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Title: Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity

Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Department of Chemistry, University of California, Irvine, USA
Publication Date:
Grant/Contract Number:
SC0012150
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 10; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1420343

Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., and Yang, Jenny Y.. Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity. United Kingdom: N. p., Web. doi:10.1039/C7SC04960A.
Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., & Yang, Jenny Y.. Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity. United Kingdom. doi:10.1039/C7SC04960A.
Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., and Yang, Jenny Y.. 2018. "Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity". United Kingdom. doi:10.1039/C7SC04960A.
@article{osti_1420343,
title = {Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity},
author = {Khosrowabadi Kotyk, Juliet F. and Hanna, Caitlin M. and Combs, Rebecca L. and Ziller, Joseph W. and Yang, Jenny Y.},
abstractNote = {Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction.},
doi = {10.1039/C7SC04960A},
journal = {Chemical Science},
number = 10,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co4(H2O)2(PW9O34)2]10–: Identification of Heterogeneous CoOx as the Dominant Catalyst
journal, September 2011
  • Stracke, Jordan J.; Finke, Richard G.
  • Journal of the American Chemical Society, Vol. 133, Issue 38, p. 14872-14875
  • DOI: 10.1021/ja205569j

Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
journal, April 2010
  • Chen, Z.; Concepcion, J. J.; Hu, X.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 16, p. 7225-7229
  • DOI: 10.1073/pnas.1001132107

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
journal, July 2008
  • Savéant, Jean-Michel
  • Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378
  • DOI: 10.1021/cr068079z