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Title: Transport Properties of Ionic Liquid Mixtures Containing Heterodications

Abstract

This report discusses the transport properties of ionic liquid mixtures that incorporate a series of asymmetrical dications, including heterodications. The dicationic ILs combine either triphenylphosphonium and trimethylammonium cationic sites that are bridged to methylimidazolium or methylpyrrolidinium cationic sites. Mixtures were made of the dicationic bis(trifluoromethylsulfonyl)amide ionic liquids with N-ethoxyethyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide. The IL mixtures were characterized for their transport properties (temperature dependent conductivity and viscosity) and thermal properties (melting point and glass transition point).

Authors:
 [1];  [1];  [1];  [1];  [2];  [2]
  1. Queensborough Community College, Queens, NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1425013
Report Number(s):
BNL-114826-2017-JAAM
Journal ID: ISSN 1938-6737
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
ECS Transactions (Online)
Additional Journal Information:
Journal Name: ECS Transactions (Online); Journal Volume: 75; Journal Issue: 15; Journal ID: ISSN 1938-6737
Publisher:
Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Lall-Ramnarine, S., Fernandez, E., Rodriguez, C., Wei, S., Dhiman, S., and Wishart, J. F. Transport Properties of Ionic Liquid Mixtures Containing Heterodications. United States: N. p., 2016. Web. doi:10.1149/07515.0555ecst.
Lall-Ramnarine, S., Fernandez, E., Rodriguez, C., Wei, S., Dhiman, S., & Wishart, J. F. Transport Properties of Ionic Liquid Mixtures Containing Heterodications. United States. doi:10.1149/07515.0555ecst.
Lall-Ramnarine, S., Fernandez, E., Rodriguez, C., Wei, S., Dhiman, S., and Wishart, J. F. Tue . "Transport Properties of Ionic Liquid Mixtures Containing Heterodications". United States. doi:10.1149/07515.0555ecst. https://www.osti.gov/servlets/purl/1425013.
@article{osti_1425013,
title = {Transport Properties of Ionic Liquid Mixtures Containing Heterodications},
author = {Lall-Ramnarine, S. and Fernandez, E. and Rodriguez, C. and Wei, S. and Dhiman, S. and Wishart, J. F.},
abstractNote = {This report discusses the transport properties of ionic liquid mixtures that incorporate a series of asymmetrical dications, including heterodications. The dicationic ILs combine either triphenylphosphonium and trimethylammonium cationic sites that are bridged to methylimidazolium or methylpyrrolidinium cationic sites. Mixtures were made of the dicationic bis(trifluoromethylsulfonyl)amide ionic liquids with N-ethoxyethyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide. The IL mixtures were characterized for their transport properties (temperature dependent conductivity and viscosity) and thermal properties (melting point and glass transition point).},
doi = {10.1149/07515.0555ecst},
journal = {ECS Transactions (Online)},
number = 15,
volume = 75,
place = {United States},
year = {2016},
month = {8}
}

Journal Article:
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