A comparison of pulsed and continuous lasers for high-temperature Raman measurements of anhydrite
Abstract
Abstract Oxygen carrier particles (OCPs) serve as fuel oxidant in emerging chemical looping combustion systems. However, chemical looping combustion process optimization is hindered by the lack of online sensors for measurements of OCP oxidation states at temperatures up to 1,000 °C and pressures up to 10 atm. We are investigating Raman spectroscopy as a potential solution, as this technique is known for its ability to provide noninvasive, molecularly specific information in real time in a wide variety of applications. As a case study, Raman spectra from high‐temperature (>1,000 °C) anhydrite, a potential OCP, are presented using pulsed and continuous wave excitation at 532 nm. When pulsed excitation is coupled with time‐gated detection, background signal from thermal radiation can be significantly reduced from single pulse spectra, outperforming results using an ungated detector. Also, laser heating of the sample is not observed but laser‐induced breakdown spectra increasingly appear with increasing temperature and pulse intensity. Compared with pulsed excitation, continuous wave excitation with longer acquisition time, offers higher signal to noise and avoids the risk for laser‐induced breakdown spectra but demonstrates minor sample heating. Finally, the data demonstrate practical utility by (a) providing a calibration of anhydrite's ν 1 (1,017 cm −1 ) Raman temperature‐dependent band position andmore »
- Publication Date:
- Research Org.:
- Washington State Univ., Pullman, WA (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1782241
- Alternate Identifier(s):
- OSTI ID: 1422839
- Grant/Contract Number:
- FE0027840
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Raman Spectroscopy
- Additional Journal Information:
- Journal Volume: 49; Journal Issue: 5; Journal ID: ISSN 0377-0486
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 20 FOSSIL-FUELED POWER PLANTS; 47 OTHER INSTRUMENTATION; calcium sulfate; high temperature; laser heating; pulsed laser; time gating
Citation Formats
Kirtley, John, Leichner, Victoria, Anderson, Benjamin R., and Eilers, Hergen. A comparison of pulsed and continuous lasers for high-temperature Raman measurements of anhydrite. United States: N. p., 2018.
Web. doi:10.1002/jrs.5356.
Kirtley, John, Leichner, Victoria, Anderson, Benjamin R., & Eilers, Hergen. A comparison of pulsed and continuous lasers for high-temperature Raman measurements of anhydrite. United States. https://doi.org/10.1002/jrs.5356
Kirtley, John, Leichner, Victoria, Anderson, Benjamin R., and Eilers, Hergen. Tue .
"A comparison of pulsed and continuous lasers for high-temperature Raman measurements of anhydrite". United States. https://doi.org/10.1002/jrs.5356. https://www.osti.gov/servlets/purl/1782241.
@article{osti_1782241,
title = {A comparison of pulsed and continuous lasers for high-temperature Raman measurements of anhydrite},
author = {Kirtley, John and Leichner, Victoria and Anderson, Benjamin R. and Eilers, Hergen},
abstractNote = {Abstract Oxygen carrier particles (OCPs) serve as fuel oxidant in emerging chemical looping combustion systems. However, chemical looping combustion process optimization is hindered by the lack of online sensors for measurements of OCP oxidation states at temperatures up to 1,000 °C and pressures up to 10 atm. We are investigating Raman spectroscopy as a potential solution, as this technique is known for its ability to provide noninvasive, molecularly specific information in real time in a wide variety of applications. As a case study, Raman spectra from high‐temperature (>1,000 °C) anhydrite, a potential OCP, are presented using pulsed and continuous wave excitation at 532 nm. When pulsed excitation is coupled with time‐gated detection, background signal from thermal radiation can be significantly reduced from single pulse spectra, outperforming results using an ungated detector. Also, laser heating of the sample is not observed but laser‐induced breakdown spectra increasingly appear with increasing temperature and pulse intensity. Compared with pulsed excitation, continuous wave excitation with longer acquisition time, offers higher signal to noise and avoids the risk for laser‐induced breakdown spectra but demonstrates minor sample heating. Finally, the data demonstrate practical utility by (a) providing a calibration of anhydrite's ν 1 (1,017 cm −1 ) Raman temperature‐dependent band position and by (b) providing estimates of temperature using the ratios of the Stokes/anti‐Stokes ν 1 integrated intensities. These results demonstrate the first high‐temperature, pulsed Raman spectra from anhydrite while evaluating challenges associated with high‐temperature, Raman measurements of OCP materials in general.},
doi = {10.1002/jrs.5356},
journal = {Journal of Raman Spectroscopy},
number = 5,
volume = 49,
place = {United States},
year = {Tue Feb 27 00:00:00 EST 2018},
month = {Tue Feb 27 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 2 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Raman study of magnetite (Fe3O4): laser-induced thermal effects and oxidation
journal, January 2003
- Shebanova, Olga N.; Lazor, Peter
- Journal of Raman Spectroscopy, Vol. 34, Issue 11
New evidences of in situ laser irradiation effects on γ-Fe2O3 nanoparticles: a Raman spectroscopic study
journal, September 2010
- El Mendili, Y.; Bardeau, J. -F.; Randrianantoandro, N.
- Journal of Raman Spectroscopy, Vol. 42, Issue 2
Importance of temperature-dependent optical properties for Raman-temperature measurements for silicon
journal, September 1983
- Jellison, G. E.; Lowndes, D. H.; Wood, R. F.
- Physical Review B, Vol. 28, Issue 6
Temperature-depending Raman line-shift of silicon carbide
journal, December 2009
- Bauer, Michael; Gigler, Alexander M.; Huber, Andreas J.
- Journal of Raman Spectroscopy, Vol. 40, Issue 12
High-Temperature “Spectrochronopotentiometry”: Correlating Electrochemical Performance with In Situ Raman Spectroscopy in Solid Oxide Fuel Cells
journal, October 2012
- Kirtley, John D.; Halat, David M.; McIntyre, Melissa D.
- Analytical Chemistry, Vol. 84, Issue 22
Raman microspectroscopy of some iron oxides and oxyhydroxides
journal, November 1997
- de Faria, D. L. A.; Venâncio Silva, S.; de Oliveira, M. T.
- Journal of Raman Spectroscopy, Vol. 28, Issue 11
Optical and structural properties of Mn doped CaSO4 powders synthesized by sol-gel process
journal, December 2016
- Kadari, Ahmed; Mahi, Khaled; Mostefa, Rabah
- Journal of Alloys and Compounds, Vol. 688
Stand-off Raman spectroscopy: a powerful technique for qualitative and quantitative analysis of inorganic and organic compounds including explosives
journal, February 2011
- Zachhuber, Bernhard; Ramer, Georg; Hobro, Alison
- Analytical and Bioanalytical Chemistry, Vol. 400, Issue 8
Temperature-Dependent Nonlinear Phonon Shifts in a Supported MoS 2 Monolayer
journal, June 2014
- Taube, Andrzej; Judek, Jarosław; Jastrzębski, Cezariusz
- ACS Applied Materials & Interfaces, Vol. 6, Issue 12
Stokes/Anti-Stokes Raman Vibrational Temperatures: Reference Materials, Standard Lamps, and Spectrophotometric Calibrations
journal, July 1983
- Malyj, M.; Griffiths, J. E.
- Applied Spectroscopy, Vol. 37, Issue 4
High pressure-temperature Raman measurements of H[sub 2]O melting to 22 GPa and 900 K
journal, January 2004
- Lin, Jung-Fu; Militzer, Burkhard; Struzhkin, Viktor V.
- The Journal of Chemical Physics, Vol. 121, Issue 17
Raman Spectra of the Different Phases in the CaSO4–H2O System
journal, September 2014
- Prieto-Taboada, Nagore; Gómez-Laserna, Olivia; Martínez-Arkarazo, Irantzu
- Analytical Chemistry, Vol. 86, Issue 20, p. 10131-10137
Use of time-resolved Raman scattering to determine temperatures in shocked carbon tetrachloride
journal, May 1997
- Pangilinan, G. I.; Gupta, Y. M.
- Journal of Applied Physics, Vol. 81, Issue 10
Raman Spectroscopy for Homeland Security Applications
journal, June 2012
- Mogilevsky, Gregory; Borland, Laura; Brickhouse, Mark
- International Journal of Spectroscopy, Vol. 2012
High-pressure and high-temperature study of the phase transition in anhydrite
journal, September 2007
- Ma, Y. M.; Zhou, Q.; He, Z.
- Journal of Physics: Condensed Matter, Vol. 19, Issue 42
In Situ Studies of Fuel Oxidation in Solid Oxide Fuel Cells
journal, March 2007
- Pomfret, Michael B.; Owrutsky, Jeffrey C.; Walker, Robert A.
- Analytical Chemistry, Vol. 79, Issue 6
A combined remote Raman and LIBS instrument for characterizing minerals with 532nm laser excitation
journal, August 2009
- Sharma, Shiv K.; Misra, Anupam K.; Lucey, Paul G.
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 73, Issue 3
Combined remote LIBS and Raman spectroscopy at 8.6m of sulfur-containing minerals, and minerals coated with hematite or covered with basaltic dust
journal, December 2007
- Sharma, S. K.; Misra, A. K.; Lucey, P. G.
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 68, Issue 4
An operando surface enhanced Raman spectroscopy (SERS) study of carbon deposition on SOFC anodes
journal, January 2015
- Li, Xiaxi; Liu, Mingfei; Lee, Jung-pil
- Physical Chemistry Chemical Physics, Vol. 17, Issue 33
Temperature-dependent nonlinear phonon shifts in a supported MoS2 monolayer
text, January 2014
- Taube, Andrzej; Judek, Jarosław; Jastrzębski, Cezariusz
- arXiv