A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications

Liu, Jian; Zheng, Jian; Barpaga, Dushyant; Sabale, Sandip; Arey, Bruce; Derewinski, Miroslaw A.; McGrail, B. Peter; Motkuri, Radha Kishan

doi:10.1002/ejic.201800042

Title: A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications

Abstract

The mixed‐metal strategy, by which a MOF framework with two different metal nodes was prepared, was utilized with MOF‐74 for potential adsorption chiller applications. The Ni salt precursor was partially replaced during synthesis with the relatively inexpensive Zn salt. The bimetallic MOF‐74 containing only a fraction of Ni was shown to provide efficient H ₂ O adsorption performance, while utilizing the more inexpensive Zn salt thus significantly mitigated the material costs of industrial scale synthesis/applications.

Authors:

^[1];

^[1]; Sabale, Sandip ^[2]; Arey, Bruce ^[3];

^[1]; McGrail, B. Peter ^[1];

^[1]

Pacific Northwest National Laboratory 99352 Richland WA USA
Pacific Northwest National Laboratory 99352 Richland WA USA, P.G. Department of Chemistry Jaysingpur College 416101 Jaysingpur Maharashtra India
Environmental Molecular Sciences Laboratory (EMSL) Pacific Northwest National Laboratory 99352 Richland WA USA

Publication Date:: Mon Feb 12 00:00:00 EST 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1420181

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: European Journal of Inorganic Chemistry

Additional Journal Information:: Journal Name: European Journal of Inorganic Chemistry Journal Volume: 2018 Journal Issue: 7; Journal ID: ISSN 1434-1948

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Liu, Jian, Zheng, Jian, Barpaga, Dushyant, Sabale, Sandip, Arey, Bruce, Derewinski, Miroslaw A., McGrail, B. Peter, and Motkuri, Radha Kishan. A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications.  Germany: N. p., 2018. 
Web.  doi:10.1002/ejic.201800042.

Copy to clipboard


                    Liu, Jian, Zheng, Jian, Barpaga, Dushyant, Sabale, Sandip, Arey, Bruce, Derewinski, Miroslaw A., McGrail, B. Peter, & Motkuri, Radha Kishan. A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications.  Germany.  https://doi.org/10.1002/ejic.201800042

Copy to clipboard


                    Liu, Jian, Zheng, Jian, Barpaga, Dushyant, Sabale, Sandip, Arey, Bruce, Derewinski, Miroslaw A., McGrail, B. Peter, and Motkuri, Radha Kishan. Mon .  
"A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications".  Germany.  https://doi.org/10.1002/ejic.201800042.

Copy to clipboard


                    
@article{osti_1420181,

  title        = {A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications},

  author       = {Liu, Jian and Zheng, Jian and Barpaga, Dushyant and Sabale, Sandip and Arey, Bruce and Derewinski, Miroslaw A. and McGrail, B. Peter and Motkuri, Radha Kishan},

  abstractNote = {The mixed‐metal strategy, by which a MOF framework with two different metal nodes was prepared, was utilized with MOF‐74 for potential adsorption chiller applications. The Ni salt precursor was partially replaced during synthesis with the relatively inexpensive Zn salt. The bimetallic MOF‐74 containing only a fraction of Ni was shown to provide efficient H 2 O adsorption performance, while utilizing the more inexpensive Zn salt thus significantly mitigated the material costs of industrial scale synthesis/applications.},

  doi          = {10.1002/ejic.201800042},

  journal      = {European Journal of Inorganic Chemistry},

  number       = 7,

  volume       = 2018,

  place        = {Germany},

  year         = {Mon Feb 12 00:00:00 EST 2018},

  month        = {Mon Feb 12 00:00:00 EST 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1002/ejic.201800042

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 31 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Understanding the H ₂ Sorption Trends in the M-MOF-74 Series (M = Mg, Ni, Co, Zn)
journal, December 2014

Pham, Tony; Forrest, Katherine A.; Banerjee, Rahul
The Journal of Physical Chemistry C, Vol. 119, Issue 2
DOI: 10.1021/jp510253m

The effect of pyridine modification of Ni–DOBDC on CO ₂ capture under humid conditions
journal, January 2014

Bae, Youn-Sang; Liu, Jian; Wilmer, Christopher E.
Chem. Commun., Vol. 50, Issue 25
DOI: 10.1039/c3cc44954h

Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
journal, February 2001

Chen, Banglin; Eddaoudi, M.; Hyde, S. T.
Science, Vol. 291, Issue 5506, p. 1021-1023
DOI: 10.1126/science.1056598

“Heterogeneity within Order” in Metal-Organic Frameworks
journal, January 2015

Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M.
Angewandte Chemie International Edition, Vol. 54, Issue 11
DOI: 10.1002/anie.201410252

Scalability of Continuous Flow Production of Metal-Organic Frameworks
journal, April 2016

Rubio-Martinez, Marta; Hadley, Trevor D.; Batten, Michael P.
ChemSusChem, Vol. 9, Issue 9
DOI: 10.1002/cssc.201501684

CO ₂ Dynamics in a Metal–Organic Framework with Open Metal Sites
journal, August 2012

Kong, Xueqian; Scott, Eric; Ding, Wen
Journal of the American Chemical Society, Vol. 134, Issue 35
DOI: 10.1021/ja306822p

Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications
journal, July 2017

Zheng, Jian; Vemuri, Rama S.; Estevez, Luis
Journal of the American Chemical Society, Vol. 139, Issue 31
DOI: 10.1021/jacs.7b04872

Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni
journal, December 2015

Jiao, Yang; Morelock, Cody R.; Burtch, Nicholas C.
Industrial & Engineering Chemistry Research, Vol. 54, Issue 49
DOI: 10.1021/acs.iecr.5b03843

CO ₂ /H ₂ O Adsorption Equilibrium and Rates on Metal−Organic Frameworks: HKUST-1 and Ni/DOBDC
journal, September 2010

Liu, Jian; Wang, Yu; Benin, Annabelle I.
Langmuir, Vol. 26, Issue 17
DOI: 10.1021/la102359q

Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach
journal, December 2009

Yazaydın, A. Özgür; Snurr, Randall Q.; Park, Tae-Hong
Journal of the American Chemical Society, Vol. 131, Issue 51
DOI: 10.1021/ja9057234

Harnessing Lewis acidic open metal sites of metal–organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane
journal, January 2016

Mukherjee, Soumya; Manna, Biplab; Desai, Aamod V.
Chemical Communications, Vol. 52, Issue 53
DOI: 10.1039/C6CC03015G

H ₂ O Adsorption/Desorption in MOF-74: Ab Initio Molecular Dynamics and Experiments
journal, May 2015

Li, Yunsong; Wang, Xinjiang; Xu, Dongyan
The Journal of Physical Chemistry C, Vol. 119, Issue 23
DOI: 10.1021/acs.jpcc.5b02069

An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance
journal, June 2016

Das, Atanu Kumar; Vemuri, Rama Sesha; Kutnyakov, Igor
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep28050

Metal-Organic Frameworks - Heading towards Application: Metal-Organic Frameworks - Heading towards Application
journal, September 2016

Dietzel, Pascal D. C.; Kitagawa, Hiroshi
European Journal of Inorganic Chemistry, Vol. 2016, Issue 27
DOI: 10.1002/ejic.201601041

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

Rowsell, Jesse L. C.; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 128, Issue 4, p. 1304-1315
DOI: 10.1021/ja056639q

An In-Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal-Organic Frameworks CPO-27-M
journal, March 2017

Pato-Doldán, Breogán; Rosnes, Mali H.; Dietzel, Pascal D. C.
ChemSusChem, Vol. 10, Issue 8
DOI: 10.1002/cssc.201601752

Separation of polar compounds using a flexible metal–organic framework
journal, January 2015

Motkuri, Radha Kishan; Thallapally, Praveen K.; Annapureddy, Harsha V. R.
Chemical Communications, Vol. 51, Issue 40
DOI: 10.1039/C5CC00113G

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009

Britt, D.; Furukawa, H.; Wang, B.
Proceedings of the National Academy of Sciences, Vol. 106, Issue 49, p. 20637-20640
DOI: 10.1073/pnas.0909718106

Water Reaction Mechanism in Metal Organic Frameworks with Coordinatively Unsaturated Metal Ions: MOF-74
journal, November 2014

Tan, Kui; Zuluaga, Sebastian; Gong, Qihan
Chemistry of Materials, Vol. 26, Issue 23
DOI: 10.1021/cm5038183

“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten
journal, January 2015

Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M.
Angewandte Chemie, Vol. 127, Issue 11
DOI: 10.1002/ange.201410252

Investigation of Acid Sites in a Zeotypic Giant Pores Chromium(III) Carboxylate
journal, March 2006

Vimont, Alexandre; Goupil, Jean-Michel; Lavalley, Jean-Claude
Journal of the American Chemical Society, Vol. 128, Issue 10
DOI: 10.1021/ja056906s

Multifunctional metal–organic frameworks: from academia to industrial applications
journal, January 2015

Silva, Patrícia; Vilela, Sérgio M. F.; Tomé, João P. C.
Chemical Society Reviews, Vol. 44, Issue 19
DOI: 10.1039/C5CS00307E

Synthesis, Characterization, and Application of Metal Organic Framework Nanostructures
journal, December 2010

Fernandez, Carlos A.; Nune, Satish K.; Motkuri, Radha Kishan
Langmuir, Vol. 26, Issue 24
DOI: 10.1021/la103590t

Stability Effects on CO ₂ Adsorption for the DOBDC Series of Metal–Organic Frameworks
journal, September 2011

Liu, Jian; Benin, Annabelle I.; Furtado, Amanda M. B.
Langmuir, Vol. 27, Issue 18
DOI: 10.1021/la201774x

Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields
journal, January 2015

Garzón-Tovar, L.; Carné-Sánchez, A.; Carbonell, C.
Journal of Materials Chemistry A, Vol. 3, Issue 41
DOI: 10.1039/C5TA04923G

Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M ₂ (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)
journal, January 2014

Queen, Wendy L.; Hudson, Matthew R.; Bloch, Eric D.
Chem. Sci., Vol. 5, Issue 12
DOI: 10.1039/C4SC02064B

Evaluation of an industrial pilot scale densified MOF-177 adsorbent as an on-board hydrogen storage medium
journal, January 2011

Dailly, Anne; Poirier, Eric
Energy & Environmental Science, Vol. 4, Issue 9
DOI: 10.1039/c1ee01426a

Fluorocarbon adsorption in hierarchical porous frameworks
journal, July 2014

Motkuri, Radha Kishan; Annapureddy, Harsha V. R.; Vijaykumar, M.
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms5368

Generation of 2D and 3D (PtS, Adamantanoid) Nets with a Flexible Tetrahedral Building Block
journal, September 2010

Tian, Jian; Motkuri, Radha Kishan; Thallapally, Praveen K.
Crystal Growth & Design, Vol. 10, Issue 9
DOI: 10.1021/cg1005677

Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
journal, September 2011

Stock, Norbert; Biswas, Shyam
Chemical Reviews, Vol. 112, Issue 2
DOI: 10.1021/cr200304e

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
DOI: 10.1021/ja8036096

A water-based and high space-time yield synthetic route to MOF Ni ₂ (dhtp) and its linker 2,5-dihydroxyterephthalic acid
journal, January 2014

Cadot, Stéphane; Veyre, Laurent; Luneau, Dominique
J. Mater. Chem. A, Vol. 2, Issue 42
DOI: 10.1039/C4TA03066D

Water Cluster Confinement and Methane Adsorption in the Hydrophobic Cavities of a Fluorinated Metal–Organic Framework
journal, August 2013

Nijem, Nour; Canepa, Pieremanuele; Kaipa, Ushasree
Journal of the American Chemical Society, Vol. 135, Issue 34
DOI: 10.1021/ja400754p

Facile xenon capture and release at room temperature using a metal–organic framework: a comparison with activated charcoal
journal, January 2012

Thallapally, Praveen K.; Grate, Jay W.; Motkuri, Radha Kishan
Chem. Commun., Vol. 48, Issue 3
DOI: 10.1039/C1CC14685H

Competitive Coadsorption of CO ₂ with H ₂ O, NH ₃ , SO ₂ , NO, NO ₂ , N ₂ , O ₂ , and CH ₄ in M-MOF-74 (M = Mg, Co, Ni): The Role of Hydrogen Bonding
journal, March 2015

Tan, Kui; Zuluaga, Sebastian; Gong, Qihan
Chemistry of Materials, Vol. 27, Issue 6
DOI: 10.1021/acs.chemmater.5b00315

Similar Records in DOE PAGES and OSTI.GOV collections:

A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications

Journal Article Liu, Jian ; Zheng, Jian ; Barpaga, Dushyant ; ... - European Journal of Inorganic Chemistry

A mixed metal strategy, in which two different metal nodes coexist in one MOF framework, was examined using MOF-74. The Ni salt precursor for the MOF-74(Ni) analogue was partially replaced during synthesis with relatively inexpensive Zn salt. These bimetallic MOFs were developed and examined for water sorption for potential use in adsorption cooling/chiller applications. Varying concentration ratios of Ni:Zn in MOF-74 achieved using this mixed metal strategy were shown to provide unique impacts on H2O uptake while significantly mitigating the costs of synthesis
https://doi.org/10.1002/ejic.201800042
Ab Initio Derived Force Fields for Predicting CO₂ Adsorption and Accessibility of Metal Sites in the Metal–Organic Frameworks M-MOF-74 (M = Mn, Co, Ni, Cu)

Journal Article Haldoupis, Emmanuel ; Borycz, Joshua ; Shi, Huiliang ; ... - Journal of Physical Chemistry. C

Metal–organic frameworks (MOFs) are versatile nanoporous materials that have gained significant interest as low heat capacity, high selectivity sorbents for CO₂ capture applications. Large-scale atomistic simulations for identifying high-performance MOFs are possible, but are limited to systems for which existing molecular mechanics force fields describe the interactions between the guest and framework atoms with sufficient accuracy. However, standard force fields are not applicable to cases involving coordinatively unsaturated metal centers that can strongly bind specific sorbate molecules. It has been previously shown that improved force fields can be derived from quantum mechanical calculations. We derived force fields for an isostructuralmore »« less
Cited by 70
https://doi.org/10.1021/acs.jpcc.5b03700

Full Text Available
Mixed‐Metal MOF‐74 Templated Catalysts for Efficient Carbon Dioxide Capture and Methanation

Journal Article Zurrer, Timothy ; Wong, Kenneth ; Horlyck, Jonathan ; ... - Advanced Functional Materials

Abstract The vast chemical and structural tunability of metal–organic frameworks (MOFs) are beginning to be harnessed as functional supports for catalytic nanoparticles spanning a range of applications. However, a lack of straightforward methods for producing nanoparticle‐encapsulated MOFs as efficient heterogeneous catalysts limits their usage. Herein, a mixed‐metal MOF, NiMg‐MOF‐74, is utilized as a template to disperse small Ni nanoclusters throughout the parent MOF. By exploiting the difference in NiO and MgO coordination bond strength, Ni ²⁺ is selectively reduced to form highly dispersed Ni nanoclusters constrained by the parent MOF pore diameter, while Mg ²⁺ remains coordinated in the framework. Bymore »« less
https://doi.org/10.1002/adfm.202007624
Revisiting Competitive Adsorption of Small Molecules in the Metal–Organic Framework Ni-MOF-74

Journal Article Pandey, Haardik ; Wang, Hao ; Feng, Liang ; ... - Inorganic Chemistry

To precisely evaluate the potential of metal-organic frameworks (MOFs) for gas separation and purification applications, it is crucial to understand how various molecules competitively adsorb inside MOFs. In this paper, we combine in situ infrared spectroscopy with ab initio calculations to investigate the mechanisms associated with co-adsorption of a number of small molecules including CO, NO, and CO₂ inside the prototypical framework Ni-MOF-74. Surprisingly, we find that the displacement of CO bound inside Ni-MOF-74 (binding energy of 53 kJ/mol) is readily driven by CO₂ exposure, even though CO₂ has a noticeably weaker binding energy of only 41 kJ/mol; meanwhile, themore »« less
https://doi.org/10.1021/acs.inorgchem.2c03751

Full Text Available
Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni

Journal Article Jiao, Yang ; Morelock, Cody R. ; Burtch, Nicholas C. ; ... - Industrial and Engineering Chemistry Research

Varying amounts of Co and Ni were substituted into the metal–organic framework Mg-MOF-74 via a one-pot solvothermal reaction, and the effects of these substitutions on CO₂ adsorption and kinetic water stability properties were examined. Based on elemental analyses, Co and Ni are more favorably incorporated into the MOF-74 framework from solution than Mg. In addition, reaction temperature more strongly impacts the final metal composition in these mixed-metal (MM) MOF-74 structures than does the reaction solvent composition. Single-component CO₂ adsorption isotherms were measured for the MM-MOF-74 systems at 5, 25, and 45 °C, and isosteric heats of adsorption were calculated. Thesemore »« less
Cited by 120
https://doi.org/10.1021/acs.iecr.5b03843

Full Text Available

Similar Records

Title: A Tunable Bimetallic MOF‐74 for Adsorption Chiller Applications

Abstract

Citation Formats

Understanding the H 2 Sorption Trends in the M-MOF-74 Series (M = Mg, Ni, Co, Zn) journal, December 2014

The effect of pyridine modification of Ni–DOBDC on CO 2 capture under humid conditions journal, January 2014

Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores journal, February 2001

“Heterogeneity within Order” in Metal-Organic Frameworks journal, January 2015

Scalability of Continuous Flow Production of Metal-Organic Frameworks journal, April 2016

CO 2 Dynamics in a Metal–Organic Framework with Open Metal Sites journal, August 2012

Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications journal, July 2017

Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni journal, December 2015

CO 2 /H 2 O Adsorption Equilibrium and Rates on Metal−Organic Frameworks: HKUST-1 and Ni/DOBDC journal, September 2010

Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach journal, December 2009

Harnessing Lewis acidic open metal sites of metal–organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane journal, January 2016

H 2 O Adsorption/Desorption in MOF-74: Ab Initio Molecular Dynamics and Experiments journal, May 2015

An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance journal, June 2016

Metal-Organic Frameworks - Heading towards Application: Metal-Organic Frameworks - Heading towards Application journal, September 2016

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks journal, February 2006

An In-Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal-Organic Frameworks CPO-27-M journal, March 2017

Separation of polar compounds using a flexible metal–organic framework journal, January 2015

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites journal, November 2009

Water Reaction Mechanism in Metal Organic Frameworks with Coordinatively Unsaturated Metal Ions: MOF-74 journal, November 2014

“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten journal, January 2015

Investigation of Acid Sites in a Zeotypic Giant Pores Chromium(III) Carboxylate journal, March 2006

Multifunctional metal–organic frameworks: from academia to industrial applications journal, January 2015

Synthesis, Characterization, and Application of Metal Organic Framework Nanostructures journal, December 2010

Stability Effects on CO 2 Adsorption for the DOBDC Series of Metal–Organic Frameworks journal, September 2011

Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields journal, January 2015

Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) journal, January 2014

Evaluation of an industrial pilot scale densified MOF-177 adsorbent as an on-board hydrogen storage medium journal, January 2011

Fluorocarbon adsorption in hierarchical porous frameworks journal, July 2014

Generation of 2D and 3D (PtS, Adamantanoid) Nets with a Flexible Tetrahedral Building Block journal, September 2010

Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites journal, September 2011

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores journal, August 2008

A water-based and high space-time yield synthetic route to MOF Ni 2 (dhtp) and its linker 2,5-dihydroxyterephthalic acid journal, January 2014

Water Cluster Confinement and Methane Adsorption in the Hydrophobic Cavities of a Fluorinated Metal–Organic Framework journal, August 2013

Facile xenon capture and release at room temperature using a metal–organic framework: a comparison with activated charcoal journal, January 2012

Competitive Coadsorption of CO 2 with H 2 O, NH 3 , SO 2 , NO, NO 2 , N 2 , O 2 , and CH 4 in M-MOF-74 (M = Mg, Co, Ni): The Role of Hydrogen Bonding journal, March 2015

Understanding the H ₂ Sorption Trends in the M-MOF-74 Series (M = Mg, Ni, Co, Zn)
journal, December 2014

The effect of pyridine modification of Ni–DOBDC on CO ₂ capture under humid conditions
journal, January 2014

Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
journal, February 2001

“Heterogeneity within Order” in Metal-Organic Frameworks
journal, January 2015

Scalability of Continuous Flow Production of Metal-Organic Frameworks
journal, April 2016

CO ₂ Dynamics in a Metal–Organic Framework with Open Metal Sites
journal, August 2012

Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications
journal, July 2017

Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni
journal, December 2015

CO ₂ /H ₂ O Adsorption Equilibrium and Rates on Metal−Organic Frameworks: HKUST-1 and Ni/DOBDC
journal, September 2010

Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach
journal, December 2009

Harnessing Lewis acidic open metal sites of metal–organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane
journal, January 2016

H ₂ O Adsorption/Desorption in MOF-74: Ab Initio Molecular Dynamics and Experiments
journal, May 2015

An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance
journal, June 2016

Metal-Organic Frameworks - Heading towards Application: Metal-Organic Frameworks - Heading towards Application
journal, September 2016

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

An In-Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal-Organic Frameworks CPO-27-M
journal, March 2017

Separation of polar compounds using a flexible metal–organic framework
journal, January 2015

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009

Water Reaction Mechanism in Metal Organic Frameworks with Coordinatively Unsaturated Metal Ions: MOF-74
journal, November 2014

“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten
journal, January 2015

Investigation of Acid Sites in a Zeotypic Giant Pores Chromium(III) Carboxylate
journal, March 2006

Multifunctional metal–organic frameworks: from academia to industrial applications
journal, January 2015

Synthesis, Characterization, and Application of Metal Organic Framework Nanostructures
journal, December 2010

Stability Effects on CO ₂ Adsorption for the DOBDC Series of Metal–Organic Frameworks
journal, September 2011

Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields
journal, January 2015

Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M ₂ (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)
journal, January 2014

Evaluation of an industrial pilot scale densified MOF-177 adsorbent as an on-board hydrogen storage medium
journal, January 2011

Fluorocarbon adsorption in hierarchical porous frameworks
journal, July 2014

Generation of 2D and 3D (PtS, Adamantanoid) Nets with a Flexible Tetrahedral Building Block
journal, September 2010

Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
journal, September 2011

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

A water-based and high space-time yield synthetic route to MOF Ni ₂ (dhtp) and its linker 2,5-dihydroxyterephthalic acid
journal, January 2014

Water Cluster Confinement and Methane Adsorption in the Hydrophobic Cavities of a Fluorinated Metal–Organic Framework
journal, August 2013

Facile xenon capture and release at room temperature using a metal–organic framework: a comparison with activated charcoal
journal, January 2012

Competitive Coadsorption of CO ₂ with H ₂ O, NH ₃ , SO ₂ , NO, NO ₂ , N ₂ , O ₂ , and CH ₄ in M-MOF-74 (M = Mg, Co, Ni): The Role of Hydrogen Bonding
journal, March 2015