Visualization and prediction of supercritical CO2 distribution in sandstones during drainage: An in situ synchrotron X-ray micro-computed tomography study
Abstract
Pore-scale distribution of supercritical CO2 (scCO2) exerts significant control on a variety of key hydrologic as well as geochemical processes, including residual trapping and dissolution. Despite such importance, only a small number of experiments have directly characterized the three-dimensional distribution of scCO2 in geologic materials during the invasion (drainage) process. Here, we present a study which couples dynamic high-resolution synchrotron X-ray micro-computed tomography imaging of a scCO2/brine system at in situ pressure/temperature conditions with quantitative pore-scale modeling to allow direct validation of a pore-scale description of scCO2 distribution. The experiment combines high-speed synchrotron radiography with tomography to characterize the brine saturated sample, the scCO2 breakthrough process, and the partially saturated state of a sandstone sample from the Domengine Formation, a regionally extensive unit within the Sacramento Basin (California, USA). The availability of a 3D dataset allowed us to examine correlations between grains and pores morphometric parameters and the actual distribution of scCO2 in the sample, including the examination of the role of small-scale sedimentary structure on CO2 distribution. The segmented scCO2/brine volume was also used to validate a simple computational model based on the local thickness concept, able to accurately simulate the distribution of scCO2 after drainage. The same methodmore »
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Nanoscale Control of Geologic CO2 (NCGC); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1420108
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- International Journal of Greenhouse Gas Control
- Additional Journal Information:
- Journal Volume: 66; Journal Issue: C; Journal ID: ISSN 1750-5836
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES; Geological carbon sequestration; scCO2 drainage; In situ synchrotron X-ray micro computed tomography; 3D quantitative morphometric analysis; Drainage predictive model.
Citation Formats
Voltolini, Marco, Kwon, Tae-Hyuk, and Ajo-Franklin, Jonathan. Visualization and prediction of supercritical CO2 distribution in sandstones during drainage: An in situ synchrotron X-ray micro-computed tomography study. United States: N. p., 2017.
Web. doi:10.1016/j.ijggc.2017.10.002.
Voltolini, Marco, Kwon, Tae-Hyuk, & Ajo-Franklin, Jonathan. Visualization and prediction of supercritical CO2 distribution in sandstones during drainage: An in situ synchrotron X-ray micro-computed tomography study. United States. https://doi.org/10.1016/j.ijggc.2017.10.002
Voltolini, Marco, Kwon, Tae-Hyuk, and Ajo-Franklin, Jonathan. Sat .
"Visualization and prediction of supercritical CO2 distribution in sandstones during drainage: An in situ synchrotron X-ray micro-computed tomography study". United States. https://doi.org/10.1016/j.ijggc.2017.10.002. https://www.osti.gov/servlets/purl/1420108.
@article{osti_1420108,
title = {Visualization and prediction of supercritical CO2 distribution in sandstones during drainage: An in situ synchrotron X-ray micro-computed tomography study},
author = {Voltolini, Marco and Kwon, Tae-Hyuk and Ajo-Franklin, Jonathan},
abstractNote = {Pore-scale distribution of supercritical CO2 (scCO2) exerts significant control on a variety of key hydrologic as well as geochemical processes, including residual trapping and dissolution. Despite such importance, only a small number of experiments have directly characterized the three-dimensional distribution of scCO2 in geologic materials during the invasion (drainage) process. Here, we present a study which couples dynamic high-resolution synchrotron X-ray micro-computed tomography imaging of a scCO2/brine system at in situ pressure/temperature conditions with quantitative pore-scale modeling to allow direct validation of a pore-scale description of scCO2 distribution. The experiment combines high-speed synchrotron radiography with tomography to characterize the brine saturated sample, the scCO2 breakthrough process, and the partially saturated state of a sandstone sample from the Domengine Formation, a regionally extensive unit within the Sacramento Basin (California, USA). The availability of a 3D dataset allowed us to examine correlations between grains and pores morphometric parameters and the actual distribution of scCO2 in the sample, including the examination of the role of small-scale sedimentary structure on CO2 distribution. The segmented scCO2/brine volume was also used to validate a simple computational model based on the local thickness concept, able to accurately simulate the distribution of scCO2 after drainage. The same method was also used to simulate Hg capillary pressure curves with satisfactory results when compared to the measured ones. Finally, this predictive approach, requiring only a tomographic scan of the dry sample, proved to be an effective route for studying processes related to CO2 invasion structure in geological samples at the pore scale.},
doi = {10.1016/j.ijggc.2017.10.002},
journal = {International Journal of Greenhouse Gas Control},
number = C,
volume = 66,
place = {United States},
year = {Sat Oct 21 00:00:00 EDT 2017},
month = {Sat Oct 21 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Reconstruction of Berea sandstone and pore-scale modelling of wettability effects
journal, September 2003
- Øren, Pål-Eric; Bakke, Stig
- Journal of Petroleum Science and Engineering, Vol. 39, Issue 3-4
High-resolution characterization of a CO2 plume using crosswell seismic tomography: Cranfield, MS, USA
journal, October 2013
- Ajo-Franklin, J. B.; Peterson, J.; Doetsch, J.
- International Journal of Greenhouse Gas Control, Vol. 18
Pore-scale imaging of geological carbon dioxide storage under in situ conditions: PORE-SCALE IMAGING OF CARBON STORAGE
journal, August 2013
- Andrew, Matthew; Bijeljic, Branko; Blunt, Martin J.
- Geophysical Research Letters, Vol. 40, Issue 15
Pore-scale imaging of trapped supercritical carbon dioxide in sandstones and carbonates
journal, March 2014
- Andrew, Matthew; Bijeljic, Branko; Blunt, Martin J.
- International Journal of Greenhouse Gas Control, Vol. 22
Pore-by-pore capillary pressure measurements using X-ray microtomography at reservoir conditions: Curvature, snap-off, and remobilization of residual CO 2
journal, November 2014
- Andrew, Matthew; Bijeljic, Branko; Blunt, Martin J.
- Water Resources Research, Vol. 50, Issue 11
The Imaging of Dynamic Multiphase Fluid Flow Using Synchrotron-Based X-ray Microtomography at Reservoir Conditions
journal, August 2015
- Andrew, Matthew; Menke, Hannah; Blunt, Martin J.
- Transport in Porous Media, Vol. 110, Issue 1
Investigating biomineralization using synchrotron based X-ray computed microtomography: MICROTOMOGRAPHY IMAGED BIOPRECIPITATES
journal, April 2011
- Armstrong, Ryan; Ajo-Franklin, Jonathan
- Geophysical Research Letters, Vol. 38, Issue 8
Near-liquidus growth of feldspar spherulites in trachytic melts: 3D morphologies and implications in crystallization mechanisms
journal, February 2015
- Arzilli, Fabio; Mancini, Lucia; Voltolini, Marco
- Lithos, Vol. 216-217
A novel protocol for resolving feldspar crystals in synchrotron X-ray microtomographic images of crystallized natural magmas and synthetic analogs
journal, October 2016
- Arzilli, Fabio; Polacci, Margherita; Landi, Patrizia
- American Mineralogist, Vol. 101, Issue 10
A four-dimensional X-ray tomographic microscopy study of bubble growth in basaltic foam
journal, January 2012
- Baker, Don R.; Brun, Francesco; O'Shaughnessy, Cedrick
- Nature Communications, Vol. 3, Issue 1
3-D Pore-Scale Modelling of Sandstones and Flow Simulations in the Pore Networks
journal, June 1997
- Bakke, Stig; Øren, Pål-Eric
- SPE Journal, Vol. 2, Issue 02
Real-time 3D imaging of Haines jumps in porous media flow
journal, February 2013
- Berg, S.; Ott, H.; Klapp, S. A.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 10
Connected pathway relative permeability from pore-scale imaging of imbibition
journal, April 2016
- Berg, S.; Rücker, M.; Ott, H.
- Advances in Water Resources, Vol. 90
Relative permeabilities from two- and three-dimensional pore-scale network modelling
journal, August 1991
- Blunt, Martin; King, Peter
- Transport in Porous Media, Vol. 6, Issue 4
Pore-scale imaging and modelling
journal, January 2013
- Blunt, Martin J.; Bijeljic, Branko; Dong, Hu
- Advances in Water Resources, Vol. 51
On Digital Distance Transforms in Three Dimensions
journal, November 1996
- Borgefors, Gunilla
- Computer Vision and Image Understanding, Vol. 64, Issue 3
Theory of quantitative phase-contrast computed tomography
journal, January 2002
- Bronnikov, Andrei V.
- Journal of the Optical Society of America A, Vol. 19, Issue 3
SYRMEP Tomo Project: a graphical user interface for customizing CT reconstruction workflows
journal, January 2017
- Brun, Francesco; Massimi, Lorenzo; Fratini, Michela
- Advanced Structural and Chemical Imaging, Vol. 3, Issue 1
Time-lapse sonic logs reveal patchy CO 2 saturation in-situ : IN-SITU CO
journal, July 2011
- Caspari, E.; Müller, T. M.; Gurevich, B.
- Geophysical Research Letters, Vol. 38, Issue 13
Interfacial tension measurements and wettability evaluation for geological CO2 storage
journal, January 2009
- Chalbaud, C.; Robin, M.; Lombard, J-M
- Advances in Water Resources, Vol. 32, Issue 1
PITRE : software for phase-sensitive X-ray image processing and tomography reconstruction
journal, August 2012
- Chen, Rong-Chang; Dreossi, Diego; Mancini, Lucia
- Journal of Synchrotron Radiation, Vol. 19, Issue 5
Octopus, a fast and user-friendly tomographic reconstruction package developed in LabView®
journal, June 2004
- Dierick, M.; Masschaele, B.; Hoorebeke, L. Van
- Measurement Science and Technology, Vol. 15, Issue 7
Computing Local Thickness of 3D Structures with ImageJ
journal, August 2007
- Dougherty, R.; Kunzelmann, K-H
- Microscopy and Microanalysis, Vol. 13, Issue S02
TomoPy: a framework for the analysis of synchrotron tomographic data
journal, August 2014
- Gürsoy, Dogˇa; De Carlo, Francesco; Xiao, Xianghui
- Journal of Synchrotron Radiation, Vol. 21, Issue 5
Characterizing Small-scale Migration Behavior of Sequestered CO2 in a Realistic Geologic Fabric
journal, January 2013
- Ganesh, Priya Ravi; Bryant, Steven L.; Meckel, Timothy A.
- Energy Procedia, Vol. 37
Characterization of microstructural anisotropy in orthotropic materials using a second rank tensor
journal, March 1984
- Harrigan, T. P.; Mann, R. W.
- Journal of Materials Science, Vol. 19, Issue 3
Pore-scale observations of supercritical CO2 drainage in Bentheimer sandstone by synchrotron x-ray imaging
journal, June 2014
- Herring, Anna L.; Andersson, Linnéa; Newell, D. L.
- International Journal of Greenhouse Gas Control, Vol. 25
Kinetic Model of Gas Bubble Dissolution in Groundwater and Its Implications for the Dissolved Gas Composition
journal, April 2003
- Holocher, J.; Peeters, F.; Aeschbach-Hertig, W.
- Environmental Science & Technology, Vol. 37, Issue 7
Fast connected-component labelling in three-dimensional binary images based on iterative recursion
journal, September 2005
- Hu, Qingmao; Qian, Guoyu; Nowinski, Wieslaw L.
- Computer Vision and Image Understanding, Vol. 99, Issue 3
Computation of Relative Permeability from Imaged Fluid Distributions at the Pore Scale
journal, May 2014
- Hussain, F.; Pinczewski, W. V.; Cinar, Y.
- Transport in Porous Media, Vol. 104, Issue 1
Residual CO 2 imaged with X-ray micro-tomography : RESIDUAL CO
journal, November 2011
- Iglauer, Stefan; Paluszny, Adriana; Pentland, Christopher H.
- Geophysical Research Letters, Vol. 38, Issue 21
Numerical investigations on the effect of initial state CO 2 topology on capillary trapping efficiency
journal, June 2016
- Jiang, Fei; Tsuji, Takeshi
- International Journal of Greenhouse Gas Control, Vol. 49
Computational methods for quantitative analysis of three-dimensional features in geological specimens
journal, January 2005
- Ketcham, Richard A.
- Geosphere, Vol. 1, Issue 1
Three-dimensional grain fabric measurements using high-resolution X-ray computed tomography
journal, July 2005
- Ketcham, Richard A.
- Journal of Structural Geology, Vol. 27, Issue 7
Dewetting of Silica Surfaces upon Reactions with Supercritical CO 2 and Brine: Pore-Scale Studies in Micromodels
journal, March 2012
- Kim, Yongman; Wan, Jiamin; Kneafsey, Timothy J.
- Environmental Science & Technology, Vol. 46, Issue 7
Supercritical CO2 flow through a layered silica sand/calcite sand system: Experiment and modified maximal inscribed spheres analysis
journal, May 2013
- Kneafsey, Timothy J.; Silin, Dmitriy; Ajo-Franklin, Jonathan B.
- International Journal of Greenhouse Gas Control, Vol. 14
Measurement of accessible reactive surface area in a sandstone, with application to CO2 mineralization
journal, July 2012
- Landrot, Gautier; Ajo-Franklin, Jonathan B.; Yang, Li
- Chemical Geology, Vol. 318-319
Pore-Scale Characterization of Two-Phase Flow Using Integral Geometry
journal, March 2017
- Liu, Zhishang; Herring, Anna; Arns, Christoph
- Transport in Porous Media, Vol. 118, Issue 1
Modeling and simulation of pore-scale multiphase fluid flow and reactive transport in fractured and porous media
journal, January 2009
- Meakin, Paul; Tartakovsky, Alexandre M.
- Reviews of Geophysics, Vol. 47, Issue 3
Digital Rendering of Sedimentary-Relief Peels: Implications for Clastic Facies Characterization and Fluid Flow
journal, June 2013
- Meckel, T. A.
- Journal of Sedimentary Research, Vol. 83, Issue 6
Topographic distance and watershed lines
journal, July 1994
- Meyer, Fernand
- Signal Processing, Vol. 38, Issue 1
Polychromatic cone-beam phase-contrast tomography
journal, October 2007
- Myers, G. R.; Mayo, S. C.; Gureyev, T. E.
- Physical Review A, Vol. 76, Issue 4
Laboratory seismic monitoring of supercritical CO 2 flooding in sandstone cores using the Split Hopkinson Resonant Bar technique with concurrent x-ray Computed Tomography imaging
journal, January 2013
- Nakagawa, Seiji; Kneafsey, Timothy J.; Daley, Thomas M.
- Geophysical Prospecting, Vol. 61, Issue 2
Upscaling calcium carbonate precipitation rates from pore to continuum scale
journal, July 2012
- Noiriel, Catherine; Steefel, Carl I.; Yang, Li
- Chemical Geology, Vol. 318-319
A Threshold Selection Method from Gray-Level Histograms
journal, January 1979
- Otsu, Nobuyuki
- IEEE Transactions on Systems, Man, and Cybernetics, Vol. 9, Issue 1
Simultaneous phase and amplitude extraction from a single defocused image of a homogeneous object
journal, April 2002
- Paganin, D.; Mayo, S. C.; Gureyev, T. E.
- Journal of Microscopy, Vol. 206, Issue 1
Verification of a Complete Pore Network Simulator of Drainage and Imbibition
conference, April 2013
- Patzek, Tad W.
- SPE/DOE Improved Oil Recovery Symposium
Simultaneous determination of capillary pressure and relative permeability curves from core-flooding experiments with various fluid pairs: Capillary Pressure and Relative Permeability Curves
journal, June 2013
- Pini, Ronny; Benson, Sally M.
- Water Resources Research, Vol. 49, Issue 6
Picture Thresholding Using an Iterative Selection Method
journal, January 1978
- Ridler, T. W.; Calvard, S.
- IEEE Transactions on Systems, Man, and Cybernetics, Vol. 8, Issue 8, p. 630-632
The Watershed Transform: Definitions, Algorithms and Parallelization Strategies
journal, January 2000
- Roerdink, Jos B. T. M.; Meijster, Arnold
- Fundamenta Informaticae, Vol. 41, Issue 1,2
Fiji: an open-source platform for biological-image analysis
journal, June 2012
- Schindelin, Johannes; Arganda-Carreras, Ignacio; Frise, Erwin
- Nature Methods, Vol. 9, Issue 7
Pore space morphology analysis using maximal inscribed spheres
journal, November 2006
- Silin, Dmitriy; Patzek, Tad
- Physica A: Statistical Mechanics and its Applications, Vol. 371, Issue 2
Microtomography and Pore-Scale Modeling of Two-Phase Fluid Distribution
journal, August 2010
- Silin, Dmitriy; Tomutsa, Liviu; Benson, Sally M.
- Transport in Porous Media, Vol. 86, Issue 2
Pore Scale Processes Associated with Subsurface CO2 Injection and Sequestration
journal, January 2013
- Steefel, C. I.; Molins, S.; Trebotich, D.
- Reviews in Mineralogy and Geochemistry, Vol. 77, Issue 1
Capillary pressure and saturation relations for supercritical CO 2 and brine in sand: High-pressure P c ( S w ) controller/meter measurements and capillary scaling predictions : CO
journal, August 2013
- Tokunaga, Tetsu K.; Wan, Jiamin; Jung, Jong-Won
- Water Resources Research, Vol. 49, Issue 8
Two-Phase Flow: Structure, Upscaling, and Consequences for Macroscopic Transport Properties
journal, January 2012
- Toussaint, R.; Måløy, K. J.; Méheust, Y.
- Vadose Zone Journal, Vol. 11, Issue 3
Texture analysis of volcanic rock samples: Quantitative study of crystals and vesicles shape preferred orientation from X-ray microtomography data
journal, April 2011
- Voltolini, M.; Zandomeneghi, D.; Mancini, L.
- Journal of Volcanology and Geothermal Research, Vol. 202, Issue 1-2
Capillary Pressure–Saturation Relations for Supercritical CO 2 and Brine in Limestone/Dolomite Sands: Implications for Geologic Carbon Sequestration in Carbonate Reservoirs
journal, June 2015
- Wang, Shibo; Tokunaga, Tetsu K.
- Environmental Science & Technology, Vol. 49, Issue 12
ANKAphase : software for single-distance phase retrieval from inline X-ray phase-contrast radiographs
journal, March 2011
- Weitkamp, T.; Haas, D.; Wegrzynek, D.
- Journal of Synchrotron Radiation, Vol. 18, Issue 4
Computed Seismic Speeds and Attenuation in Rocks with Partial gas Saturation
journal, April 1975
- White, J. E.
- GEOPHYSICS, Vol. 40, Issue 2
Invasion percolation: a new form of percolation theory
journal, October 1983
- Wilkinson, D.; Willemsen, J. F.
- Journal of Physics A: Mathematical and General, Vol. 16, Issue 14
Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation
journal, September 2011
- Wu, Yuxin; Ajo-Franklin, Jonathan B.; Spycher, Nicolas
- Geochemical Transactions, Vol. 12, Issue 1
3D Pore-network quantitative analysis in deformed carbonate grainstones
journal, April 2017
- Zambrano, Miller; Tondi, Emanuele; Mancini, Lucia
- Marine and Petroleum Geology, Vol. 82
Quantitative analysis of X-ray microtomography images of geomaterials: Application to volcanic rocks
journal, October 2010
- Zandomeneghi, D.; Voltolini, M.; Mancini, L.
- Geosphere, Vol. 6, Issue 6
Pore-scale multiphase flow modeling and imaging of CO2 exsolution in Sandstone
journal, July 2017
- Zuo, Lin; Ajo-Franklin, Jonathan B.; Voltolini, Marco
- Journal of Petroleum Science and Engineering, Vol. 155
Works referencing / citing this record:
A new mini-triaxial cell for combined high-pressure and high-temperature in situ synchrotron X-ray microtomography experiments up to 400°C and 24 MPa
journal, January 2019
- Voltolini, Marco; Barnard, Harold; Creux, Patrice
- Journal of Synchrotron Radiation, Vol. 26, Issue 1
Implementation of Dynamic Neutron Radiography and Integrated X-Ray and Neutron Tomography in Porous Carbonate Reservoir Rocks
journal, December 2019
- Zambrano, Miller; Hameed, Fareeha; Anders, Kaestner
- Frontiers in Earth Science, Vol. 7