Thermally activated delayed fluorescence of a Zr-based metal–organic framework
- Kyushu Univ. (Japan). Center for Organic Photonics and Electronics Research (OPERA)
- Kyushu Univ. (Japan). Center for Organic Photonics and Electronics Research (OPERA); Kyushu Univ. (Japan). Japan Science and Technology Agency (JST), ERATO, Adachi Molecular Exciton Engineering Project
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Kyushu Univ. (Japan). Center for Organic Photonics and Electronics Research (OPERA); Kyushu Univ. (Japan). Japan Science and Technology Agency (JST), ERATO, Adachi Molecular Exciton Engineering Project; Kyushu Univ. (Japan). International Inst. for Carbon Neutral Energy Research (WPI-I2CNER)
Here, the first metal–organic framework exhibiting thermally activated delayed fluorescence (TADF) was developed. The zirconium-based framework (UiO-68-dpa) uses a newly designed linker composed of a terphenyl backbone, an electron-accepting carboxyl group, and an electron-donating diphenylamine and exhibits green TADF emission with a photoluminescence quantum yield of 30% and high thermal stability.
- Research Organization:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA)
- Grant/Contract Number:
- AC04-94AL85000
- OSTI ID:
- 1421615
- Report Number(s):
- SAND-2017-12341J; CHCOFS; 658757
- Journal Information:
- ChemComm, Vol. 54, Issue 6; ISSN 1359-7345
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 24 works
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