Dissection of the Voltage Losses of an Acidic Quinone Redox Flow Battery
Abstract
We measure the polarization characteristics of a quinone-bromide redox flow battery with interdigitated flow fields, using electrochemical impedance spectroscopy and voltammetry of a full cell and of a half cell against a reference electrode. We find linear polarization behavior at 50% state of charge all the way to the short-circuit current density of 2.5 A/cm2. We uniquely identify the polarization area-specific resistance (ASR) of each electrode, the membrane ASR to ionic current, and the electronic contact ASR. We use voltage probes to deduce the electronic current density through each sheet of carbon paper in the quinone-bearing electrode. By also interpreting the results using the Newman 1-D porous electrode model, we deduce the volumetric exchange current density of the porous electrode. We uniquely evaluate the power dissipation and identify a correspondence to the contributions to the electrode ASR from the faradaic, electronic, and ionic transport processes. We find that, within the electrode, more power is dissipated in the faradaic process than in the electronic and ionic conduction processes combined, despite the observed linear polarization behavior. We examine the sensitivity of the ASR to the values of the model parameters. The greatest performance improvement is anticipated from increasing the volumetric exchange currentmore »
- Authors:
-
- Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences (SEAS); Hong Kong Univ. of Science and Technology, Kowloon (China). Dept. of Mechanical and Aerospace Engineering
- Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences (SEAS)
- Publication Date:
- Research Org.:
- Harvard Univ., Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E); Massachusetts Clean Energy Technology Center (MassCEC), Boston, MA (United States)
- OSTI Identifier:
- 1422403
- Grant/Contract Number:
- AR0000348
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 6; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; Flow batteries; Modeling
Citation Formats
Chen, Qing, Gerhardt, Michael R., and Aziz, Michael J. Dissection of the Voltage Losses of an Acidic Quinone Redox Flow Battery. United States: N. p., 2017.
Web. doi:10.1149/2.0721706jes.
Chen, Qing, Gerhardt, Michael R., & Aziz, Michael J. Dissection of the Voltage Losses of an Acidic Quinone Redox Flow Battery. United States. https://doi.org/10.1149/2.0721706jes
Chen, Qing, Gerhardt, Michael R., and Aziz, Michael J. Tue .
"Dissection of the Voltage Losses of an Acidic Quinone Redox Flow Battery". United States. https://doi.org/10.1149/2.0721706jes. https://www.osti.gov/servlets/purl/1422403.
@article{osti_1422403,
title = {Dissection of the Voltage Losses of an Acidic Quinone Redox Flow Battery},
author = {Chen, Qing and Gerhardt, Michael R. and Aziz, Michael J.},
abstractNote = {We measure the polarization characteristics of a quinone-bromide redox flow battery with interdigitated flow fields, using electrochemical impedance spectroscopy and voltammetry of a full cell and of a half cell against a reference electrode. We find linear polarization behavior at 50% state of charge all the way to the short-circuit current density of 2.5 A/cm2. We uniquely identify the polarization area-specific resistance (ASR) of each electrode, the membrane ASR to ionic current, and the electronic contact ASR. We use voltage probes to deduce the electronic current density through each sheet of carbon paper in the quinone-bearing electrode. By also interpreting the results using the Newman 1-D porous electrode model, we deduce the volumetric exchange current density of the porous electrode. We uniquely evaluate the power dissipation and identify a correspondence to the contributions to the electrode ASR from the faradaic, electronic, and ionic transport processes. We find that, within the electrode, more power is dissipated in the faradaic process than in the electronic and ionic conduction processes combined, despite the observed linear polarization behavior. We examine the sensitivity of the ASR to the values of the model parameters. The greatest performance improvement is anticipated from increasing the volumetric exchange current density.},
doi = {10.1149/2.0721706jes},
journal = {Journal of the Electrochemical Society},
number = 6,
volume = 164,
place = {United States},
year = {Tue Mar 28 00:00:00 EDT 2017},
month = {Tue Mar 28 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Electrochemical Impedance Spectroscopy and its Applications
book, January 2002
- Lasia, Andrzej; Conway, B. E.; Bockris, J. O'M.
- Modern Aspects of Electrochemistry, p. 143-248
Theoretical Analysis of Current Distribution in Porous Electrodes
journal, January 1962
- Newman, John S.; Tobias, Charles W.
- Journal of The Electrochemical Society, Vol. 109, Issue 12
The Influence of Electrode and Channel Configurations on Flow Battery Performance
journal, January 2014
- Darling, Robert M.; Perry, Mike L.
- Journal of The Electrochemical Society, Vol. 161, Issue 9
A comparative study of carbon felt and activated carbon based electrodes for sodium polysulfide/bromine redox flow battery
journal, September 2006
- Zhou, Hantao; Zhang, Huamin; Zhao, Ping
- Electrochimica Acta, Vol. 51, Issue 28, p. 6304-6312
Polarization curve analysis of all-vanadium redox flow batteries
journal, August 2011
- Aaron, Doug; Tang, Zhijiang; Papandrew, Alexander B.
- Journal of Applied Electrochemistry, Vol. 41, Issue 10
A palladium-hydrogen probe electrode for use as a microreference electrode
journal, June 1968
- Fleischmann, M.; Hiddleston, J. N.
- Journal of Physics E: Scientific Instruments, Vol. 1, Issue 6
A Quinone-Bromide Flow Battery with 1 W/cm2 Power Density
journal, July 2015
- Chen, Qing; Gerhardt, Michael R.; Hartle, Lauren
- Journal of The Electrochemical Society, Vol. 163, Issue 1, p. A5010-A5013
Model of Performance of a Regenerative Hydrogen Chlorine Fuel Cell for Grid-Scale Electrical Energy Storage
journal, January 2011
- Rugolo, Jason; Huskinson, Brian; Aziz, Michael J.
- Journal of The Electrochemical Society, Vol. 159, Issue 2
High Performance Vanadium Redox Flow Batteries with Optimized Electrode Configuration and Membrane Selection
journal, January 2012
- Liu, Q. H.; Grim, G. M.; Papandrew, A. B.
- Journal of The Electrochemical Society, Vol. 159, Issue 8
Alkaline quinone flow battery
journal, September 2015
- Lin, K.; Chen, Q.; Gerhardt, M. R.
- Science, Vol. 349, Issue 6255, p. 1529-1532
Positioning the reference electrode in proton exchange membrane fuel cells: calculations of primary and secondary current distribution
journal, March 2004
- Liu, Zhenyu; Wainright, J. S.; Huang, Weiwei
- Electrochimica Acta, Vol. 49, Issue 6
Composition and Conductivity of Membranes Equilibrated with Solutions of Sulfuric Acid and Vanadyl Sulfate
journal, January 2013
- Tang, Zhijiang; Svoboda, Rachel; Lawton, Jamie S.
- Journal of The Electrochemical Society, Vol. 160, Issue 9
Flow Batteries: Current Status and Trends
journal, September 2015
- Soloveichik, Grigorii L.
- Chemical Reviews, Vol. 115, Issue 20
In situ potential distribution measurement in an all-vanadium flow battery
journal, January 2013
- Liu, Qinghua; Turhan, Ahmet; Zawodzinski, Thomas A.
- Chemical Communications, Vol. 49, Issue 56
Porous-electrode theory with battery applications
journal, January 1975
- Newman, John; Tiedemann, William
- AIChE Journal, Vol. 21, Issue 1
Resolving Losses at the Negative Electrode in All-Vanadium Redox Flow Batteries Using Electrochemical Impedance Spectroscopy
journal, January 2014
- Sun, Che-Nan; Delnick, Frank M.; Aaron, Douglas S.
- Journal of The Electrochemical Society, Vol. 161, Issue 6
Analysis of a model for the operation of a vanadium redox battery
journal, April 2011
- Vynnycky, M.
- Energy, Vol. 36, Issue 4
A metal-free organic–inorganic aqueous flow battery
journal, January 2014
- Huskinson, Brian; Marshak, Michael P.; Suh, Changwon
- Nature, Vol. 505, Issue 7482, p. 195-198
Works referencing / citing this record:
Redox flow batteries—Concepts and chemistries for cost-effective energy storage
journal, March 2018
- Holland-Cunz, Matthäa Verena; Cording, Faye; Friedl, Jochen
- Frontiers in Energy, Vol. 12, Issue 2
Redox targeting-based flow batteries
journal, August 2019
- Ye, Jiaye; Xia, Lu; Wu, Chun
- Journal of Physics D: Applied Physics, Vol. 52, Issue 44
The Effect of Interdigitated Channel and Land Dimensions on Flow Cell Performance
journal, January 2018
- Gerhardt, Michael R.; Wong, Andrew A.; Aziz, Michael J.
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Effect of Operating Temperature on Individual Half-Cell Reactions in All-Vanadium Redox Flow Batteries
journal, November 2018
- Schweiss, Ruediger; Meiser, Christian; Dan, Dana
- Batteries, Vol. 4, Issue 4