Improved performance through tight coupling of redox cycles of sulfur and 2,6-polyanthraquinone in lithium–sulfur batteries
Abstract
Lithium–sulfur (Li–S) batteries offer high theoretical capacity and energy density; however, complex nanoengineered cathodes have been required to suppress the unwanted polysulfide shuttling. The textural complexity of such electrodes hinders detailed understanding of their function, impeding the development of new materials. In this report, the redox-active polymer 2,6-polyanthraquinone (PAQ) was incorporated into the cathode. The presence of this polymer improves capacity retention in galvanostatic cycling and inhibits Li corrosion and S deposition. In conclusion, we show that redox reactions of this polymer are strongly coupled to the S redox cycle and hypothesize that the observed improvements in the performance originate from the electrocatalytic inhibition of polysulfide shuttling in this system.
- Authors:
-
[1];
[1];
[3];
[1];
[1]
- Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR); Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1421979
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 46; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Lau, Ka-Cheong, Shkrob, Ilya A., Dietz Rago, Nancy L., Connell, Justin G., Phelan, Daniel, Hu, Bin, Zhang, Lu, Zhang, Zhengcheng, and Liao, Chen. Improved performance through tight coupling of redox cycles of sulfur and 2,6-polyanthraquinone in lithium–sulfur batteries. United States: N. p., 2017.
Web. doi:10.1039/C7TA08129D.
Lau, Ka-Cheong, Shkrob, Ilya A., Dietz Rago, Nancy L., Connell, Justin G., Phelan, Daniel, Hu, Bin, Zhang, Lu, Zhang, Zhengcheng, & Liao, Chen. Improved performance through tight coupling of redox cycles of sulfur and 2,6-polyanthraquinone in lithium–sulfur batteries. United States. https://doi.org/10.1039/C7TA08129D
Lau, Ka-Cheong, Shkrob, Ilya A., Dietz Rago, Nancy L., Connell, Justin G., Phelan, Daniel, Hu, Bin, Zhang, Lu, Zhang, Zhengcheng, and Liao, Chen. Tue .
"Improved performance through tight coupling of redox cycles of sulfur and 2,6-polyanthraquinone in lithium–sulfur batteries". United States. https://doi.org/10.1039/C7TA08129D. https://www.osti.gov/servlets/purl/1421979.
@article{osti_1421979,
title = {Improved performance through tight coupling of redox cycles of sulfur and 2,6-polyanthraquinone in lithium–sulfur batteries},
author = {Lau, Ka-Cheong and Shkrob, Ilya A. and Dietz Rago, Nancy L. and Connell, Justin G. and Phelan, Daniel and Hu, Bin and Zhang, Lu and Zhang, Zhengcheng and Liao, Chen},
abstractNote = {Lithium–sulfur (Li–S) batteries offer high theoretical capacity and energy density; however, complex nanoengineered cathodes have been required to suppress the unwanted polysulfide shuttling. The textural complexity of such electrodes hinders detailed understanding of their function, impeding the development of new materials. In this report, the redox-active polymer 2,6-polyanthraquinone (PAQ) was incorporated into the cathode. The presence of this polymer improves capacity retention in galvanostatic cycling and inhibits Li corrosion and S deposition. In conclusion, we show that redox reactions of this polymer are strongly coupled to the S redox cycle and hypothesize that the observed improvements in the performance originate from the electrocatalytic inhibition of polysulfide shuttling in this system.},
doi = {10.1039/C7TA08129D},
journal = {Journal of Materials Chemistry. A},
number = 46,
volume = 5,
place = {United States},
year = {2017},
month = {11}
}
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Works referenced in this record:
Highly Reversible Lithium/Dissolved Polysulfide Batteries with Carbon Nanotube Electrodes
journal, May 2013
- Fu, Yongzhu; Su, Yu-Sheng; Manthiram, Arumugam
- Angewandte Chemie International Edition, Vol. 52, Issue 27
Insights into Li-S Battery Cathode Capacity Fading Mechanisms: Irreversible Oxidation of Active Mass during Cycling
journal, January 2012
- Diao, Yan; Xie, Kai; Xiong, Shizhao
- Journal of The Electrochemical Society, Vol. 159, Issue 11
Electrocatalytic Polysulfide Traps for Controlling Redox Shuttle Process of Li–S Batteries
journal, September 2015
- Al Salem, Hesham; Babu, Ganguli; V. Rao, Chitturi
- Journal of the American Chemical Society, Vol. 137, Issue 36
Electrocatalysis of polysulfide conversion by sulfur-deficient MoS 2 nanoflakes for lithium–sulfur batteries
journal, January 2017
- Lin, Haibin; Yang, Liuqing; Jiang, Xi
- Energy & Environmental Science, Vol. 10, Issue 6
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors
journal, September 2012
- Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A.
- Angewandte Chemie International Edition, Vol. 51, Issue 40
Surface-enhanced redox chemistry of polysulphides on a metallic and polar host for lithium-sulphur batteries
journal, August 2014
- Pang, Quan; Kundu, Dipan; Cuisinier, Marine
- Nature Communications, Vol. 5, Issue 1
Introduction: Organocatalysis
journal, December 2007
- List, Benjamin
- Chemical Reviews, Vol. 107, Issue 12
Understanding the Effect of a Fluorinated Ether on the Performance of Lithium–Sulfur Batteries
journal, April 2015
- Azimi, Nasim; Xue, Zheng; Bloom, Ira
- ACS Applied Materials & Interfaces, Vol. 7, Issue 17
Directing the Lithium–Sulfur Reaction Pathway via Sparingly Solvating Electrolytes for High Energy Density Batteries
journal, May 2017
- Lee, Chang-Wook; Pang, Quan; Ha, Seungbum
- ACS Central Science, Vol. 3, Issue 6
Recent Advances in Electrolytes for Lithium-Sulfur Batteries
journal, April 2015
- Zhang, Shiguo; Ueno, Kazuhide; Dokko, Kaoru
- Advanced Energy Materials, Vol. 5, Issue 16
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition
journal, May 2015
- Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J.
- ACS Nano, Vol. 9, Issue 6
Transition Metal Dichalcogenide Atomic Layers for Lithium Polysulfides Electrocatalysis
journal, December 2016
- Babu, Ganguli; Masurkar, Nirul; Al Salem, Hesham
- Journal of the American Chemical Society, Vol. 139, Issue 1
A highly efficient polysulfide mediator for lithium–sulfur batteries
journal, January 2015
- Liang, Xiao; Hart, Connor; Pang, Quan
- Nature Communications, Vol. 6, Issue 1
Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries
journal, January 2014
- Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D.
- Energy Environ. Sci., Vol. 7, Issue 8
Carbonyls: Powerful Organic Materials for Secondary Batteries
journal, April 2015
- Häupler, Bernhard; Wild, Andreas; Schubert, Ulrich S.
- Advanced Energy Materials, Vol. 5, Issue 11
Lithium metal protected by atomic layer deposition metal oxide for high performance anodes
journal, January 2017
- Chen, Lin; Connell, Justin G.; Nie, Anmin
- Journal of Materials Chemistry A, Vol. 5, Issue 24
Heterogeneous Catalysis for Lithium–Sulfur Batteries: Enhanced Rate Performance by Promoting Polysulfide Fragmentations
journal, January 2017
- Jeong, Tae-Gyung; Choi, Dong Shin; Song, Hannah
- ACS Energy Letters, Vol. 2, Issue 2
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
journal, June 2013
- Zhang, Sheng S.
- Journal of Power Sources, Vol. 231, p. 153-162
Rechargeable Lithium–Sulfur Batteries
journal, July 2014
- Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng
- Chemical Reviews, Vol. 114, Issue 23
Polyanthraquinone-based nanostructured electrode material capable of high-performance pseudocapacitive energy storage in aprotic electrolyte
journal, July 2015
- Zhou, Yu; Wang, Bin; Liu, Changhai
- Nano Energy, Vol. 15
Polyanthraquinone-Based Organic Cathode for High-Performance Rechargeable Magnesium-Ion Batteries
journal, May 2016
- Pan, Baofei; Huang, Jinhua; Feng, Zhenxing
- Advanced Energy Materials, Vol. 6, Issue 14
Organic Electrode Materials for Rechargeable Lithium Batteries
journal, May 2012
- Liang, Yanliang; Tao, Zhanliang; Chen, Jun
- Advanced Energy Materials, Vol. 2, Issue 7
Solvate Ionic Liquid Electrolyte for Li–S Batteries
journal, January 2013
- Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento
- Journal of The Electrochemical Society, Vol. 160, Issue 8
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013
- Suo, Liumin; Hu, Yong-Sheng; Li, Hong
- Nature Communications, Vol. 4, Issue 1
Catalytic oxidation of Li 2 S on the surface of metal sulfides for Li−S batteries
journal, January 2017
- Zhou, Guangmin; Tian, Hongzhen; Jin, Yang
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 5
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes
journal, September 2016
- Pang, Quan; Liang, Xiao; Kwok, Chun Yuen
- Nature Energy, Vol. 1, Issue 9
Lithium metal anodes for rechargeable batteries
journal, January 2014
- Xu, Wu; Wang, Jiulin; Ding, Fei
- Energy Environ. Sci., Vol. 7, Issue 2
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009
- Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
- Nature Materials, Vol. 8, Issue 6, p. 500-506
Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014
- Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
- Nature Nanotechnology, Vol. 9, Issue 8
Supramolecular Perylene Bisimide-Polysulfide Gel Networks as Nanostructured Redox Mediators in Dissolved Polysulfide Lithium–Sulfur Batteries
journal, September 2015
- Frischmann, Peter D.; Gerber, Laura C. H.; Doris, Sean E.
- Chemistry of Materials, Vol. 27, Issue 19
Microwave-Assisted Oxidation of Side Chain Arenes by MagtrieveTM
journal, December 2003
- Lukasiewicz, Marcin; Bogdal, Dariusz; Pielichowski, Jan
- Advanced Synthesis & Catalysis, Vol. 345, Issue 12
The advent and development of organocatalysis
journal, September 2008
- MacMillan, David W. C.
- Nature, Vol. 455, Issue 7211
Works referencing / citing this record:
High performance polyanthraquinone/Co–Ni(OH) 2 aqueous batteries based on hydroxyl and potassium insertion/extraction reactions
journal, January 2020
- Liu, Chang; Ma, Ting; Xia, Kexin
- Sustainable Energy & Fuels, Vol. 4, Issue 1
Lipophilic Additives for Highly Concentrated Electrolytes in Lithium-Sulfur Batteries
journal, January 2019
- Lau, Ka-Cheong; Rago, Nancy L. Dietz; Liao, Chen
- Journal of The Electrochemical Society, Vol. 166, Issue 12