skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene

Authors:
 [1]; ORCiD logo [2];  [3]; ORCiD logo [4];  [2];  [5]
  1. Graduate Group in Applied Science and Technology, University of California, Berkeley, California 94720, USA, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA
  3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA, Department of Chemistry, University of California at Davis, Davis, California 95616, USA
  4. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA, Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan
  5. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA, PULSE Institute for Ultrafast Energy Science, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1421057
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 144 Journal Issue: 1; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Champenois, Elio G., Shivaram, Niranjan H., Wright, Travis W., Yang, Chan-Shan, Belkacem, Ali, and Cryan, James P. Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene. United States: N. p., 2016. Web. doi:10.1063/1.4939220.
Champenois, Elio G., Shivaram, Niranjan H., Wright, Travis W., Yang, Chan-Shan, Belkacem, Ali, & Cryan, James P. Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene. United States. doi:https://doi.org/10.1063/1.4939220
Champenois, Elio G., Shivaram, Niranjan H., Wright, Travis W., Yang, Chan-Shan, Belkacem, Ali, and Cryan, James P. Thu . "Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene". United States. doi:https://doi.org/10.1063/1.4939220.
@article{osti_1421057,
title = {Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene},
author = {Champenois, Elio G. and Shivaram, Niranjan H. and Wright, Travis W. and Yang, Chan-Shan and Belkacem, Ali and Cryan, James P.},
abstractNote = {},
doi = {10.1063/1.4939220},
journal = {Journal of Chemical Physics},
number = 1,
volume = 144,
place = {United States},
year = {2016},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1063/1.4939220

Citation Metrics:
Cited by: 13 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Ultrafast internal conversion in ethylene. I. The excited state lifetime
journal, June 2011

  • Tao, H.; Allison, T. K.; Wright, T. W.
  • The Journal of Chemical Physics, Vol. 134, Issue 24
  • DOI: 10.1063/1.3604007

High-Resolution Excited-State Photoelectron Spectroscopy of the Lower Rydberg States of Jet-Cooled C 2 H 4 and C 2 D 4
journal, April 2002

  • Rijkenberg, R. A.; Buma, W. J.
  • The Journal of Physical Chemistry A, Vol. 106, Issue 15
  • DOI: 10.1021/jp013714k

Ethylene. Experimental Evidence for New Assignments of Electronic Transitions in the π → π* Energy Region. Absorption and Magnetic Circular Dichroism Measurements with Synchrotron Radiation
journal, May 2004

  • Snyder, Patricia Ann; Atanasova, Sylvia; Hansen, Roger W. C.
  • The Journal of Physical Chemistry A, Vol. 108, Issue 19
  • DOI: 10.1021/jp030837r

A photoionization mass spectrometric study of acetylene and ethylene in the VUV spectral region
journal, January 2003


Theoretical study of the ethylene electronic spectrum and extraction of an r-dependent Hubbard Hamiltonian
journal, October 1996


Role of Rydberg States in the Photochemical Dynamics of Ethylene
journal, December 2011

  • Mori, Toshifumi; Glover, William J.; Schuurman, Michael S.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 11
  • DOI: 10.1021/jp2097185

Excited-state dynamics of furan studied by sub-20-fs time-resolved photoelectron imaging using 159-nm pulses
journal, July 2015

  • Spesyvtsev, R.; Horio, T.; Suzuki, Y. -I.
  • The Journal of Chemical Physics, Vol. 143, Issue 1
  • DOI: 10.1063/1.4922904

A new interpretation of the electronic spectrum of ethylene from 6–8 eV
journal, November 1995


Femtosecond spectroscopy with vacuum ultraviolet pulse pairs
journal, January 2010

  • Allison, T. K.; Wright, T. W.; Stooke, A. M.
  • Optics Letters, Vol. 35, Issue 21
  • DOI: 10.1364/OL.35.003664

Ultrafast non-adiabatic dynamics of methyl substituted ethylenes: The π 3s Rydberg state
journal, October 2011

  • Wu, Guorong; Boguslavskiy, Andrey E.; Schalk, Oliver
  • The Journal of Chemical Physics, Vol. 135, Issue 16
  • DOI: 10.1063/1.3652966

Femtosecond Time-Resolved Photoelectron Spectroscopy
journal, April 2004

  • Stolow, Albert; Bragg, Arthur E.; Neumark, Daniel M.
  • Chemical Reviews, Vol. 104, Issue 4
  • DOI: 10.1021/cr020683w

Optimizing High Harmonic Generation in Absorbing Gases: Model and Experiment
journal, February 1999


Photoelectron angular distributions for states of any mixed character: An experiment-friendly model for atomic, molecular, and cluster anions
journal, September 2014

  • Khuseynov, Dmitry; Blackstone, Christopher C.; Culberson, Lori M.
  • The Journal of Chemical Physics, Vol. 141, Issue 12
  • DOI: 10.1063/1.4896241

Ultraviolet spectra and excited states of ethylene and its alkyl derivatives
journal, October 1969

  • Merer, A. J.; Mulliken, Robert S.
  • Chemical Reviews, Vol. 69, Issue 5
  • DOI: 10.1021/cr60261a003

From the (1B) Spectroscopic State to the Photochemical Product of the Ultrafast Ring-Opening of 1,3-Cyclohexadiene: A Spectral Observation of the Complete Reaction Path
journal, August 2015

  • Pemberton, Christine C.; Zhang, Yao; Saita, Kenichiro
  • The Journal of Physical Chemistry A, Vol. 119, Issue 33
  • DOI: 10.1021/acs.jpca.5b05672

Unimolecular decay paths of electronically excited species. II. The C 2 H + 4 ion
journal, February 1981

  • Sannen, C.; Raşeev, G.; Galloy, C.
  • The Journal of Chemical Physics, Vol. 74, Issue 4
  • DOI: 10.1063/1.441361

Neutral excited radicals formed by ethylene photodissociation in the 8–24 eV region
journal, January 2004

  • Alnama, Koutayba; Boyé, Séverine; Douin, Stéphane
  • Phys. Chem. Chem. Phys., Vol. 6, Issue 9
  • DOI: 10.1039/b316056d

T IME -R ESOLVED P HOTOELECTRON S PECTROSCOPY OF M OLECULES AND C LUSTERS
journal, October 2001


Ab initio molecular dynamics with equation-of-motion coupled-cluster theory: electronic absorption spectrum of ethylene
journal, July 2003


Isomerization Through Conical Intersections
journal, May 2007


Probing Ultrafast Internal Conversion through Conical Intersection via Time-Energy Map of Photoelectron Angular Anisotropy
journal, August 2009

  • Horio, Takuya; Fuji, Takao; Suzuki, Yoshi-Ichi
  • Journal of the American Chemical Society, Vol. 131, Issue 30
  • DOI: 10.1021/ja904780b

Ultrafast internal conversion in ethylene. II. Mechanisms and pathways for quenching and hydrogen elimination
journal, March 2012

  • Allison, T. K.; Tao, H.; Glover, W. J.
  • The Journal of Chemical Physics, Vol. 136, Issue 12
  • DOI: 10.1063/1.3697760

Vibrationally Mediated Photodissociation of C 2 H 4 +
journal, August 2007

  • Kim, Myung Hwa; Leskiw, Brian D.; Shen, Lei
  • The Journal of Physical Chemistry A, Vol. 111, Issue 31
  • DOI: 10.1021/jp071348k

Two-dimensional charged particle image inversion using a polar basis function expansion
journal, November 2004

  • Garcia, Gustavo A.; Nahon, Laurent; Powis, Ivan
  • Review of Scientific Instruments, Vol. 75, Issue 11
  • DOI: 10.1063/1.1807578

Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen
journal, September 1997

  • Eppink, André T. J. B.; Parker, David H.
  • Review of Scientific Instruments, Vol. 68, Issue 9
  • DOI: 10.1063/1.1148310

Femtosecond time-resolved dynamics of the electronically excited ethylene molecule
journal, April 2004


Ultrafast non-adiabatic dynamics of ethylene including Rydberg states
journal, September 2013


Efficient generation of below-threshold harmonics for high-fidelity multi-photon physics in the VUV spectral range
journal, January 2015

  • Rompotis, Dimitrios; Gebert, Thomas; Wieland, Marek
  • Optics Letters, Vol. 40, Issue 8
  • DOI: 10.1364/OL.40.001675

Ultrafast Deactivation of the ππ*( V ) State of Ethylene Studied Using Sub-20 fs Time-Resolved Photoelectron Imaging
journal, August 2015

  • Kobayashi, Takufumi; Horio, Takuya; Suzuki, Toshinori
  • The Journal of Physical Chemistry A, Vol. 119, Issue 36
  • DOI: 10.1021/acs.jpca.5b06094

Ultrafast Dynamics and Coherent Oscillations in Ethylene and Ethylene- d 4 Excited at 162 nm
journal, August 2008

  • Kosma, K.; Trushin, S. A.; Fuss, W.
  • The Journal of Physical Chemistry A, Vol. 112, Issue 33
  • DOI: 10.1021/jp803548c

Far Ultraviolet Absorption Spectra of Ethylene and Ethylene‐ d 4
journal, October 1955

  • Wilkinson, P. G.; Mulliken, R. S.
  • The Journal of Chemical Physics, Vol. 23, Issue 10
  • DOI: 10.1063/1.1740601

A photoabsorption, photodissociation and photoelectron spectroscopy study of C2H4 and C2D4
journal, June 1997


Internal Conversion versus Intersystem Crossing: What Drives the Gas Phase Dynamics of Cyclic α,β-Enones?
journal, March 2014

  • Schalk, Oliver; Schuurman, Michael S.; Wu, Guorong
  • The Journal of Physical Chemistry A, Vol. 118, Issue 12
  • DOI: 10.1021/jp4124937

Two-Photon Excited State Dynamics of Dark Valence, Rydberg, and Superexcited States in 1,3-Butadiene
journal, January 2014

  • Schalk, Oliver; Boguslavskiy, Andrey E.; Stolow, Albert
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 3
  • DOI: 10.1021/jz402725u