Enhancement and destruction of spin-Peierls physics in a one-dimensional quantum magnet under pressure
Abstract
The application of pressure reveals a rich phase diagram for the quantum S = 1/2 spin chain material TiOCl. We performed x-ray diffraction on single-crystal samples in a diamond-anvil cell down to T = 4 K and pressures up to 14.5 GPa. Remarkably, the magnetic interaction scale increases dramatically with increasing pressure, as indicated by the high onset temperature of the spin-Peierls phase. The spin-Peierls phase was probed at similar to 6 GPa up to 215 K but possibly extends in temperature to above T = 300 K, indicating the possibility of a quantum singlet state at room temperature. Near the critical pressure for the transition to the more metallic phase, coexisting phases are exemplified by incommensurate order in two directions. Finally, further comparisons are made with the phase diagrams of related spin-Peierls systems that display metallicity and superconductivity under pressure.
- Authors:
-
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES); Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES); Stanford Univ., CA (United States). Dept. of Applied Physics
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States); Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1423522
- Alternate Identifier(s):
- OSTI ID: 1421297; OSTI ID: 1426199
- Grant/Contract Number:
- AC02-76SF00515; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 97; Journal Issue: 5; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Rotundu, Costel R., Wen, Jiajia, He, Wei, Choi, Yongseong, Haskel, Daniel, and Lee, Young S. Enhancement and destruction of spin-Peierls physics in a one-dimensional quantum magnet under pressure. United States: N. p., 2018.
Web. doi:10.1103/physrevb.97.054415.
Rotundu, Costel R., Wen, Jiajia, He, Wei, Choi, Yongseong, Haskel, Daniel, & Lee, Young S. Enhancement and destruction of spin-Peierls physics in a one-dimensional quantum magnet under pressure. United States. https://doi.org/10.1103/physrevb.97.054415
Rotundu, Costel R., Wen, Jiajia, He, Wei, Choi, Yongseong, Haskel, Daniel, and Lee, Young S. Thu .
"Enhancement and destruction of spin-Peierls physics in a one-dimensional quantum magnet under pressure". United States. https://doi.org/10.1103/physrevb.97.054415. https://www.osti.gov/servlets/purl/1423522.
@article{osti_1423522,
title = {Enhancement and destruction of spin-Peierls physics in a one-dimensional quantum magnet under pressure},
author = {Rotundu, Costel R. and Wen, Jiajia and He, Wei and Choi, Yongseong and Haskel, Daniel and Lee, Young S.},
abstractNote = {The application of pressure reveals a rich phase diagram for the quantum S = 1/2 spin chain material TiOCl. We performed x-ray diffraction on single-crystal samples in a diamond-anvil cell down to T = 4 K and pressures up to 14.5 GPa. Remarkably, the magnetic interaction scale increases dramatically with increasing pressure, as indicated by the high onset temperature of the spin-Peierls phase. The spin-Peierls phase was probed at similar to 6 GPa up to 215 K but possibly extends in temperature to above T = 300 K, indicating the possibility of a quantum singlet state at room temperature. Near the critical pressure for the transition to the more metallic phase, coexisting phases are exemplified by incommensurate order in two directions. Finally, further comparisons are made with the phase diagrams of related spin-Peierls systems that display metallicity and superconductivity under pressure.},
doi = {10.1103/physrevb.97.054415},
journal = {Physical Review B},
number = 5,
volume = 97,
place = {United States},
year = {2018},
month = {2}
}
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Figures / Tables:
FIG. 1: Structure of TiOCl. (a) Crystal structure of TiOCl. (b) Representation of the commensurate dimer singlet state at T < Tc1 (the spin-Peierls state). (c) Scans along K through the commensurate (0,1.5,0) and (0,2.5,0) peak positions showing the peak intensity normalized to the nearest Bragg peak (0,2,0). For clarity,more »
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Works referenced in this record:
Infrared optical properties of the spin- quantum magnet TiOCl
journal, March 2004
- Caimi, G.; Degiorgi, L.; Kovaleva, N. N.
- Physical Review B, Vol. 69, Issue 12
Ordering phenomena in quasi-one-dimensional organic conductors
journal, May 2007
- Dressel, Martin
- Naturwissenschaften, Vol. 94, Issue 7
chains and spin-Peierls transition in TiOCl
journal, January 2003
- Seidel, Alexander; Marianetti, Chris A.; Chou, F. C.
- Physical Review B, Vol. 67, Issue 2
Two pressure-induced structural phase transitions in TiOCl
journal, October 2010
- Ebad-Allah, J.; Schönleber, A.; van Smaalen, S.
- Physical Review B, Vol. 82, Issue 13
Evaluations of pressure-transmitting media for cryogenic experiments with diamond anvil cell
journal, December 2009
- Tateiwa, Naoyuki; Haga, Yoshinori
- Review of Scientific Instruments, Vol. 80, Issue 12
Commensurate fluctuations in the pseudogap and incommensurate spin-Peierls phases of TiOCl
journal, March 2007
- Clancy, J. P.; Gaulin, B. D.; Rule, K. C.
- Physical Review B, Vol. 75, Issue 10
Structure of the incommensurate phase of the quantum magnet TiOCl
journal, June 2006
- Schönleber, Andreas; van Smaalen, Sander; Palatinus, Lukáš
- Physical Review B, Vol. 73, Issue 21
Incommensurate structure of the spin-Peierls compound TiOCl in zero and finite magnetic fields
journal, May 2006
- Krimmel, A.; Strempfer, J.; Bohnenbuck, B.
- Physical Review B, Vol. 73, Issue 17
Magnetic susceptibility in the spin-Peierls system
journal, June 1995
- Riera, José; Dobry, Ariel
- Physical Review B, Vol. 51, Issue 22
TiOCl, TiOBr-are these RVB d 1 , S=1/2 materials? The results of scandium substitution set in the context of other S=1/2 systems of current interest for high-temperature superconductivity and the metal-insulator transition
journal, March 1993
- Beynon, R. J.; Wilson, J. A.
- Journal of Physics: Condensed Matter, Vol. 5, Issue 13
An x-ray topographic study of diamond anvils: Correlation between defects and helium diffusion
journal, May 2006
- Dewaele, Agnès; Loubeyre, Paul; André, Ramesh
- Journal of Applied Physics, Vol. 99, Issue 10
Observation of the spin-Peierls transition in linear (spin-1/2) chains in an inorganic compound
journal, June 1993
- Hase, Masashi; Terasaki, Ichiro; Uchinokura, Kunimitsu
- Physical Review Letters, Vol. 70, Issue 23
Enhanced Dimerization of TiOCl under Pressure: Spin-Peierls to Peierls Transition
journal, February 2009
- Blanco-Canosa, S.; Rivadulla, F.; Piñeiro, A.
- Physical Review Letters, Vol. 102, Issue 5
Can the Mott Insulator TiOCl be Metallized by Doping? A First-Principles Study
journal, April 2010
- Zhang, Yu-Zhong; Foyevtsova, Kateryna; Jeschke, Harald O.
- Physical Review Letters, Vol. 104, Issue 14
�ber Titanchloride. V. Titan(III)-oxychlorid
journal, June 1958
- Sch�fer, Harald; Wartenpfuhl, Friedel; Weise, Eberhard
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 295, Issue 3-4
Possible metallization of the Mott insulators TiOCl and TiOBr: Effects of doping and external pressure
journal, December 2009
- Kuntscher, C. A.; Klemm, M.; Horn, S.
- The European Physical Journal Special Topics, Vol. 180, Issue 1
Metallizing the Mott insulator TiOCl by electron doping
journal, November 2006
- Craco, L.; Laad, M. S.; Müller-Hartmann, E.
- Journal of Physics: Condensed Matter, Vol. 18, Issue 48
From spin-Peierls to superconductivity: (TMTTF) 2 PF 6 under high pressure
journal, January 2001
- Jaccard, D.; Wilhelm, H.; Jérome, D.
- Journal of Physics: Condensed Matter, Vol. 13, Issue 4
Peierls instability in Heisenberg chains
journal, December 1974
- Pytte, E.
- Physical Review B, Vol. 10, Issue 11
Spin-Peierls transitions in magnetic donor-acceptor compounds of tetrathiafulvalene (TTF) with bisdithiolene metal complexes
journal, October 1976
- Jacobs, I. S.; Bray, J. W.; Hart, H. R.
- Physical Review B, Vol. 14, Issue 7
Zero-Field Incommensurate Spin-Peierls Phase with Interchain Frustration in TiOCl
journal, August 2005
- Rückamp, R.; Baier, J.; Kriener, M.
- Physical Review Letters, Vol. 95, Issue 9
Resonating valence bonds: A new kind of insulator?
journal, February 1973
- Anderson, P. W.
- Materials Research Bulletin, Vol. 8, Issue 2
X-ray scattering study of the spin-Peierls transition and soft phonon behavior in TiOCl
journal, December 2007
- Abel, E. T.; Matan, K.; Chou, F. C.
- Physical Review B, Vol. 76, Issue 21
Effects of Uniaxial Strain on Transport Properties of Organic Conductor α-(BEDT-TTF) 2 I 3 and Discovery of Superconductivity
journal, August 2002
- Tajima, Naoya; Ebina-Tajima, Akiko; Tamura, Masafumi
- Journal of the Physical Society of Japan, Vol. 71, Issue 8
Spin-Peierls transition in TiOCl
journal, March 2005
- Shaz, Mohammad; van Smaalen, Sander; Palatinus, Lukas
- Physical Review B, Vol. 71, Issue 10
Invited Article: High-pressure techniques for condensed matter physics at low temperature
journal, April 2010
- Feng, Yejun; Jaramillo, R.; Wang, Jiyang
- Review of Scientific Instruments, Vol. 81, Issue 4
Orbital order in the low-dimensional quantum spin system TiOCl probed by ESR
journal, October 2003
- Kataev, V.; Baier, J.; Möller, A.
- Physical Review B, Vol. 68, Issue 14
Superconducting Transition of (TMTTF) 2 PF 6 above 50 kbar [TMTTF = Tetramethyltetrathiafulvalene]
journal, April 2000
- Adachi, Takafumi; Ojima, Emiko; Kato, Kiyonori
- Journal of the American Chemical Society, Vol. 122, Issue 13
Effect of covalent bonding on magnetism and the missing neutron intensity in copper oxide compounds
journal, October 2009
- Walters, Andrew C.; Perring, Toby G.; Caux, Jean-Sébastien
- Nature Physics, Vol. 5, Issue 12
Electron-lattice coupling and broken symmetries of the molecular salt
journal, September 2004
- Yu, W.; Zhang, F.; Zamborszky, F.
- Physical Review B, Vol. 70, Issue 12
Pressure-induced metallization and structural phase transition of the Mott-Hubbard insulator TiOBr
journal, December 2007
- Kuntscher, C. A.; Frank, S.; Pashkin, A.
- Physical Review B, Vol. 76, Issue 24
Giant phonon softening in the pseudogap phase of the quantum spin system
journal, October 2004
- Lemmens, P.; Choi, K. Y.; Caimi, G.
- Physical Review B, Vol. 70, Issue 13
Possible pressure-induced insulator-to-metal transition in low-dimensional
journal, November 2006
- Kuntscher, C. A.; Frank, S.; Pashkin, A.
- Physical Review B, Vol. 74, Issue 18
Spin-Peierls transition in N-methyl-N-ethyl-morpholinium-ditetracyanoquinodimethanide [MEM- ]
journal, May 1979
- Huizinga, S.; Kommandeur, J.; Sawatzky, G. A.
- Physical Review B, Vol. 19, Issue 9
Mott-Hubbard gap closure and structural phase transition in the oxyhalides TiOBr and TiOCl under pressure
journal, July 2008
- Kuntscher, C. A.; Pashkin, A.; Hoffmann, H.
- Physical Review B, Vol. 78, Issue 3
Effect of pressure on the electrical transport and structure of
journal, April 2008
- Forthaus, Martin K.; Taetz, Timo; Möller, Angela
- Physical Review B, Vol. 77, Issue 16
Observation of a Spin-Peierls Transition in a Heisenberg Antiferromagnetic Linear-Chain System
journal, September 1975
- Bray, J. W.; Hart, H. R.; Interrante, L. V.
- Physical Review Letters, Vol. 35, Issue 11
Heat capacity of the quantum magnet TiOCl
journal, July 2005
- Hemberger, J.; Hoinkis, M.; Klemm, M.
- Physical Review B, Vol. 72, Issue 1
Pressure-induced spin-Peierls to incommensurate charge-density-wave transition in the ground state of TiOCl
journal, May 2010
- Prodi, A.; Helton, J. S.; Feng, Yejun
- Physical Review B, Vol. 81, Issue 20
Works referencing / citing this record:
The role of magnetic order in VOCl
journal, May 2019
- Ekholm, M.; Schönleber, A.; van Smaalen, S.
- Journal of Physics: Condensed Matter, Vol. 31, Issue 32
The role of magnetic order in VOCl
text, January 2019
- Ekholm, Marcus; Schönleber, Andreas; van Smaalen, Sander
- arXiv
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