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Title: Fines migration during CO 2 injection: Experimental results interpreted using surface forces

The South West Hub project is one of the Australian Flagship Carbon Capture and Storage projects located in the south-west of Western Australia. To evaluate the injectivity potential during the forthcoming full-scale CO 2 injection, we conducted three core-flooding experiments using reservoir core plugs from the well Harvey-1. We aimed to investigate in this paper whether the injection of CO 2 leads to fines migration and permeability reduction due to the relatively high kaolinite content (up to 13%) in the injection interval of the target formation (i.e. the Wonnerup Member of the Lesueur Formation). We imaged the core samples before flooding to verify the presence of kaolinite at the pore-scale using scanning electron microscopy (SEM). We also examined the pore network of the core plugs before and after the core-flooding experiments using Nuclear Magnetic Resonance (NMR). Moreover, to gain a better understanding of any kaolinite fines migration, we delineated surface force using two models based on Derjaguin-Landau-Verwey-Overbeek (denoted by DLVO) theory coupled hydrodynamic force: (1) sphere/flat model representing interaction between kaolinite/quartz, and (2) flat/flat model representing interaction between kaolinite/kaolinite. Our core-flooding experimental results showed that CO 2/brine injection triggered moderate to significant reduction in the permeability of the core samplesmore » with a negligible porosity change. NMR measurements supported the core-flooding results, suggesting that the relatively large pores disappeared in favour of a higher proportion of the medium to small pores after flooding. The DLVO calculations showed that some kaolinite particles probably lifted off and detached from neighbouring kaolinite particles rather than quartz grains. Moreover, the modelling results showed that the kaolinite fines migration would not occur under normal reservoir multiphase flow conditions. This is not because of the low hydrodynamic force. It is rather because the geometries of the particles dominate their interplay. Finally and overall, both of the experimental and analytical modelling results point to the fines migration to be the most likely cause of the permeability impairment observed during core-flooding experiments.« less
Authors:
 [1] ;  [1] ;  [2] ;  [2] ;  [3]
  1. Curtin Univ., Kensington, WA (Australia). Dept. of Petroleum Engineering
  2. CSIRO Energy, Kensington, WA (Australia)
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Report Number(s):
SAND2017-13620J
Journal ID: ISSN 1750-5836; PII: S1750583617301883
Grant/Contract Number:
NA0003525
Type:
Accepted Manuscript
Journal Name:
International Journal of Greenhouse Gas Control
Additional Journal Information:
Journal Volume: 65; Journal ID: ISSN 1750-5836
Publisher:
Elsevier
Research Org:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Curtin Univ., Kensington, WA (Australia)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA); Australian National Low Emissions Coal Research and Development (ANLEC R&D)
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; CO2 geo-sequestration; core-flooding; fines migration; geo-chemical interactions; surface forces
OSTI Identifier:
1421635

Xie, Quan, Saeedi, Ali, Delle Piane, Claudio, Esteban, Lionel, and Brady, Patrick V. Fines migration during CO2 injection: Experimental results interpreted using surface forces. United States: N. p., Web. doi:10.1016/j.ijggc.2017.08.011.
Xie, Quan, Saeedi, Ali, Delle Piane, Claudio, Esteban, Lionel, & Brady, Patrick V. Fines migration during CO2 injection: Experimental results interpreted using surface forces. United States. doi:10.1016/j.ijggc.2017.08.011.
Xie, Quan, Saeedi, Ali, Delle Piane, Claudio, Esteban, Lionel, and Brady, Patrick V. 2017. "Fines migration during CO2 injection: Experimental results interpreted using surface forces". United States. doi:10.1016/j.ijggc.2017.08.011. https://www.osti.gov/servlets/purl/1421635.
@article{osti_1421635,
title = {Fines migration during CO2 injection: Experimental results interpreted using surface forces},
author = {Xie, Quan and Saeedi, Ali and Delle Piane, Claudio and Esteban, Lionel and Brady, Patrick V.},
abstractNote = {The South West Hub project is one of the Australian Flagship Carbon Capture and Storage projects located in the south-west of Western Australia. To evaluate the injectivity potential during the forthcoming full-scale CO2 injection, we conducted three core-flooding experiments using reservoir core plugs from the well Harvey-1. We aimed to investigate in this paper whether the injection of CO2 leads to fines migration and permeability reduction due to the relatively high kaolinite content (up to 13%) in the injection interval of the target formation (i.e. the Wonnerup Member of the Lesueur Formation). We imaged the core samples before flooding to verify the presence of kaolinite at the pore-scale using scanning electron microscopy (SEM). We also examined the pore network of the core plugs before and after the core-flooding experiments using Nuclear Magnetic Resonance (NMR). Moreover, to gain a better understanding of any kaolinite fines migration, we delineated surface force using two models based on Derjaguin-Landau-Verwey-Overbeek (denoted by DLVO) theory coupled hydrodynamic force: (1) sphere/flat model representing interaction between kaolinite/quartz, and (2) flat/flat model representing interaction between kaolinite/kaolinite. Our core-flooding experimental results showed that CO2/brine injection triggered moderate to significant reduction in the permeability of the core samples with a negligible porosity change. NMR measurements supported the core-flooding results, suggesting that the relatively large pores disappeared in favour of a higher proportion of the medium to small pores after flooding. The DLVO calculations showed that some kaolinite particles probably lifted off and detached from neighbouring kaolinite particles rather than quartz grains. Moreover, the modelling results showed that the kaolinite fines migration would not occur under normal reservoir multiphase flow conditions. This is not because of the low hydrodynamic force. It is rather because the geometries of the particles dominate their interplay. Finally and overall, both of the experimental and analytical modelling results point to the fines migration to be the most likely cause of the permeability impairment observed during core-flooding experiments.},
doi = {10.1016/j.ijggc.2017.08.011},
journal = {International Journal of Greenhouse Gas Control},
number = ,
volume = 65,
place = {United States},
year = {2017},
month = {9}
}