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Title: Positional effects of second-sphere amide pendants on electrochemical CO 2 reduction catalyzed by iron porphyrins

Abstract

The development of catalysts for electrochemical reduction of carbon dioxide offers an attractive approach to transforming this greenhouse gas into value-added carbon products with sustainable energy input. Inspired by natural bioinorganic systems that feature precisely positioned hydrogen-bond donors in the secondary coordination sphere to direct chemical transformations occurring at redox-active metal centers, we now report the design, synthesis, and characterization of a series of iron tetraphenylporphyrin (Fe-TPP) derivatives bearing amide pendants at various positions at the periphery of the metal core. Proper positioning of the amide pendants greatly affects the electrocatalytic activity for carbon dioxide reduction to carbon monoxide. In particular, derivatives bearing proximal and distal amide pendants on the ortho position of the phenyl ring exhibit significantly larger turnover frequencies (TOF) compared to the analogous para-functionalized amide isomers or unfunctionalized Fe-TPP. Analysis of TOF as a function of catalyst standard reduction potential enables first-sphere electronic effects to be disentangled from second-sphere through-space interactions, suggesting that the ortho-functionalized porphyrins can utilize the latter second-sphere property to promote CO2 reduction. Indeed, the distally-functionalized ortho-amide isomer shows a significantly larger through-space interaction than its proximal ortho-amide analogue. These data establish that proper positioning of secondary coordination sphere groups is an effective designmore » element for breaking electronic scaling relationships that are often observed in electrochemical CO2 reduction.The development of catalysts for electrochemical reduction of carbon dioxide offers an attractive approach to transforming this greenhouse gas into value-added carbon products with sustainable energy input.« less

Authors:
 [1];  [1];  [2];  [1]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, USA
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1422003
Alternate Identifier(s):
OSTI ID: 1465425
Grant/Contract Number:  
101528-002; AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 11; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Nichols, Eva M., Derrick, Jeffrey S., Nistanaki, Sepand K., Smith, Peter T., and Chang, Christopher J. Positional effects of second-sphere amide pendants on electrochemical CO 2 reduction catalyzed by iron porphyrins. United Kingdom: N. p., 2018. Web. doi:10.1039/C7SC04682K.
Nichols, Eva M., Derrick, Jeffrey S., Nistanaki, Sepand K., Smith, Peter T., & Chang, Christopher J. Positional effects of second-sphere amide pendants on electrochemical CO 2 reduction catalyzed by iron porphyrins. United Kingdom. doi:https://doi.org/10.1039/C7SC04682K
Nichols, Eva M., Derrick, Jeffrey S., Nistanaki, Sepand K., Smith, Peter T., and Chang, Christopher J. Mon . "Positional effects of second-sphere amide pendants on electrochemical CO 2 reduction catalyzed by iron porphyrins". United Kingdom. doi:https://doi.org/10.1039/C7SC04682K.
@article{osti_1422003,
title = {Positional effects of second-sphere amide pendants on electrochemical CO 2 reduction catalyzed by iron porphyrins},
author = {Nichols, Eva M. and Derrick, Jeffrey S. and Nistanaki, Sepand K. and Smith, Peter T. and Chang, Christopher J.},
abstractNote = {The development of catalysts for electrochemical reduction of carbon dioxide offers an attractive approach to transforming this greenhouse gas into value-added carbon products with sustainable energy input. Inspired by natural bioinorganic systems that feature precisely positioned hydrogen-bond donors in the secondary coordination sphere to direct chemical transformations occurring at redox-active metal centers, we now report the design, synthesis, and characterization of a series of iron tetraphenylporphyrin (Fe-TPP) derivatives bearing amide pendants at various positions at the periphery of the metal core. Proper positioning of the amide pendants greatly affects the electrocatalytic activity for carbon dioxide reduction to carbon monoxide. In particular, derivatives bearing proximal and distal amide pendants on the ortho position of the phenyl ring exhibit significantly larger turnover frequencies (TOF) compared to the analogous para-functionalized amide isomers or unfunctionalized Fe-TPP. Analysis of TOF as a function of catalyst standard reduction potential enables first-sphere electronic effects to be disentangled from second-sphere through-space interactions, suggesting that the ortho-functionalized porphyrins can utilize the latter second-sphere property to promote CO2 reduction. Indeed, the distally-functionalized ortho-amide isomer shows a significantly larger through-space interaction than its proximal ortho-amide analogue. These data establish that proper positioning of secondary coordination sphere groups is an effective design element for breaking electronic scaling relationships that are often observed in electrochemical CO2 reduction.The development of catalysts for electrochemical reduction of carbon dioxide offers an attractive approach to transforming this greenhouse gas into value-added carbon products with sustainable energy input.},
doi = {10.1039/C7SC04682K},
journal = {Chemical Science},
number = 11,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1039/C7SC04682K

Citation Metrics:
Cited by: 12 works
Citation information provided by
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Figures / Tables:

Fig. 1 Fig. 1: Titration of 3,5-[bis(trifluoromethyl)phenyl]amide to Fe-TPP under CO2 showing current increases with increasing concentrations of amide. Conditions: 0.1 M TBAPF6 in DMF, 1 mM Fe-TPP.

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Works referenced in this record:

Exploring secondary-sphere interactions in Fe–N x H y complexes relevant to N 2 fixation
journal, January 2017


Electrochemical reduction of carbon dioxide catalyzed by Rh(diphos)2Cl
journal, September 1984

  • Slater, Sydney; Wagenknecht, John H.
  • Journal of the American Chemical Society, Vol. 106, Issue 18
  • DOI: 10.1021/ja00330a064

Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis
journal, February 2014

  • Sampson, Matthew D.; Nguyen, An D.; Grice, Kyle A.
  • Journal of the American Chemical Society, Vol. 136, Issue 14
  • DOI: 10.1021/ja501252f

Nickel N-heterocyclic carbene–pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water
journal, January 2011

  • Thoi, V. Sara; Chang, Christopher J.
  • Chemical Communications, Vol. 47, Issue 23
  • DOI: 10.1039/c1cc10449g

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
journal, January 2012

  • Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya
  • Energy & Environmental Science, Vol. 5, Issue 11
  • DOI: 10.1039/c2ee22528j

Nitrite reduction by copper through ligand-mediated proton and electron transfer
journal, January 2015

  • Moore, Cameron M.; Szymczak, Nathaniel K.
  • Chemical Science, Vol. 6, Issue 6
  • DOI: 10.1039/C5SC00720H

Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO-
journal, January 1987

  • Ishida, Hitoshi.; Tanaka, Koji.; Tanaka, Toshio.
  • Organometallics, Vol. 6, Issue 1
  • DOI: 10.1021/om00144a033

Life on carbon monoxide: X-ray structure of Rhodospirillum rubrum Ni-Fe-S carbon monoxide dehydrogenase
journal, October 2001

  • Drennan, C. L.; Heo, J.; Sintchak, M. D.
  • Proceedings of the National Academy of Sciences, Vol. 98, Issue 21
  • DOI: 10.1073/pnas.211429998

Ultraefficient homogeneous catalyst for the CO 2 -to-CO electrochemical conversion
journal, October 2014

  • Costentin, Cyrille; Passard, Guillaume; Robert, Marc
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
  • DOI: 10.1073/pnas.1416697111

Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations
journal, October 1991

  • Hammouche, Mohamed; Lexa, Doris; Momenteau, Michel
  • Journal of the American Chemical Society, Vol. 113, Issue 22
  • DOI: 10.1021/ja00022a038

Electrocatalytic Behavior of Metal Porphyrins in the Reduction of Carbon Dioxide
journal, April 1979

  • Takahashi, Katsuhiro; Hiratsuka, Kazuya; Sasaki, Hideo
  • Chemistry Letters, Vol. 8, Issue 4
  • DOI: 10.1246/cl.1979.305

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO 2 -to-CO Electrochemical Conversion
journal, December 2016

  • Azcarate, Iban; Costentin, Cyrille; Robert, Marc
  • Journal of the American Chemical Society, Vol. 138, Issue 51
  • DOI: 10.1021/jacs.6b07014

Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase
journal, November 2007


Modeling Substrate- and Inhibitor-Bound Forms of Liver Alcohol Dehydrogenase:  Chemistry of Mononuclear Nitrogen/Sulfur-Ligated Zinc Alcohol, Formamide, and Sulfoxide Complexes
journal, September 2002

  • Makowska-Grzyska, Magdalena M.; Jeppson, Peter C.; Allred, Russell A.
  • Inorganic Chemistry, Vol. 41, Issue 19
  • DOI: 10.1021/ic0255609

Electrochemical reduction of carbon dioxide catalyzed by [Pd(triphosphine)(solvent)](BF4)2 complexes: synthetic and mechanistic studies
journal, November 1991

  • DuBois, Daniel L.; Miedaner, Alex; Haltiwanger, R. Curtis
  • Journal of the American Chemical Society, Vol. 113, Issue 23, p. 8753-8764
  • DOI: 10.1021/ja00023a023

Tetraaza-macrocyclic cobalt(II) and nickel(II) complexes as electron-transfer agents in the photo(electro)chemical and electrochemical reduction of carbon dioxide
journal, January 1984

  • Tinnemans, A. H. A.; Koster, T. P. M.; Thewissen, D. H. M. W.
  • Recueil des Travaux Chimiques des Pays-Bas, Vol. 103, Issue 10
  • DOI: 10.1002/recl.19841031004

De Novo 3D Structure Determination from Sub-milligram Protein Samples by Solid-State 100 kHz MAS NMR Spectroscopy
journal, September 2014

  • Agarwal, Vipin; Penzel, Susanne; Szekely, Kathrin
  • Angewandte Chemie International Edition, Vol. 53, Issue 45
  • DOI: 10.1002/anie.201405730

Carbon dioxide activation by cobalt(I) macrocycles: factors affecting carbon dioxide and carbon monoxide binding
journal, January 1991

  • Fujita, Etsuko; Creutz, Carol; Sutin, Norman
  • Journal of the American Chemical Society, Vol. 113, Issue 1
  • DOI: 10.1021/ja00001a048

Electrocatalytic reduction of carbon dioxide by 2,2'-bipyridine complexes of rhodium and iridium
journal, December 1988

  • Bolinger, C. Mark; Story, Nicole; Sullivan, B. Patrick
  • Inorganic Chemistry, Vol. 27, Issue 25
  • DOI: 10.1021/ic00298a016

Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO) 3 Cl (bipy = 2,2′-bipyridine)
journal, January 1984

  • Hawecker, Jeannot; Lehn, Jean-Marie; Ziessel, Raymond
  • J. Chem. Soc., Chem. Commun., Issue 6
  • DOI: 10.1039/C39840000328

Proton-Coupled O−O Activation on a Redox Platform Bearing a Hydrogen-Bonding Scaffold
journal, February 2003

  • Chang, Christopher J.; Chng, Leng Leng; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 125, Issue 7
  • DOI: 10.1021/ja028548o

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis
journal, June 2012

  • Costentin, Cyrille; Drouet, Samuel; Robert, Marc
  • Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242
  • DOI: 10.1021/ja303560c

Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid
journal, March 2017

  • Roy, Souvik; Sharma, Bhaskar; Pécaut, Jacques
  • Journal of the American Chemical Society, Vol. 139, Issue 10
  • DOI: 10.1021/jacs.6b11474

Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO 2 -to-CO Conversion Catalyzed by Iron Porphyrins
journal, December 2016

  • Azcarate, Iban; Costentin, Cyrille; Robert, Marc
  • The Journal of Physical Chemistry C, Vol. 120, Issue 51
  • DOI: 10.1021/acs.jpcc.6b09947

Synthetic Heme-Dioxygen Complexes
journal, May 1994

  • Momenteau, Michel; Reed, Christopher A.
  • Chemical Reviews, Vol. 94, Issue 3
  • DOI: 10.1021/cr00027a006

Conformational Control of Intramolecular Hydrogen Bonding in Heme Models: Maximal CoII-O2 Binding in a C-Clamp Porphyrin
journal, April 1995

  • Chang, C. K.; Liang, Ying; Aviles, Gladys
  • Journal of the American Chemical Society, Vol. 117, Issue 14
  • DOI: 10.1021/ja00119a044

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions
journal, October 2016


Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins
journal, March 1975

  • Collman, James P.; Gagne, Robert R.; Reed, Christopher
  • Journal of the American Chemical Society, Vol. 97, Issue 6
  • DOI: 10.1021/ja00839a026

Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles
journal, June 2011

  • Dogutan, Dilek K.; McGuire, Robert; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 133, Issue 24
  • DOI: 10.1021/ja202138m

Activating Fe(I) Porphyrins for the Hydrogen Evolution Reaction Using Second-Sphere Proton Transfer Residues
journal, February 2017


Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process
journal, November 1986

  • Beley, Marc.; Collin, Jean Paul.; Ruppert, Romain.
  • Journal of the American Chemical Society, Vol. 108, Issue 24
  • DOI: 10.1021/ja00284a003

Hydrogen-bonded oxyhemoglobin models with substituted picket-fence porphyrins: the model compound equivalent of site-directed mutagenesis
journal, April 1992

  • Wuenschell, Gerald E.; Tetreau, Catherine; Lavalette, Daniel
  • Journal of the American Chemical Society, Vol. 114, Issue 9
  • DOI: 10.1021/ja00035a028

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO
journal, May 2012

  • Smieja, J. M.; Benson, E. E.; Kumar, B.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1119863109

Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays
journal, March 2012

  • Carver, Colin T.; Matson, Benjamin D.; Mayer, James M.
  • Journal of the American Chemical Society, Vol. 134, Issue 12
  • DOI: 10.1021/ja211987f

Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst
journal, January 2013

  • Kang, Peng; Meyer, Thomas J.; Brookhart, Maurice
  • Chemical Science, Vol. 4, Issue 9
  • DOI: 10.1039/c3sc51339d

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production
journal, August 2011

  • Helm, M. L.; Stewart, M. P.; Bullock, R. M.
  • Science, Vol. 333, Issue 6044, p. 863-866
  • DOI: 10.1126/science.1205864

[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction
journal, September 2011

  • Bourrez, Marc; Molton, Florian; Chardon-Noblat, Sylvie
  • Angewandte Chemie International Edition, Vol. 50, Issue 42
  • DOI: 10.1002/anie.201103616

Dioxygen Binding in Iron and Cobalt Picnic Basket Porphyrins
journal, July 1994

  • Collman, James P.; Zhang, Xumu; Wong, Kelvin
  • Journal of the American Chemical Society, Vol. 116, Issue 14
  • DOI: 10.1021/ja00093a026

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
journal, October 2012


Catalysis of the electrochemical reduction of carbon dioxide by iron(“0”) porphyrins
journal, July 1988

  • Hammouche, M.; Lexa, D.; Savéant, J. M.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2
  • DOI: 10.1016/0022-0728(88)80372-3

Studies of Cobalt-Mediated Electrocatalytic CO 2 Reduction Using a Redox-Active Ligand
journal, April 2014

  • Lacy, David C.; McCrory, Charles C. L.; Peters, Jonas C.
  • Inorganic Chemistry, Vol. 53, Issue 10
  • DOI: 10.1021/ic403122j

Structure of the  2 2 Ni-dependent CO dehydrogenase component of the Methanosarcina barkeri acetyl-CoA decarbonylase/synthase complex
journal, July 2008

  • Gong, W.; Hao, B.; Wei, Z.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 28
  • DOI: 10.1073/pnas.0800415105

Molecular Designs for Controlling the Local Environments around Metal Ions
journal, July 2015


Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere
journal, June 2013

  • Yang, Jenny Y.; Smith, Stuart E.; Liu, Tianbiao
  • Journal of the American Chemical Society, Vol. 135, Issue 26
  • DOI: 10.1021/ja400705a

Proton-Assisted Reduction of CO 2 by Cobalt Aminopyridine Macrocycles
journal, April 2016

  • Chapovetsky, Alon; Do, Thomas H.; Haiges, Ralf
  • Journal of the American Chemical Society, Vol. 138, Issue 18
  • DOI: 10.1021/jacs.6b01980

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
journal, September 2013

  • Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
  • Journal of the American Chemical Society, Vol. 135, Issue 38
  • DOI: 10.1021/ja4074003

A bioinspired iron catalyst for nitrate and perchlorate reduction
journal, November 2016


Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins:  Synergystic Effect of Weak Brönsted Acids
journal, January 1996

  • Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel
  • Journal of the American Chemical Society, Vol. 118, Issue 7
  • DOI: 10.1021/ja9534462

Photoinduced irreversible insertion of CO 2 into a metal–hydride bond
journal, January 1984

  • Sullivan, B. Patrick; Meyer, Thomas J.
  • J. Chem. Soc., Chem. Commun., Issue 18
  • DOI: 10.1039/C39840001244

Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo
journal, December 2014

  • Matson, Ellen M.; Park, Yun Ji; Fout, Alison R.
  • Journal of the American Chemical Society, Vol. 136, Issue 50
  • DOI: 10.1021/ja510615p

Steric and Hydrogen-Bonding Effects on the Stability of Copper Complexes with Small Molecules
journal, September 2004

  • Wada, Akira; Honda, Yasutaka; Yamaguchi, Syuhei
  • Inorganic Chemistry, Vol. 43, Issue 18
  • DOI: 10.1021/ic0496572

Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO 2
journal, June 2013

  • Costentin, Cyrille; Drouet, Samuel; Passard, Guillaume
  • Journal of the American Chemical Society, Vol. 135, Issue 24
  • DOI: 10.1021/ja4030148

Cobalt Porphyrin Catalyzed Reduction of CO 2 . Radiation Chemical, Photochemical, and Electrochemical Studies
journal, April 1998

  • Behar, D.; Dhanasekaran, T.; Neta, P.
  • The Journal of Physical Chemistry A, Vol. 102, Issue 17
  • DOI: 10.1021/jp9807017

Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
journal, September 1980

  • Fisher, Barbara J.; Eisenberg, Richard
  • Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363
  • DOI: 10.1021/ja00544a035

Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
journal, January 2009

  • Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J.
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B804323J

Bio-inspired mechanistic insights into CO2 reduction
journal, April 2015


Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation
journal, April 2010

  • Shook, Ryan L.; Borovik, A. S.
  • Inorganic Chemistry, Vol. 49, Issue 8
  • DOI: 10.1021/ic901550k

Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water
journal, January 1984

  • Beley, Marc; Collin, Jean-Paul; Ruppert, Romain
  • Journal of the Chemical Society, Chemical Communications, Issue 19
  • DOI: 10.1039/c39840001315

Structural and Spectroscopic Characterization of a Mononuclear Hydroperoxo-Copper(II) Complex with Tripodal Pyridylamine Ligands
journal, April 1998


Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013

  • Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr300463y

Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
journal, December 2009

  • Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar9001679

[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction
journal, September 2011

  • Bourrez, Marc; Molton, Florian; Chardon-Noblat, Sylvie
  • Angewandte Chemie, Vol. 123, Issue 42
  • DOI: 10.1002/ange.201103616

A Synthetic Nickel Electrocatalyst with a Turnover Frequency above 100 000 s−1 for H2 Production
journal, November 2011


    Works referencing / citing this record:

    Structural and Spectroscopic Characterization of a Mononuclear Hydroperoxo-Copper(II) Complex with Tripodal Pyridylamine Ligands
    journal, April 1998


    [Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction
    journal, September 2011

    • Bourrez, Marc; Molton, Florian; Chardon-Noblat, Sylvie
    • Angewandte Chemie International Edition, Vol. 50, Issue 42
    • DOI: 10.1002/anie.201103616

    De Novo 3D Structure Determination from Sub-milligram Protein Samples by Solid-State 100 kHz MAS NMR Spectroscopy
    journal, September 2014

    • Agarwal, Vipin; Penzel, Susanne; Szekely, Kathrin
    • Angewandte Chemie International Edition, Vol. 53, Issue 45
    • DOI: 10.1002/anie.201405730

    Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO 2 Reduction of Iron Porphyrins
    journal, February 2019

    • Gotico, Philipp; Boitrel, Bernard; Guillot, Régis
    • Angewandte Chemie International Edition, Vol. 58, Issue 14
    • DOI: 10.1002/anie.201814339

    Rh I -Catalyzed P III -Directed C−H Bond Alkylation: Design of Multifunctional Phosphines for Carboxylation of Aryl Bromides with Carbon Dioxide
    journal, August 2019

    • Zhang, Zhuan; Roisnel, Thierry; Dixneuf, Pierre H.
    • Angewandte Chemie International Edition, Vol. 58, Issue 40
    • DOI: 10.1002/anie.201906913

    Tetraaza-macrocyclic cobalt(II) and nickel(II) complexes as electron-transfer agents in the photo(electro)chemical and electrochemical reduction of carbon dioxide
    journal, January 1984

    • Tinnemans, A. H. A.; Koster, T. P. M.; Thewissen, D. H. M. W.
    • Recueil des Travaux Chimiques des Pays-Bas, Vol. 103, Issue 10
    • DOI: 10.1002/recl.19841031004

    Catalysis of the electrochemical reduction of carbon dioxide by iron(“0”) porphyrins
    journal, July 1988

    • Hammouche, M.; Lexa, D.; Savéant, J. M.
    • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2
    • DOI: 10.1016/0022-0728(88)80372-3

    Bio-inspired mechanistic insights into CO2 reduction
    journal, April 2015


    Molecular Designs for Controlling the Local Environments around Metal Ions
    journal, July 2015


    Activating Fe(I) Porphyrins for the Hydrogen Evolution Reaction Using Second-Sphere Proton Transfer Residues
    journal, February 2017


    Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO 2 -to-CO Conversion Catalyzed by Iron Porphyrins
    journal, December 2016

    • Azcarate, Iban; Costentin, Cyrille; Robert, Marc
    • The Journal of Physical Chemistry C, Vol. 120, Issue 51
    • DOI: 10.1021/acs.jpcc.6b09947

    Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions
    journal, October 2016


    Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
    journal, December 2009

    • Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko
    • Accounts of Chemical Research, Vol. 42, Issue 12
    • DOI: 10.1021/ar9001679

    Synthetic Heme-Dioxygen Complexes
    journal, May 1994

    • Momenteau, Michel; Reed, Christopher A.
    • Chemical Reviews, Vol. 94, Issue 3
    • DOI: 10.1021/cr00027a006

    Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
    journal, June 2013

    • Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
    • Chemical Reviews, Vol. 113, Issue 8
    • DOI: 10.1021/cr300463y

    Electrocatalytic reduction of carbon dioxide by 2,2'-bipyridine complexes of rhodium and iridium
    journal, December 1988

    • Bolinger, C. Mark; Story, Nicole; Sullivan, B. Patrick
    • Inorganic Chemistry, Vol. 27, Issue 25
    • DOI: 10.1021/ic00298a016

    Modeling Substrate- and Inhibitor-Bound Forms of Liver Alcohol Dehydrogenase:  Chemistry of Mononuclear Nitrogen/Sulfur-Ligated Zinc Alcohol, Formamide, and Sulfoxide Complexes
    journal, September 2002

    • Makowska-Grzyska, Magdalena M.; Jeppson, Peter C.; Allred, Russell A.
    • Inorganic Chemistry, Vol. 41, Issue 19
    • DOI: 10.1021/ic0255609

    Steric and Hydrogen-Bonding Effects on the Stability of Copper Complexes with Small Molecules
    journal, September 2004

    • Wada, Akira; Honda, Yasutaka; Yamaguchi, Syuhei
    • Inorganic Chemistry, Vol. 43, Issue 18
    • DOI: 10.1021/ic0496572

    Studies of Cobalt-Mediated Electrocatalytic CO 2 Reduction Using a Redox-Active Ligand
    journal, April 2014

    • Lacy, David C.; McCrory, Charles C. L.; Peters, Jonas C.
    • Inorganic Chemistry, Vol. 53, Issue 10
    • DOI: 10.1021/ic403122j

    Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation
    journal, April 2010

    • Shook, Ryan L.; Borovik, A. S.
    • Inorganic Chemistry, Vol. 49, Issue 8
    • DOI: 10.1021/ic901550k

    Carbon dioxide activation by cobalt(I) macrocycles: factors affecting carbon dioxide and carbon monoxide binding
    journal, January 1991

    • Fujita, Etsuko; Creutz, Carol; Sutin, Norman
    • Journal of the American Chemical Society, Vol. 113, Issue 1
    • DOI: 10.1021/ja00001a048

    Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations
    journal, October 1991

    • Hammouche, Mohamed; Lexa, Doris; Momenteau, Michel
    • Journal of the American Chemical Society, Vol. 113, Issue 22
    • DOI: 10.1021/ja00022a038

    Electrochemical reduction of carbon dioxide catalyzed by [Pd(triphosphine)(solvent)](BF4)2 complexes: synthetic and mechanistic studies
    journal, November 1991

    • DuBois, Daniel L.; Miedaner, Alex; Haltiwanger, R. Curtis
    • Journal of the American Chemical Society, Vol. 113, Issue 23, p. 8753-8764
    • DOI: 10.1021/ja00023a023

    Hydrogen-bonded oxyhemoglobin models with substituted picket-fence porphyrins: the model compound equivalent of site-directed mutagenesis
    journal, April 1992

    • Wuenschell, Gerald E.; Tetreau, Catherine; Lavalette, Daniel
    • Journal of the American Chemical Society, Vol. 114, Issue 9
    • DOI: 10.1021/ja00035a028

    Dioxygen Binding in Iron and Cobalt Picnic Basket Porphyrins
    journal, July 1994

    • Collman, James P.; Zhang, Xumu; Wong, Kelvin
    • Journal of the American Chemical Society, Vol. 116, Issue 14
    • DOI: 10.1021/ja00093a026

    Conformational Control of Intramolecular Hydrogen Bonding in Heme Models: Maximal CoII-O2 Binding in a C-Clamp Porphyrin
    journal, April 1995

    • Chang, C. K.; Liang, Ying; Aviles, Gladys
    • Journal of the American Chemical Society, Vol. 117, Issue 14
    • DOI: 10.1021/ja00119a044

    Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process
    journal, November 1986

    • Beley, Marc.; Collin, Jean Paul.; Ruppert, Romain.
    • Journal of the American Chemical Society, Vol. 108, Issue 24
    • DOI: 10.1021/ja00284a003

    Electrochemical reduction of carbon dioxide catalyzed by Rh(diphos)2Cl
    journal, September 1984

    • Slater, Sydney; Wagenknecht, John H.
    • Journal of the American Chemical Society, Vol. 106, Issue 18
    • DOI: 10.1021/ja00330a064

    Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
    journal, September 1980

    • Fisher, Barbara J.; Eisenberg, Richard
    • Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363
    • DOI: 10.1021/ja00544a035

    Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins
    journal, March 1975

    • Collman, James P.; Gagne, Robert R.; Reed, Christopher
    • Journal of the American Chemical Society, Vol. 97, Issue 6
    • DOI: 10.1021/ja00839a026

    Proton-Coupled O−O Activation on a Redox Platform Bearing a Hydrogen-Bonding Scaffold
    journal, February 2003

    • Chang, Christopher J.; Chng, Leng Leng; Nocera, Daniel G.
    • Journal of the American Chemical Society, Vol. 125, Issue 7
    • DOI: 10.1021/ja028548o

    Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles
    journal, June 2011

    • Dogutan, Dilek K.; McGuire, Robert; Nocera, Daniel G.
    • Journal of the American Chemical Society, Vol. 133, Issue 24
    • DOI: 10.1021/ja202138m

    Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays
    journal, March 2012

    • Carver, Colin T.; Matson, Benjamin D.; Mayer, James M.
    • Journal of the American Chemical Society, Vol. 134, Issue 12
    • DOI: 10.1021/ja211987f

    Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis
    journal, June 2012

    • Costentin, Cyrille; Drouet, Samuel; Robert, Marc
    • Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242
    • DOI: 10.1021/ja303560c

    Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere
    journal, June 2013

    • Yang, Jenny Y.; Smith, Stuart E.; Liu, Tianbiao
    • Journal of the American Chemical Society, Vol. 135, Issue 26
    • DOI: 10.1021/ja400705a

    Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO 2
    journal, June 2013

    • Costentin, Cyrille; Drouet, Samuel; Passard, Guillaume
    • Journal of the American Chemical Society, Vol. 135, Issue 24
    • DOI: 10.1021/ja4030148

    Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
    journal, September 2013

    • Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
    • Journal of the American Chemical Society, Vol. 135, Issue 38
    • DOI: 10.1021/ja4074003

    Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis
    journal, February 2014

    • Sampson, Matthew D.; Nguyen, An D.; Grice, Kyle A.
    • Journal of the American Chemical Society, Vol. 136, Issue 14
    • DOI: 10.1021/ja501252f

    Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo
    journal, December 2014

    • Matson, Ellen M.; Park, Yun Ji; Fout, Alison R.
    • Journal of the American Chemical Society, Vol. 136, Issue 50
    • DOI: 10.1021/ja510615p

    Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins:  Synergystic Effect of Weak Brönsted Acids
    journal, January 1996

    • Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel
    • Journal of the American Chemical Society, Vol. 118, Issue 7
    • DOI: 10.1021/ja9534462

    Proton-Assisted Reduction of CO 2 by Cobalt Aminopyridine Macrocycles
    journal, April 2016

    • Chapovetsky, Alon; Do, Thomas H.; Haiges, Ralf
    • Journal of the American Chemical Society, Vol. 138, Issue 18
    • DOI: 10.1021/jacs.6b01980

    Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO 2 -to-CO Electrochemical Conversion
    journal, December 2016

    • Azcarate, Iban; Costentin, Cyrille; Robert, Marc
    • Journal of the American Chemical Society, Vol. 138, Issue 51
    • DOI: 10.1021/jacs.6b07014

    Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid
    journal, March 2017

    • Roy, Souvik; Sharma, Bhaskar; Pécaut, Jacques
    • Journal of the American Chemical Society, Vol. 139, Issue 10
    • DOI: 10.1021/jacs.6b11474

    Cobalt Porphyrin Catalyzed Reduction of CO 2 . Radiation Chemical, Photochemical, and Electrochemical Studies
    journal, April 1998

    • Behar, D.; Dhanasekaran, T.; Neta, P.
    • The Journal of Physical Chemistry A, Vol. 102, Issue 17
    • DOI: 10.1021/jp9807017

    Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO-
    journal, January 1987

    • Ishida, Hitoshi.; Tanaka, Koji.; Tanaka, Toshio.
    • Organometallics, Vol. 6, Issue 1
    • DOI: 10.1021/om00144a033

    Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
    journal, January 2009

    • Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J.
    • Chem. Soc. Rev., Vol. 38, Issue 1
    • DOI: 10.1039/b804323j

    Nickel N-heterocyclic carbene–pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water
    journal, January 2011

    • Thoi, V. Sara; Chang, Christopher J.
    • Chemical Communications, Vol. 47, Issue 23
    • DOI: 10.1039/c1cc10449g

    Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
    journal, January 2012

    • Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya
    • Energy & Environmental Science, Vol. 5, Issue 11
    • DOI: 10.1039/c2ee22528j

    Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO) 3 Cl (bipy = 2,2′-bipyridine)
    journal, January 1984

    • Hawecker, Jeannot; Lehn, Jean-Marie; Ziessel, Raymond
    • J. Chem. Soc., Chem. Commun., Issue 6
    • DOI: 10.1039/c39840000328

    Photoinduced irreversible insertion of CO 2 into a metal–hydride bond
    journal, January 1984

    • Sullivan, B. Patrick; Meyer, Thomas J.
    • J. Chem. Soc., Chem. Commun., Issue 18
    • DOI: 10.1039/c39840001244

    Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water
    journal, January 1984

    • Beley, Marc; Collin, Jean-Paul; Ruppert, Romain
    • Journal of the Chemical Society, Chemical Communications, Issue 19
    • DOI: 10.1039/c39840001315

    Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst
    journal, January 2013

    • Kang, Peng; Meyer, Thomas J.; Brookhart, Maurice
    • Chemical Science, Vol. 4, Issue 9
    • DOI: 10.1039/c3sc51339d

    Nitrite reduction by copper through ligand-mediated proton and electron transfer
    journal, January 2015

    • Moore, Cameron M.; Szymczak, Nathaniel K.
    • Chemical Science, Vol. 6, Issue 6
    • DOI: 10.1039/c5sc00720h

    Exploring secondary-sphere interactions in Fe–N x H y complexes relevant to N 2 fixation
    journal, January 2017


    A look at periodic trends in d-block molecular electrocatalysts for CO 2 reduction
    journal, January 2019

    • Jiang, Changcheng; Nichols, Asa W.; Machan, Charles W.
    • Dalton Transactions, Vol. 48, Issue 26
    • DOI: 10.1039/c9dt00491b

    Evaluation of attractive interactions in the second coordination sphere of iron complexes containing pendant amines
    journal, January 2019

    • Liao, Qian; Liu, Tianbiao; Johnson, Samantha I.
    • Dalton Transactions, Vol. 48, Issue 15
    • DOI: 10.1039/c9dt00708c

    Rhenium bipyridine catalysts with hydrogen bonding pendant amines for CO 2 reduction
    journal, January 2019

    • Hellman, Ashley N.; Haiges, Ralf; Marinescu, Smaranda C.
    • Dalton Transactions, Vol. 48, Issue 38
    • DOI: 10.1039/c9dt02689d

    Structure of the  2 2 Ni-dependent CO dehydrogenase component of the Methanosarcina barkeri acetyl-CoA decarbonylase/synthase complex
    journal, July 2008

    • Gong, W.; Hao, B.; Wei, Z.
    • Proceedings of the National Academy of Sciences, Vol. 105, Issue 28
    • DOI: 10.1073/pnas.0800415105

    Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO
    journal, May 2012

    • Smieja, J. M.; Benson, E. E.; Kumar, B.
    • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
    • DOI: 10.1073/pnas.1119863109

    Ultraefficient homogeneous catalyst for the CO 2 -to-CO electrochemical conversion
    journal, October 2014

    • Costentin, Cyrille; Passard, Guillaume; Robert, Marc
    • Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
    • DOI: 10.1073/pnas.1416697111

    Life on carbon monoxide: X-ray structure of Rhodospirillum rubrum Ni-Fe-S carbon monoxide dehydrogenase
    journal, October 2001

    • Drennan, C. L.; Heo, J.; Sintchak, M. D.
    • Proceedings of the National Academy of Sciences, Vol. 98, Issue 21
    • DOI: 10.1073/pnas.211429998

    Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase
    journal, November 2007


    A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production
    journal, August 2011

    • Helm, M. L.; Stewart, M. P.; Bullock, R. M.
    • Science, Vol. 333, Issue 6044, p. 863-866
    • DOI: 10.1126/science.1205864

    A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
    journal, October 2012


    A bioinspired iron catalyst for nitrate and perchlorate reduction
    journal, November 2016


    Electrocatalytic Behavior of Metal Porphyrins in the Reduction of Carbon Dioxide
    journal, April 1979

    • Takahashi, Katsuhiro; Hiratsuka, Kazuya; Sasaki, Hideo
    • Chemistry Letters, Vol. 8, Issue 4
    • DOI: 10.1246/cl.1979.305

    Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO 2 Reduction of Iron Porphyrins
    journal, February 2019

    • Gotico, Philipp; Boitrel, Bernard; Guillot, Régis
    • Angewandte Chemie International Edition, Vol. 58, Issue 14
    • DOI: 10.1002/anie.201814339

    Rh I -Catalyzed P III -Directed C−H Bond Alkylation: Design of Multifunctional Phosphines for Carboxylation of Aryl Bromides with Carbon Dioxide
    journal, August 2019

    • Zhang, Zhuan; Roisnel, Thierry; Dixneuf, Pierre H.
    • Angewandte Chemie International Edition, Vol. 58, Issue 40
    • DOI: 10.1002/anie.201906913

    A look at periodic trends in d-block molecular electrocatalysts for CO 2 reduction
    journal, January 2019

    • Jiang, Changcheng; Nichols, Asa W.; Machan, Charles W.
    • Dalton Transactions, Vol. 48, Issue 26
    • DOI: 10.1039/c9dt00491b

    Evaluation of attractive interactions in the second coordination sphere of iron complexes containing pendant amines
    journal, January 2019

    • Liao, Qian; Liu, Tianbiao; Johnson, Samantha I.
    • Dalton Transactions, Vol. 48, Issue 15
    • DOI: 10.1039/c9dt00708c

    Rhenium bipyridine catalysts with hydrogen bonding pendant amines for CO 2 reduction
    journal, January 2019

    • Hellman, Ashley N.; Haiges, Ralf; Marinescu, Smaranda C.
    • Dalton Transactions, Vol. 48, Issue 38
    • DOI: 10.1039/c9dt02689d

    Second‐Sphere Biomimetic Multipoint Hydrogen‐Bonding Patterns to Boost CO 2 Reduction of Iron Porphyrins
    journal, February 2019

    • Gotico, Philipp; Boitrel, Bernard; Guillot, Régis
    • Angewandte Chemie, Vol. 131, Issue 14
    • DOI: 10.1002/ange.201814339

    Rh I ‐Catalyzed P III ‐Directed C−H Bond Alkylation: Design of Multifunctional Phosphines for Carboxylation of Aryl Bromides with Carbon Dioxide
    journal, August 2019

    • Zhang, Zhuan; Roisnel, Thierry; Dixneuf, Pierre H.
    • Angewandte Chemie, Vol. 131, Issue 40
    • DOI: 10.1002/ange.201906913

    Proton Relays in Molecular Catalysis of Electrochemical Reactions: Origin and Limitations of the Boosting Effect
    journal, February 2019

    • Savéant, Jean‐Michel
    • Angewandte Chemie International Edition, Vol. 58, Issue 7
    • DOI: 10.1002/anie.201812375

    Unexpected Effect of Intramolecular Phenolic Group on Electrocatalytic CO 2 Reduction
    journal, March 2020


    Underevaluated Solvent Effects in Electrocatalytic CO 2 Reduction by Fe III Chloride Tetrakis(pentafluorophenyl)porphyrin
    journal, September 2019


    Enhanced Electrochemical Reduction of CO 2 to CO upon Immobilization onto Carbon Nanotubes Using an Iron‐Porphyrin Dimer
    journal, January 2020


    Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO 2 to CO reduction in water
    journal, January 2018

    • Khadhraoui, Asma; Gotico, Philipp; Boitrel, Bernard
    • Chemical Communications, Vol. 54, Issue 82
    • DOI: 10.1039/c8cc06475j

    Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons
    journal, January 2018

    • Garza, Alejandro J.; Pakhira, Srimanta; Bell, Alexis T.
    • Physical Chemistry Chemical Physics, Vol. 20, Issue 37
    • DOI: 10.1039/c8cp01963k

    Role of 2 nd sphere H-bonding residues in tuning the kinetics of CO 2 reduction to CO by iron porphyrin complexes
    journal, January 2019

    • Sen, Pritha; Mondal, Biswajit; Saha, Dibyajyoti
    • Dalton Transactions, Vol. 48, Issue 18
    • DOI: 10.1039/c8dt03850c

    Artificial photosynthesis with metal and covalent organic frameworks (MOFs and COFs): challenges and prospects in fuel‐forming electrocatalysis
    journal, March 2019

    • Heidary, Nina; Harris, Tomos G. A. A.; Ly, Khoa H.
    • Physiologia Plantarum, Vol. 166, Issue 1
    • DOI: 10.1111/ppl.12935