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Title: Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry

In this paper we provide a summary of the recent development of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and its application to catalytic surface chemistry. The methodology as well as significant advantages and challenges associated with this novel technique are described. Details about specific examples of using AP-XPS to probe surface chemistry under working reaction conditions for a number of reactions are explained: CO oxidation, water-gas shift (WGS), CO 2 hydrogenation, dry reforming of methane (DRM) and ethanol steam reforming (ESR). In conclusion, we discuss insights into the future development of the AP-XPS technique and its applications.
Authors:
 [1] ;  [2] ;  [1] ;  [1] ;  [3] ;  [4] ;  [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
  2. Stony Brook Univ., NY (United States). Dept. of Chemistry
  3. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Stony Brook Univ., NY (United States). Dept. of Chemistry
Publication Date:
Report Number(s):
BNL-203312-2018-JAAM
Journal ID: ISSN 0368-2048
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
Journal of Electron Spectroscopy and Related Phenomena
Additional Journal Information:
Journal Volume: 221; Journal ID: ISSN 0368-2048
Publisher:
Elsevier
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1425096

Palomino, Robert M., Hamlyn, Rebecca, Liu, Zongyuan, Grinter, David C., Waluyo, Iradwikanari, Rodriguez, Jose A., and Senanayake, Sanjaya D.. Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry. United States: N. p., Web. doi:10.1016/j.elspec.2017.04.006.
Palomino, Robert M., Hamlyn, Rebecca, Liu, Zongyuan, Grinter, David C., Waluyo, Iradwikanari, Rodriguez, Jose A., & Senanayake, Sanjaya D.. Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry. United States. doi:10.1016/j.elspec.2017.04.006.
Palomino, Robert M., Hamlyn, Rebecca, Liu, Zongyuan, Grinter, David C., Waluyo, Iradwikanari, Rodriguez, Jose A., and Senanayake, Sanjaya D.. 2017. "Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry". United States. doi:10.1016/j.elspec.2017.04.006. https://www.osti.gov/servlets/purl/1425096.
@article{osti_1425096,
title = {Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry},
author = {Palomino, Robert M. and Hamlyn, Rebecca and Liu, Zongyuan and Grinter, David C. and Waluyo, Iradwikanari and Rodriguez, Jose A. and Senanayake, Sanjaya D.},
abstractNote = {In this paper we provide a summary of the recent development of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and its application to catalytic surface chemistry. The methodology as well as significant advantages and challenges associated with this novel technique are described. Details about specific examples of using AP-XPS to probe surface chemistry under working reaction conditions for a number of reactions are explained: CO oxidation, water-gas shift (WGS), CO2 hydrogenation, dry reforming of methane (DRM) and ethanol steam reforming (ESR). In conclusion, we discuss insights into the future development of the AP-XPS technique and its applications.},
doi = {10.1016/j.elspec.2017.04.006},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
number = ,
volume = 221,
place = {United States},
year = {2017},
month = {4}
}