Title: An Aqueous Inorganic Polymer Binder for High Performance Lithium–Sulfur Batteries with Flame-Retardant Properties

Abstract

Lithium–sulfur (Li–S) batteries are regarded as promising next-generation high energy density storage devices for both portable electronics and electric vehicles due to their high energy density, low cost, and environmental friendliness. However, there remain some issues yet to be fully addressed with the main challenges stemming from the ionically insulating nature of sulfur and the dissolution of polysulfides in electrolyte with subsequent parasitic reactions leading to low sulfur utilization and poor cycle life. The high flammability of sulfur is another serious safety concern which has hindered its further application. Herein, an aqueous inorganic polymer, ammonium polyphosphate (APP), has been developed as a novel multifunctional binder to address the above issues. The strong binding affinity of the main chain of APP with lithium polysulfides blocks diffusion of polysulfide anions and inhibits their shuttling effect. The coupling of APP with Li ion facilitates ion transfer and promotes the kinetics of the cathode reaction. Moreover, APP can serve as a flame retardant, thus significantly reducing the flammability of the sulfur cathode. In addition, the aqueous characteristic of the binder avoids the use of toxic organic solvents, thus significantly improving safety. As a result, a high rate capacity of 520 mAh g^–1 at 4more » C and excellent cycling stability of ~0.038% capacity decay per cycle at 0.5 C for 400 cycles are achieved based on this binder. In conclusion, this work offers a feasible and effective strategy for employing APP as an efficient multifunctional binder toward building next-generation high energy density Li–S batteries.« less

Authors:

Zhou, Guangmin  ^[1];

• Search DOE PAGES for author "Zhou, Guangmin"
• Search DOE PAGES for ORCID "0000-0002-3629-5686"

Liu, Kai  ^[1];

• Search DOE PAGES for author "Liu, Kai"
• Search DOE PAGES for ORCID "0000-0003-3362-180X"

Fan, Yanchen ^[2]; Yuan, Mengqi ^[3]; Liu, Bofei ^[1]; Liu, Wei  ^[1];

• Search DOE PAGES for author "Liu, Wei"
• Search DOE PAGES for ORCID "0000-0002-6206-8321"

Shi, Feifei  ^[1];

• Search DOE PAGES for author "Shi, Feifei"
• Search DOE PAGES for ORCID "0000-0002-9171-6180"

Liu, Yayuan ^[1]; Chen, Wei  ^[1];

• Search DOE PAGES for author "Chen, Wei"
• Search DOE PAGES for ORCID "0000-0001-7701-1363"

Lopez, Jeffrey  ^[4];

• Search DOE PAGES for author "Lopez, Jeffrey"
• Search DOE PAGES for ORCID "0000-0002-6425-5550"

Zhuo, Denys ^[1]; Zhao, Jie  ^[1];

• Search DOE PAGES for author "Zhao, Jie"
• Search DOE PAGES for ORCID "0000-0001-6446-8313"

Tsao, Yuchi ^[1]; Huang, Xuanyi ^[1]; Zhang, Qianfan ^[2]; Cui, Yi  ^[5]

• Search DOE PAGES for author "Cui, Yi"
• Search DOE PAGES for ORCID "0000-0002-6103-6352"

---

+ Show Author Affiliations

1. Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, United States
2. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing, 100191, P. R. China
3. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, P. R. China
4. Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States
5. Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, United States, Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States

Publication Date:

Wed Feb 14 00:00:00 EST 2018

Research Org.:

SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Org.:

USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI Identifier:

1420454

Alternate Identifier(s):

OSTI ID: 1437553

Grant/Contract Number:  

AC02-76SF00515; NCET-12-0033; 11404017

Resource Type:

Published Article

Journal Name:

ACS Central Science

Additional Journal Information:

Journal Name: ACS Central Science Journal Volume: 4 Journal Issue: 2; Journal ID: ISSN 2374-7943

Publisher:

American Chemical Society

Country of Publication:

United States

Language:

English

Subject:

25 ENERGY STORAGE