Physical properties of V 1− x Ti x O 2 (0 < x < 0.187) single crystals
Abstract
Free standing, low strain, single crystals of pure and titanium doped VO₂ were grown out of an excess of V ₂O₅ using high temperature solution growth techniques. At TMI ~ 340 K, pure VO₂ exhibits a clear first-order phase transition from a high-temperature paramagnetic tetragonal phase (R) to a low-temperature non-magnetic monoclinic phase (M1). With Ti doping, another monoclinic phase (M2) emerges between the R and M1 phases. The phase transition temperature between R and M2 increases with increasing Ti doping while the transition temperature between M2 and M1 decreases.
- Authors:
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1170237
- Alternate Identifier(s):
- OSTI ID: 1201665; OSTI ID: 1421205
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Published Article
- Journal Name:
- APL Materials
- Additional Journal Information:
- Journal Name: APL Materials Journal Volume: 3 Journal Issue: 4; Journal ID: ISSN 2166-532X
- Publisher:
- American Institute of Physics
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Kong, Tai, Masters, Morgan W., Bud’ko, Sergey L., and Canfield, Paul C. Physical properties of V 1− x Ti x O 2 (0 < x < 0.187) single crystals. United States: N. p., 2015.
Web. doi:10.1063/1.4908245.
Kong, Tai, Masters, Morgan W., Bud’ko, Sergey L., & Canfield, Paul C. Physical properties of V 1− x Ti x O 2 (0 < x < 0.187) single crystals. United States. https://doi.org/10.1063/1.4908245
Kong, Tai, Masters, Morgan W., Bud’ko, Sergey L., and Canfield, Paul C. Wed .
"Physical properties of V 1− x Ti x O 2 (0 < x < 0.187) single crystals". United States. https://doi.org/10.1063/1.4908245.
@article{osti_1170237,
title = {Physical properties of V 1− x Ti x O 2 (0 < x < 0.187) single crystals},
author = {Kong, Tai and Masters, Morgan W. and Bud’ko, Sergey L. and Canfield, Paul C.},
abstractNote = {Free standing, low strain, single crystals of pure and titanium doped VO₂ were grown out of an excess of V ₂O₅ using high temperature solution growth techniques. At TMI ~ 340 K, pure VO₂ exhibits a clear first-order phase transition from a high-temperature paramagnetic tetragonal phase (R) to a low-temperature non-magnetic monoclinic phase (M1). With Ti doping, another monoclinic phase (M2) emerges between the R and M1 phases. The phase transition temperature between R and M2 increases with increasing Ti doping while the transition temperature between M2 and M1 decreases.},
doi = {10.1063/1.4908245},
journal = {APL Materials},
number = 4,
volume = 3,
place = {United States},
year = {Wed Apr 01 00:00:00 EDT 2015},
month = {Wed Apr 01 00:00:00 EDT 2015}
}
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