Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering
Abstract
Zinc oxide (ZnO) nanowire arrays have potential applications for various devices including ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of the reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Stony Brook Univ., NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1425053
- Alternate Identifier(s):
- OSTI ID: 1411282
- Report Number(s):
- BNL-114871-2017-JAAM
Journal ID: ISSN 0003-6951; TRN: US1802019
- Grant/Contract Number:
- SC0012704; SC00122704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 111; Journal Issue: 23; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Yan, Danhua, Zhang, Wenrui, Cen, Jiajie, Stavitski, Eli, Sadowski, Jerzy T., Vescovo, Elio, Walter, Andrew, Attenkofer, Klaus, Stacchiola, Darío J., and Liu, Mingzhao. Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering. United States: N. p., 2017.
Web. doi:10.1063/1.5001043.
Yan, Danhua, Zhang, Wenrui, Cen, Jiajie, Stavitski, Eli, Sadowski, Jerzy T., Vescovo, Elio, Walter, Andrew, Attenkofer, Klaus, Stacchiola, Darío J., & Liu, Mingzhao. Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering. United States. https://doi.org/10.1063/1.5001043
Yan, Danhua, Zhang, Wenrui, Cen, Jiajie, Stavitski, Eli, Sadowski, Jerzy T., Vescovo, Elio, Walter, Andrew, Attenkofer, Klaus, Stacchiola, Darío J., and Liu, Mingzhao. Mon .
"Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering". United States. https://doi.org/10.1063/1.5001043. https://www.osti.gov/servlets/purl/1425053.
@article{osti_1425053,
title = {Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering},
author = {Yan, Danhua and Zhang, Wenrui and Cen, Jiajie and Stavitski, Eli and Sadowski, Jerzy T. and Vescovo, Elio and Walter, Andrew and Attenkofer, Klaus and Stacchiola, Darío J. and Liu, Mingzhao},
abstractNote = {Zinc oxide (ZnO) nanowire arrays have potential applications for various devices including ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of the reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.},
doi = {10.1063/1.5001043},
journal = {Applied Physics Letters},
number = 23,
volume = 111,
place = {United States},
year = {Mon Dec 04 00:00:00 EST 2017},
month = {Mon Dec 04 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
White Light-Emitting Diode From Sb-Doped p-ZnO Nanowire Arrays/n-GaN Film
journal, February 2015
- Ren, Xiaoliang; Zhang, Xianghui; Liu, Nishuang
- Advanced Functional Materials, Vol. 25, Issue 14
Wavelength-Emission Tuning of ZnO Nanowire-Based Light-Emitting Diodes by Cu Doping: Experimental and Computational Insights
journal, July 2011
- Lupan, Oleg; Pauporté, Thierry; Le Bahers, Tangui
- Advanced Functional Materials, Vol. 21, Issue 18
Role of size and defects in ultrafast broadband emission dynamics of ZnO nanostructures
journal, March 2014
- Appavoo, Kannatassen; Liu, Mingzhao; Sfeir, Matthew Y.
- Applied Physics Letters, Vol. 104, Issue 13
Phosphorus-Doped p–n Homojunction ZnO Nanowires: Growth Kinetics in Liquid and Their Optoelectronic Properties
journal, June 2015
- Lee, Wei-Che; Chen, Jui-Yuan; Huang, Chun-Wei
- Chemistry of Materials, Vol. 27, Issue 12
Seed layer synthesis effect on the concentration of interface defects and emission spectra of ZnO nanorods/p-GaN light-emitting diode: Interface defects and emission spectra of ZnO nanorods/p-GaN LED
journal, September 2016
- Alnoor, Hatim; Pozina, Galia; Willander, Magnus
- physica status solidi (a), Vol. 214, Issue 1
Low-Temperature Wafer-Scale Production of ZnO Nanowire Arrays
journal, July 2003
- Greene, Lori E.; Law, Matt; Goldberger, Joshua
- Angewandte Chemie International Edition, Vol. 42, Issue 26, p. 3031-3034
Critical Nucleation Effects on the Structural Relationship Between ZnO Seed Layer and Nanowires
journal, November 2012
- Guillemin, Sophie; Consonni, Vincent; Appert, Estelle
- The Journal of Physical Chemistry C, Vol. 116, Issue 47
Hydrothermal growth of ZnO nanowire arrays: fine tuning by precursor supersaturation
journal, January 2017
- Yan, Danhua; Cen, Jiajie; Zhang, Wenrui
- CrystEngComm, Vol. 19, Issue 3
Optimizing n-ZnO/p-Si heterojunctions for photodiode applications
journal, February 2002
- Lee, J. Y.; Choi, Y. S.; Kim, J. H.
- Thin Solid Films, Vol. 403-404
Developing new understanding of photoelectrochemical water splitting via in-situ techniques: A review on recent progress
journal, April 2017
- Cen, Jiajie; Wu, Qiyuan; Liu, Mingzhao
- Green Energy & Environment, Vol. 2, Issue 2
Optical Properties of ZnO Nanostructures
journal, August 2006
- Djurišić, Aleksandra B.; Leung, Yu Hang
- Small, Vol. 2, Issue 8-9
Photoluminescence and Lasing Properties of Catalyst-Free ZnO Nanorod Arrays Fabricated by Pulsed Laser Deposition
journal, November 2011
- Li, Qian; Gao, Kun; Hu, Zhigao
- The Journal of Physical Chemistry C, Vol. 116, Issue 3
X-ray Absorption Near-Edge Structure (XANES) Spectroscopy
journal, January 2014
- Henderson, G. S.; de Groot, F. M. F.; Moulton, B. J. A.
- Reviews in Mineralogy and Geochemistry, Vol. 78, Issue 1
Low-Temperature Fabrication of Light-Emitting Zinc Oxide Micropatterns Using Self-Assembled Monolayers
journal, March 2002
- Saito, N.; Haneda, H.; Sekiguchi, T.
- Advanced Materials, Vol. 14, Issue 6
General Route to Vertical ZnO Nanowire Arrays Using Textured ZnO Seeds
journal, July 2005
- Greene, Lori E.; Law, Matt; Tan, Dawud H.
- Nano Letters, Vol. 5, Issue 7
Selectively enhanced UV and NIR photoluminescence from a degenerate ZnO nanorod array film
journal, January 2014
- Zhu, Qiang; Xie, Changsheng; Li, Huayao
- Journal of Materials Chemistry C, Vol. 2, Issue 23
Repeated temperature modulation epitaxy for p-type doping and light-emitting diode based on ZnO
journal, December 2004
- Tsukazaki, Atsushi; Ohtomo, Akira; Onuma, Takeyoshi
- Nature Materials, Vol. 4, Issue 1
Synergistic effect of Indium and Gallium co-doping on growth behavior and physical properties of hydrothermally grown ZnO nanorods
journal, February 2017
- Lim, Jun Hyung; Lee, Seung Muk; Kim, Hyun-Suk
- Scientific Reports, Vol. 7, Issue 1
Enhancing Water Splitting Activity and Chemical Stability of Zinc Oxide Nanowire Photoanodes with Ultrathin Titania Shells
journal, June 2013
- Liu, Mingzhao; Nam, Chang-Yong; Black, Charles T.
- The Journal of Physical Chemistry C, Vol. 117, Issue 26
Preparation and characterization of nanostructured ZnO thin films for photoelectrochemical splitting of water
journal, February 2009
- Gupta, Monika; Sharma, Vidhika; Shrivastava, Jaya
- Bulletin of Materials Science, Vol. 32, Issue 1
Aqueous chemical growth of ZnO disks, rods, spindles and flowers: pH dependency and photoelectrochemical properties
journal, May 2011
- Pawar, R. C.; Shaikh, J. S.; Babar, A. A.
- Solar Energy, Vol. 85, Issue 5
Large-scale patterned ZnO nanorod arrays for efficient photoelectrochemical water splitting
journal, June 2015
- Hu, Yaping; Yan, Xiaoqin; Gu, Yousong
- Applied Surface Science, Vol. 339
Quantifying Bulk and Surface Recombination Processes in Nanostructured Water Splitting Photocatalysts via In Situ Ultrafast Spectroscopy
journal, January 2015
- Appavoo, Kannatassen; Liu, Mingzhao; Black, Charles T.
- Nano Letters, Vol. 15, Issue 2
Tuning the functionalities of a mesocrystal via structural coupling
journal, July 2015
- Liu, Heng-Jui; Liu, Yun-Ya; Tsai, Chih-Ya
- Scientific Reports, Vol. 5, Issue 1
Low energy electron imaging of domains and domain walls in magnesium-doped lithium niobate
journal, September 2016
- Nataf, G. F.; Grysan, P.; Guennou, M.
- Scientific Reports, Vol. 6, Issue 1
Enhanced ultraviolet sensitivity of zinc oxide nanoparticle photoconductors by surface passivation
journal, January 2011
- Qin, Liqiao; Shing, Christopher; Sawyer, Shayla
- Optical Materials, Vol. 33, Issue 3
Effect of aspect ratio and surface defects on the photocatalytic activity of ZnO nanorods
journal, April 2014
- Zhang, Xinyu; Qin, Jiaqian; Xue, Yanan
- Scientific Reports, Vol. 4, Issue 1
Surface defects control for ZnO nanorods synthesized by quenching and their anti-recombination in photocatalysis
journal, March 2015
- Fang, Jiawen; Fan, Huiqing; Ma, Yuan
- Applied Surface Science, Vol. 332
Facile Continuous Flow Injection Process for High Quality Long ZnO Nanowire Arrays Synthesis
journal, January 2012
- Chen, Liang-Yih; Yin, Yu-Tung
- Crystal Growth & Design, Vol. 12, Issue 3
A comprehensive review of ZnO materials and devices
journal, August 2005
- Özgür, Ü.; Alivov, Ya. I.; Liu, C.
- Journal of Applied Physics, Vol. 98, Issue 4
Works referencing / citing this record:
High-performance organic/inorganic hybrid ultraviolet p-NiO/PVK/n-ZnO heterojunction photodiodes with a poly( N -vinylcarbazole) insertion layer
journal, January 2019
- Hwang, Jun Dar; Fan, Chun Wei
- Journal of Materials Chemistry C, Vol. 7, Issue 12