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Title: Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells

Authors:
 [1];  [2];  [3];  [4];  [5];  [5];  [6];  [7];  [6];  [6];  [7];  [4];  [8];  [3]; ORCiD logo [6]
  1. Univ. at Buffalo, NY (United States). Dept. of Chemical and Biological Engineering; East China Univ. of Science and Technology, Shanghai (China). School of Mechanical and Power Engineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
  5. Oregon State Univ., Corvallis, OR (United States). School of Chemical, Biological, and Environmental Engineering
  6. Univ. at Buffalo, NY (United States). Dept. of Chemical and Biological Engineering
  7. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  8. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. at Buffalo, NY (United States); East China Univ. of Science and Technology, Shanghai (China); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE Office of Science (SC); National Science Foundation (NSF); Shanghai Natural Science Foundation of China; USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1422592
Alternate Identifier(s):
OSTI ID: 1417922; OSTI ID: 1558078
Report Number(s):
LA-UR-19-27321
Journal ID: ISSN 0935-9648; TRN: US1801631
Grant/Contract Number:  
AC05-00OR22725; AC02-06CH11357; SC0012704; CBET-1604392; 16ZR1408600; 89233218CNA000001
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 30; Journal Issue: 11; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; carbon nanocomposites; electrocatalysis; oxygen reduction; proton exchange membrane fuel cells; single atomic Co; Energy Sciences

Citation Formats

Wang, Xiao Xia, Cullen, David A., Pan, Yung-Tin, Hwang, Sooyeon, Wang, Maoyu, Feng, Zhenxing, Wang, Jingyun, Engelhard, Mark H., Zhang, Hanguang, He, Yanghua, Shao, Yuyan, Su, Dong, More, Karren L., Spendelow, Jacob S., and Wu, Gang. Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells. United States: N. p., 2018. Web. https://doi.org/10.1002/adma.201706758.
Wang, Xiao Xia, Cullen, David A., Pan, Yung-Tin, Hwang, Sooyeon, Wang, Maoyu, Feng, Zhenxing, Wang, Jingyun, Engelhard, Mark H., Zhang, Hanguang, He, Yanghua, Shao, Yuyan, Su, Dong, More, Karren L., Spendelow, Jacob S., & Wu, Gang. Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells. United States. https://doi.org/10.1002/adma.201706758
Wang, Xiao Xia, Cullen, David A., Pan, Yung-Tin, Hwang, Sooyeon, Wang, Maoyu, Feng, Zhenxing, Wang, Jingyun, Engelhard, Mark H., Zhang, Hanguang, He, Yanghua, Shao, Yuyan, Su, Dong, More, Karren L., Spendelow, Jacob S., and Wu, Gang. Wed . "Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells". United States. https://doi.org/10.1002/adma.201706758. https://www.osti.gov/servlets/purl/1422592.
@article{osti_1422592,
title = {Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells},
author = {Wang, Xiao Xia and Cullen, David A. and Pan, Yung-Tin and Hwang, Sooyeon and Wang, Maoyu and Feng, Zhenxing and Wang, Jingyun and Engelhard, Mark H. and Zhang, Hanguang and He, Yanghua and Shao, Yuyan and Su, Dong and More, Karren L. and Spendelow, Jacob S. and Wu, Gang},
abstractNote = {},
doi = {10.1002/adma.201706758},
journal = {Advanced Materials},
number = 11,
volume = 30,
place = {United States},
year = {2018},
month = {1}
}

Journal Article:
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Cited by: 58 works
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Figures / Tables:

Figure 1 Figure 1: STEM images and element analysis for the best performing 20Co-NC-1100 catalysts. Aberration-corrected MAADF-STEM images (a-e) with accompanying EEL point spectra (e-f). The point spectrum in (f) was taken at the dark neighboring support area in (e) and only shows C and no any N and Co. The pointmore » spectrum (g) was taken on the bright atom in (e) and shows both Co and N, indicating that Co is coordinated with N at an atomic scale.« less

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    Boosting the performance of the Fe–N–C catalyst for the oxygen reduction reaction by introducing single-walled carbon nanohorns as branches on carbon fibers
    journal, January 2019

    • Zhang, Jianshuo; Liu, Yang; Yu, Zhoubin
    • Journal of Materials Chemistry A, Vol. 7, Issue 40
    • DOI: 10.1039/c9ta08938a

    Co single-atoms on ultrathin N-doped porous carbon via a biomass complexation strategy for high performance metal–air batteries
    journal, January 2020

    • Wang, Yanqiu; Yu, Baoying; Liu, Kang
    • Journal of Materials Chemistry A, Vol. 8, Issue 4
    • DOI: 10.1039/c9ta12171d

    Cobalt/zinc dual-sites coordinated with nitrogen in nanofibers enabling efficient and durable oxygen reduction reaction in acidic fuel cells
    journal, January 2020

    • Zang, Jian; Wang, Feiteng; Cheng, Qingqing
    • Journal of Materials Chemistry A, Vol. 8, Issue 7
    • DOI: 10.1039/c9ta12207a

    From IR to x-rays: gaining molecular level insights on metal-organic frameworks through spectroscopy
    journal, August 2019

    • Hanna, Lauren; Lockard, Jenny V.
    • Journal of Physics: Condensed Matter, Vol. 31, Issue 48
    • DOI: 10.1088/1361-648x/ab38da

    Core-Shell Polydopamine@Zr-Hemin MOFs Derived Fe-N-Doped Porous Carbon Nanospheres Electrocatalysts for the Oxygen Reduction
    journal, January 2018

    • Wang, Yinling; Wang, Juan; Zhang, Youliang
    • Journal of The Electrochemical Society, Vol. 165, Issue 10
    • DOI: 10.1149/2.1101810jes

    Alloyed Pt 3 M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction
    journal, January 2019

    • Louisia, Stéphane; Thomas, Yohann R. J.; Lecante, Pierre
    • Beilstein Journal of Nanotechnology, Vol. 10
    • DOI: 10.3762/bjnano.10.125

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.