What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?

Hays, Kevin A.; Ruther, Rose E.; Kukay, Alexander J.; Cao, Pengfei; Saito, Tomonori; Wood, David L.; Li, Jianlin

doi:10.1016/j.jpowsour.2018.02.085

Title: What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?

Abstract

Lithium substituted polyacrylic acid (LiPAA) has previously been demonstrated as a superior binder over polyacrylic acid (PAA) for Si anodes, but from where does this enhanced performance arise? In this paper, full cells are assembled with PAA and LiPAA based Si-graphite composite anodes that dried at temperatures from 100 °C to 200 °C. The performance of full cells containing PAA based Si-graphite anodes largely depend on the secondary drying temperature, as decomposition of the binder is correlated to increased electrode moisture and a rise in cell impedance. Full cells containing LiPAA based Si-graphite composite electrodes display better Coulombic efficiency than those with PAA, because of the electrochemical reduction of the PAA binder. This is identified by attenuated total reflectance Fourier transform infrared spectrometry and observed gassing during the electrochemical reaction. Finally, Coulombic losses from the PAA and Si SEI, along with depletion of the Si capacity in the anode results in progressive underutilization of the cathode and full cell capacity loss.

Authors:

^[1]; Ruther, Rose E. ^[1];

^[1]; Cao, Pengfei ^[2]; Saito, Tomonori ^[2]; Wood, David L. ^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Publication Date:: Sun Mar 04 00:00:00 EST 2018

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1424453

Alternate Identifier(s):: OSTI ID: 1548643

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Volume: 384; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Li ion battery; Si graphite anode; polyacrylic acid; lithium substituted polyacrylic acid; full cells; residual water

Citation Formats


                    Hays, Kevin A., Ruther, Rose E., Kukay, Alexander J., Cao, Pengfei, Saito, Tomonori, Wood, David L., and Li, Jianlin. What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?.  United States: N. p., 2018. 
Web.  doi:10.1016/j.jpowsour.2018.02.085.

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                    Hays, Kevin A., Ruther, Rose E., Kukay, Alexander J., Cao, Pengfei, Saito, Tomonori, Wood, David L., & Li, Jianlin. What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?.  United States.  https://doi.org/10.1016/j.jpowsour.2018.02.085

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                    Hays, Kevin A., Ruther, Rose E., Kukay, Alexander J., Cao, Pengfei, Saito, Tomonori, Wood, David L., and Li, Jianlin. Sun .  
"What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?".  United States.  https://doi.org/10.1016/j.jpowsour.2018.02.085.  https://www.osti.gov/servlets/purl/1424453.

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@article{osti_1424453,

  title        = {What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?},

  author       = {Hays, Kevin A. and Ruther, Rose E. and Kukay, Alexander J. and Cao, Pengfei and Saito, Tomonori and Wood, David L. and Li, Jianlin},

  abstractNote = {Lithium substituted polyacrylic acid (LiPAA) has previously been demonstrated as a superior binder over polyacrylic acid (PAA) for Si anodes, but from where does this enhanced performance arise? In this paper, full cells are assembled with PAA and LiPAA based Si-graphite composite anodes that dried at temperatures from 100 °C to 200 °C. The performance of full cells containing PAA based Si-graphite anodes largely depend on the secondary drying temperature, as decomposition of the binder is correlated to increased electrode moisture and a rise in cell impedance. Full cells containing LiPAA based Si-graphite composite electrodes display better Coulombic efficiency than those with PAA, because of the electrochemical reduction of the PAA binder. This is identified by attenuated total reflectance Fourier transform infrared spectrometry and observed gassing during the electrochemical reaction. Finally, Coulombic losses from the PAA and Si SEI, along with depletion of the Si capacity in the anode results in progressive underutilization of the cathode and full cell capacity loss.},

  doi          = {10.1016/j.jpowsour.2018.02.085},

  journal      = {Journal of Power Sources},

  number       = ,

  volume       = 384,

  place        = {United States},

  year         = {Sun Mar 04 00:00:00 EST 2018},

  month        = {Sun Mar 04 00:00:00 EST 2018}

}

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Figure 1: Cycle life of A) LiPAA full cells and B) PAA full cells. The Coulombic efficiency for the first 10 cycles of C) LiPAA full cells and D) PAA full cells. The long term Coulombic efficiency of E) LiPAA full cells and F) PAA full cells. The secondary dryingmore »

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Title: What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?

Abstract

Citation Formats

Figures / Tables:

25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium-Ion Batteries journal, August 2013

Colossal Reversible Volume Changes in Lithium Alloys journal, January 2001

Mixed silicon–graphite composites as anode material for lithium ion batteries journal, September 2004

Silicon/Graphite Composite Electrodes for High-Capacity Anodes: Influence of Binder Chemistry on Cycling Stability journal, January 2008

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries journal, September 2011

Polyacrylate as Functional Binder for Silicon and Graphite Composite Electrode in Lithium-Ion Batteries journal, January 2011

Lithium polyacrylate as a binder for tin–cobalt–carbon negative electrodes in lithium-ion batteries journal, March 2010

Electrochemical lithiation performance and characterization of silicon–graphite composites with lithium, sodium, potassium, and ammonium polyacrylate binders journal, January 2015

Polyacrylate Modifier for Graphite Anode of Lithium-Ion Batteries journal, January 2009

Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries journal, June 2017

Partially Oxidized Silicon Particles for Stable Aqueous Slurries and Practical Large-Scale Making of Si-Based Electrodes journal, January 2015

Electrolyte Volume Effects on Electrochemical Performance and Solid Electrolyte Interphase in Si-Graphite/NMC Lithium-Ion Pouch Cells journal, May 2017

Correlation of Electrolyte Volume and Electrochemical Performance in Lithium-Ion Pouch Cells with Graphite Anodes and NMC532 Cathodes journal, January 2017

Oxidation Behavior of Copper at a Temperature below 300 °C and the Methodology for Passivation journal, February 2016

Thermal stability and degradation mechanisms of poly(acrylic acid) and its salts: Part 1—Poly(acrylic acid) journal, January 1990

Thermal stability and degradation mechanisms of poly(acrylic acid) and its salts: Part 2—Sodium and potassium salts journal, January 1990

Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination journal, October 1980

Mechanism of Interactions between CMC Binder and Si Single Crystal Facets journal, August 2014

Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation journal, May 2016

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Reversible Cycling of Crystalline Silicon Powder journal, January 2007

Performance of Full Cells Containing Carbonate-Based LiFSI Electrolytes and Silicon-Graphite Negative Electrodes journal, December 2015

Lithium trapping in alloy forming electrodes and current collectors for lithium based batteries journal, January 2017

The surface chemistry of amorphous silica. Zhuravlev model journal, November 2000

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A Comparative Study of Synthetic Graphite and Li Electrodes in Electrolyte Solutions Based on Ethylene Carbonate-Dimethyl Carbonate Mixtures journal, January 1996

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Thermal stability and degradation mechanisms of poly(acrylic acid) and its salts: Part 2—Sodium and potassium salts
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Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination
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Mechanism of Interactions between CMC Binder and Si Single Crystal Facets
journal, August 2014

Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation
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An Apparatus for the Study of In Situ Gas Evolution in Li-Ion Pouch Cells
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Reversible Cycling of Crystalline Silicon Powder
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The surface chemistry of amorphous silica. Zhuravlev model
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