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Title: Effect of composition on the structure of lithium- and manganese-rich transition metal oxides

In this work, we establish a definitive structural model for lithium- and manganese-rich transition metal oxides and demonstrate the effect of composition on their bulk as well as the surface structure.
Authors:
ORCiD logo [1] ;  [2] ;  [3] ;  [2] ;  [2] ;  [4] ;  [5] ;  [5] ;  [5]
  1. Energy Storage and Distributed Resources Division; Lawrence Berkeley National Laboratory; Berkeley; USA; SuperSTEM
  2. SuperSTEM; Daresbury; UK
  3. National Center for Electron Microscopy; Molecular Foundry; Lawrence Berkeley National Laboratory; Berkeley; USA
  4. Erich Schmid Institute of Materials Science; Austrian Academy of Sciences; Leoben; Austria
  5. Envia Systems; Newark; USA
Publication Date:
Grant/Contract Number:
EE0006443; AC02-05CH11231
Type:
Published Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 4; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); Engineering and Physical Science Research Council (EFRC)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1420189

Shukla, Alpesh Khushalchand, Ramasse, Quentin M., Ophus, Colin, Kepaptsoglou, Despoina Maria, Hage, Fredrik S., Gammer, Christoph, Bowling, Charles, Gallegos, Pedro Alejandro Hernández, and Venkatachalam, Subramanian. Effect of composition on the structure of lithium- and manganese-rich transition metal oxides. United Kingdom: N. p., Web. doi:10.1039/C7EE02443F.
Shukla, Alpesh Khushalchand, Ramasse, Quentin M., Ophus, Colin, Kepaptsoglou, Despoina Maria, Hage, Fredrik S., Gammer, Christoph, Bowling, Charles, Gallegos, Pedro Alejandro Hernández, & Venkatachalam, Subramanian. Effect of composition on the structure of lithium- and manganese-rich transition metal oxides. United Kingdom. doi:10.1039/C7EE02443F.
Shukla, Alpesh Khushalchand, Ramasse, Quentin M., Ophus, Colin, Kepaptsoglou, Despoina Maria, Hage, Fredrik S., Gammer, Christoph, Bowling, Charles, Gallegos, Pedro Alejandro Hernández, and Venkatachalam, Subramanian. 2018. "Effect of composition on the structure of lithium- and manganese-rich transition metal oxides". United Kingdom. doi:10.1039/C7EE02443F.
@article{osti_1420189,
title = {Effect of composition on the structure of lithium- and manganese-rich transition metal oxides},
author = {Shukla, Alpesh Khushalchand and Ramasse, Quentin M. and Ophus, Colin and Kepaptsoglou, Despoina Maria and Hage, Fredrik S. and Gammer, Christoph and Bowling, Charles and Gallegos, Pedro Alejandro Hernández and Venkatachalam, Subramanian},
abstractNote = {In this work, we establish a definitive structural model for lithium- and manganese-rich transition metal oxides and demonstrate the effect of composition on their bulk as well as the surface structure.},
doi = {10.1039/C7EE02443F},
journal = {Energy & Environmental Science},
number = 4,
volume = 11,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006
  • Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
  • Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538
  • DOI: 10.1016/j.elecom.2006.06.030

Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009