligands, large particle sizes (14.00 ± 1 nm) were produced with wide particle size distribution. Finally, the metal alloy nanoparticles produced in ILs without any external reducing agent have potential to exhibit a higher catalytic activity due to smaller particle size and uniform distribution.},
doi = {10.1016/j.ultsonch.2017.09.049},
journal = {Ultrasonics Sonochemistry},
number = ,
volume = 41,
place = {United States},
year = {2017},
month = {10}
}

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Works referenced in this record:

Green chemistry for nanoparticle synthesis
journal, January 2015

  • Duan, Haohong; Wang, Dingsheng; Li, Yadong
  • Chemical Society Reviews, Vol. 44, Issue 16
  • DOI: 10.1039/C4CS00363B

Applications of Ultrasound to the Synthesis of Nanostructured Materials
journal, February 2010


Using sonochemistry for the fabrication of nanomaterials
journal, April 2004


Sonochemistry and sonoprocessing: the link, the trends and (probably) the future
journal, July 2003


Dosimetry in sonochemistry: the use of aqueous terephthalate ion as a fluorescence monitor
journal, January 1994


Calorimetric method for measurement of acoustic power absorbed in a volume of a liquid
journal, October 2003


The use of ultrasound for the fabrication of fuel cell materials
journal, November 2010


Sonochemistry: Science and Engineering
journal, March 2016


Visualization and optimization of cavitation activity at a solid surface in high frequency ultrasound fields
journal, January 2017


Toward Greener Nanosynthesis
journal, June 2007

  • Dahl, Jennifer A.; Maddux, Bettye L. S.; Hutchison, James E.
  • Chemical Reviews, Vol. 107, Issue 6
  • DOI: 10.1021/cr050943k

A Review of Ionic Liquids, Their Limits and Applications
journal, January 2014


Towards Rational Design of Nanoparticle Catalysis in Ionic Liquids
journal, June 2013


Naked metal nanoparticles from metal carbonyls in ionic liquids: Easy synthesis and stabilization
journal, September 2011


Constructing Carbon Nanotube/Pt Nanoparticle Hybrids Using an Imidazolium-Salt-Based Ionic Liquid as a Linker
journal, March 2010


Phosphonium-Based Ionic Liquids: An Overview
journal, January 2009

  • Fraser, Kevin J.; MacFarlane, Douglas R.
  • Australian Journal of Chemistry, Vol. 62, Issue 4
  • DOI: 10.1071/CH08558

Ultrasonic synthesis and optical properties of Au/Pd bimetallic nanoparticles in ethylene glycol
journal, June 2003


Properties of ionic liquid solvents for catalysis
journal, May 2004


Sono synthesis and characterization of nano-phase molybdenum-based materials for catalytic hydrodesulfurization
journal, February 2004

  • Mahajan, Devinder; Marshall, Christopher L.; Castagnola, Norma
  • Applied Catalysis A: General, Vol. 258, Issue 1
  • DOI: 10.1016/j.apcata.2003.08.014

Pt Nanoparticle Binding on Functionalized Multiwalled Carbon Nanotubes
journal, March 2006

  • Hull, Robert V.; Li, Liang; Xing, Yangchuan
  • Chemistry of Materials, Vol. 18, Issue 7
  • DOI: 10.1021/cm0518978

Ionic liquid-assisted sonochemical synthesis of SnS nanostructures
journal, March 2014

  • García-Gómez, Nora A.; Parra-Arcieniega, Salomé M. de la; Garza-Tovar, Lorena L.
  • Journal of Alloys and Compounds, Vol. 588
  • DOI: 10.1016/j.jallcom.2013.11.051

Unique role of ionic liquid in microwave-assisted synthesis of monodisperse magnetite nanoparticles
journal, January 2010

  • Hu, Hengyao; Yang, Hao; Huang, Peng
  • Chemical Communications, Vol. 46, Issue 22
  • DOI: 10.1039/b927321b

Sonochemical synthesis of nanomaterials
journal, January 2013

  • Xu, Hangxun; Zeiger, Brad W.; Suslick, Kenneth S.
  • Chem. Soc. Rev., Vol. 42, Issue 7
  • DOI: 10.1039/C2CS35282F

Ultrasound induced cavitation and sonochemical yields
journal, November 1998

  • Gong, Cuiling; Hart, Douglas P.
  • The Journal of the Acoustical Society of America, Vol. 104, Issue 5
  • DOI: 10.1121/1.423851

Nitride Stabilized PtNi Core–Shell Nanocatalyst for high Oxygen Reduction Activity
journal, February 2012

  • Kuttiyiel, Kurian A.; Sasaki, Kotaro; Choi, YongMan
  • Nano Letters, Vol. 12, Issue 12
  • DOI: 10.1021/nl303362s

Sonochemical synthesis of monodispersed magnetite nanoparticles by using an ethanol–water mixed solvent
journal, June 2009


Influence of different factors on the output power transferred into medium by ultrasound
journal, January 1999


Free radical production by manothermosonication
journal, February 1998


Sonochemistry:  Science and Engineering
journal, April 1999

  • Thompson, L. H.; Doraiswamy, L. K.
  • Industrial & Engineering Chemistry Research, Vol. 38, Issue 4
  • DOI: 10.1021/ie9804172

Sonochemistry:  Environmental Science and Engineering Applications
journal, October 2001

  • Adewuyi, Yusuf G.
  • Industrial & Engineering Chemistry Research, Vol. 40, Issue 22
  • DOI: 10.1021/ie010096l

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    Colorimetric detection of Cr( vi ) using silver nanoparticles functionalized with PVP
    journal, January 2019

    • He, Shunzhen; Lin, Xi; Liang, Hao
    • Analytical Methods, Vol. 11, Issue 45
    • DOI: 10.1039/c9ay02010a

    Highly Dispersed Carbon Supported PdNiMo Core with Pt Monolayer Shell Electrocatalysts for Oxygen Reduction Reaction
    journal, January 2018

    • Okoli, Celest; Kuttiyiel, Kurian A.; Sasaki, Kotaro
    • Journal of The Electrochemical Society, Vol. 165, Issue 15
    • DOI: 10.1149/2.0381815jes

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    • DOI: 10.3390/catal9110949