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Title: Pathway-engineering for highly-aligned block copolymer arrays

While kinetic aspects of self-assembly can hinder ordering, non-equilibirum effects can also be exploited to enforce a particular kind of order. We develop a pathway-engineering approach, using it to select a particular arrangement of a block copolymer cylinder phase.
Authors:
 [1] ;  [2] ;  [2] ; ORCiD logo [1] ; ORCiD logo [2]
  1. Yale Univ., New Haven, CT (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Report Number(s):
BNL-114832-2017-JAAM
Journal ID: ISSN 2040-3364; NANOHL
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY
OSTI Identifier:
1425014

Choo, Youngwoo, Majewski, Paweł W., Fukuto, Masafumi, Osuji, Chinedum O., and Yager, Kevin G.. Pathway-engineering for highly-aligned block copolymer arrays. United States: N. p., Web. doi:10.1039/C7NR06069F.
Choo, Youngwoo, Majewski, Paweł W., Fukuto, Masafumi, Osuji, Chinedum O., & Yager, Kevin G.. Pathway-engineering for highly-aligned block copolymer arrays. United States. doi:10.1039/C7NR06069F.
Choo, Youngwoo, Majewski, Paweł W., Fukuto, Masafumi, Osuji, Chinedum O., and Yager, Kevin G.. 2017. "Pathway-engineering for highly-aligned block copolymer arrays". United States. doi:10.1039/C7NR06069F. https://www.osti.gov/servlets/purl/1425014.
@article{osti_1425014,
title = {Pathway-engineering for highly-aligned block copolymer arrays},
author = {Choo, Youngwoo and Majewski, Paweł W. and Fukuto, Masafumi and Osuji, Chinedum O. and Yager, Kevin G.},
abstractNote = {While kinetic aspects of self-assembly can hinder ordering, non-equilibirum effects can also be exploited to enforce a particular kind of order. We develop a pathway-engineering approach, using it to select a particular arrangement of a block copolymer cylinder phase.},
doi = {10.1039/C7NR06069F},
journal = {Nanoscale},
number = 1,
volume = 10,
place = {United States},
year = {2017},
month = {12}
}

Works referenced in this record:

Enhanced Order of Block Copolymer Cylinders in Single-Layer Films Using a Sweeping Solidification Front
journal, September 2007
  • Angelescu, D.?E.; Waller, J.?H.; Adamson, D.?H.
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Block Copolymer Thin Films: Physics and Applications
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Macroscopic 10-Terabit-per-Square-Inch Arrays from Block Copolymers with Lateral Order
journal, February 2009

Nanoscopic Patterned Materials with Tunable Dimensions via Atomic Layer Deposition on Block Copolymers
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  • DOI: 10.1002/adma.201002465